File name: Pandora142s1_MexicoCity-UNAM_20250310_L2Fit_fout2c13d20231028p1-8.txt File generation date: 20250311T065418.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c13p1-8 Local principal investigator: Michel Grutter de la Mora Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora142_OF_v4d20200821.txt Instrument calibration file used: Pandora142s1_CF_v13d20231028.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20250310_L1_smca1c13d20231028p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20250310 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 12 "Modification of session 11 "Modification of session 10, but different Reference day."" First and last pixel inside fitting window: 236 378 Nominal wavelengths inside fitting window [nm]: 305.0157 305.1568 305.2979 305.4390 305.5801 305.7212 305.8622 306.0033 306.1443 306.2853 306.4263 306.5673 306.7083 306.8493 306.9903 307.1312 307.2722 307.4131 307.5540 307.6949 307.8358 307.9767 308.1176 308.2585 308.3993 308.5402 308.6810 308.8218 308.9626 309.1034 309.2442 309.3850 309.5258 309.6665 309.8073 309.9480 310.0887 310.2294 310.3701 310.5108 310.6515 310.7922 310.9328 311.0735 311.2141 311.3547 311.4953 311.6359 311.7765 311.9171 312.0577 312.1982 312.3388 312.4793 312.6198 312.7603 312.9008 313.0413 313.1818 313.3222 313.4627 313.6031 313.7436 313.8840 314.0244 314.1648 314.3052 314.4455 314.5859 314.7263 314.8666 315.0069 315.1472 315.2875 315.4278 315.5681 315.7084 315.8487 315.9889 316.1291 316.2694 316.4096 316.5498 316.6900 316.8302 316.9703 317.1105 317.2506 317.3908 317.5309 317.6710 317.8111 317.9512 318.0913 318.2314 318.3714 318.5115 318.6515 318.7915 318.9315 319.0715 319.2115 319.3515 319.4915 319.6314 319.7714 319.9113 320.0512 320.1911 320.3310 320.4709 320.6108 320.7506 320.8905 321.0303 321.1702 321.3100 321.4498 321.5896 321.7294 321.8691 322.0089 322.1486 322.2884 322.4281 322.5678 322.7075 322.8472 322.9869 323.1266 323.2662 323.4059 323.5455 323.6851 323.8247 323.9643 324.1039 324.2435 324.3831 324.5226 324.6622 324.8017 324.9412 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250310T131658.8Z 9200.553458 176 1 47.74 2 84.21 96.17 121.93 312.91 0.00 1 0.00 1 0 25 6.091e-01 3.545e-02 2.866e-01 1.483e-02 7.965639e-01 8.622014e-03 9.094907e-03 -6.000000e+00 3.563949e-01 225.65 -2.00 3.11 -2.00 322.09 0.00e+00 2.690898e-02 4.689176e-03 7.774057e-04 -6.000000e+00 1.803625e-02 280.02 -2.00 20.00 -2.00 321.63 0.00e+00 8.835 0.003 302.00 328.00 3 2.0844e+00 3.2277e-02 8.1388e-02 -6.0000e+00 8.8600e-01 1.0092e+00 4.0213e-02 6.2458e-02 -6.0000e+00 9.7042e-01 -1.4837e+00 3.2158e-02 1.9794e-02 -6.0000e+00 5.6898e-01 6.2867e-01 1.5654e-02 2.3881e-02 -6.0000e+00 2.4566e-01 3.1789e-05 -1.3626e-03 4.2883e-04 3.1539e-04 -6.0000e+00 1.8120e-02 2.0020e-02 0.0000e+00 12 8 8 10 0 0 37.58 23.48 0.38 0.02002 0.00978 26 6 1 5 0 1835.620 26.21 19.99 23.48 16.51 35.1 779.74 900000 -63775 900000 -80582 900000 -17381 900000 -88447 900000 -17631 900000 -76552 900000 -13688 900000 284 56847 52603 56087 472021 107812 900000 900000 85842 -45156 100554 -59998 900000 -49515 900000 14010 900000 -56336 900000 29142 900000 155577 900000 -14165 900000 -10542 112638 -2278 900000 10504 900000 9211 63792 8594 90252 95273 158453 85860 85982 53476 30569 61090 2912 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-6192 3554 -6217 1911 -6420 1233 -6715 4303 -1282 5540 -4584 2391 -3778 756 1109 -371 -644 -2805 1110 818 6574 -266 6798 2008 7378 -11173 4379 1111 4651 108 7043 -79 1758 -2602 -824 -3634 1218 -1339 914 -3368 -1793 SS 20250310T132802.7Z 9200.561142 179 1 48.19 2 81.62 97.12 123.75 314.87 0.00 1 0.00 1 0 17 4.228e-01 7.452e-03 2.358e-01 3.211e-03 6.612092e-01 1.725351e-03 6.553291e-03 -6.000000e+00 2.398597e-01 225.65 -2.00 3.11 -2.00 321.40 0.00e+00 6.437900e-03 8.695770e-04 7.064184e-04 -6.000000e+00 1.072547e-02 280.02 -2.00 20.00 -2.00 320.88 0.00e+00 6.470 0.001 302.00 328.00 3 1.5942e+00 5.9595e-03 5.8276e-02 -6.0000e+00 5.9433e-01 3.3915e-02 8.4819e-03 3.2527e-02 -6.0000e+00 6.4814e-01 -6.1973e-02 9.0963e-03 1.8569e-02 -6.0000e+00 3.8603e-01 1.7045e-02 4.2970e-03 1.0086e-02 -6.0000e+00 1.6385e-01 3.8866e-04 -4.1541e-04 9.2171e-05 1.0448e-04 -6.0000e+00 1.1375e-02 2.0203e-02 0.0000e+00 11 8 0 10 0 0 12.55 23.47 0.23 0.02020 0.01708 129 32 1 5 0 373.540 26.21 19.99 23.47 17.60 35.2 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-600 494 -863 1026 430 220 609 774 -306 513 -272 866 259 1853 279 916 -571 406 50 983 469 797 -70 361 34 724 -234 -241 221 75 -768 983 -1312 -856 -378 -149 -574 -178 425 440 806 -266 -703 -373 -51 323 681 -99 238 -959 -100 -459 -403 -659 -647 -1210 -755 -1101 241 -412 196 42 458 -191 694 -576 618 1145 -213 -41 -377 399 155 381 -30 1189 1427 -1188 613 959 -341 1486 -319 512 -902 -104 -556 349 -1359 174 -787 845 -13 SS 20250310T134133.6Z 9200.570528 184 1 48.16 2 78.46 98.31 125.90 317.42 0.00 1 0.00 1 0 25 1.291e-01 5.482e-03 3.873e-02 1.154e-03 5.220269e-01 5.941437e-04 5.316251e-03 -6.000000e+00 7.291880e-02 225.65 -2.00 3.11 -2.00 320.48 0.00e+00 3.720202e-03 2.251560e-04 6.047115e-04 -6.000000e+00 3.214657e-03 280.02 -2.00 20.00 -2.00 319.89 0.00e+00 4.843 0.000 302.00 328.00 3 1.2290e+00 1.8035e-03 4.4325e-02 -6.0000e+00 1.8044e-01 3.1598e-03 2.2757e-03 2.5567e-02 -6.0000e+00 1.9650e-01 2.9224e-03 2.1599e-03 1.2638e-02 -6.0000e+00 1.1707e-01 -1.3884e-02 1.0917e-03 5.9633e-03 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