File name: Pandora142s1_MexicoCity-UNAM_20250409_L2Fit_fwvt1c13d20231028p1-8.txt File generation date: 20250410T065124.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c13p1-8 Local principal investigator: Michel Grutter de la Mora Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 142 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora142_OF_v4d20200821.txt Instrument calibration file used: Pandora142s1_CF_v13d20231028.txt Level 1 file used: Pandora142s1_MexicoCity-UNAM_20250409_L1_smca1c13d20231028p1-8.txt Full location name: Centro de Ciencias de la Atmosfera, UNAM Short location name: MexicoCity-UNAM Country of location: Mexico Location latitude [deg]: 19.3262 Location longitude [deg]: -99.1761 Location altitude [m]: 2280 Local noon date: 20250409 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 12 "Modification of session 11 "Modification of session 10, but different Reference day."" First and last pixel inside fitting window: 1653 1802 Nominal wavelengths inside fitting window [nm]: 492.0134 492.1348 492.2563 492.3777 492.4991 492.6205 492.7418 492.8632 492.9845 493.1058 493.2271 493.3484 493.4697 493.5909 493.7121 493.8334 493.9546 494.0757 494.1969 494.3180 494.4392 494.5603 494.6814 494.8025 494.9235 495.0446 495.1656 495.2866 495.4076 495.5286 495.6495 495.7705 495.8914 496.0123 496.1332 496.2541 496.3750 496.4958 496.6166 496.7374 496.8582 496.9790 497.0998 497.2205 497.3412 497.4619 497.5826 497.7033 497.8240 497.9446 498.0652 498.1858 498.3064 498.4270 498.5475 498.6681 498.7886 498.9091 499.0296 499.1501 499.2705 499.3910 499.5114 499.6318 499.7522 499.8725 499.9929 500.1132 500.2335 500.3538 500.4741 500.5944 500.7146 500.8349 500.9551 501.0753 501.1955 501.3156 501.4358 501.5559 501.6760 501.7961 501.9162 502.0363 502.1563 502.2763 502.3964 502.5163 502.6363 502.7563 502.8762 502.9962 503.1161 503.2360 503.3558 503.4757 503.5955 503.7154 503.8352 503.9549 504.0747 504.1945 504.3142 504.4339 504.5536 504.6733 504.7930 504.9126 505.0323 505.1519 505.2715 505.3911 505.5107 505.6302 505.7497 505.8693 505.9888 506.1082 506.2277 506.3471 506.4666 506.5860 506.7054 506.8248 506.9441 507.0635 507.1828 507.3021 507.4214 507.5407 507.6599 507.7792 507.8984 508.0176 508.1368 508.2560 508.3751 508.4942 508.6134 508.7325 508.8516 508.9706 509.0897 509.2087 509.3277 509.4467 509.5657 509.6847 509.8036 509.9226 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250409T125011.5Z 9230.534855 178 1 19.57 2 84.63 83.61 122.19 293.35 0.00 1 0.00 1 0 22 2.655e-03 2.652e-03 1.761e-04 1.759e-04 5.560681e+03 1.152852e+01 3.783205e+02 -6.000000e+00 1.523000e+02 280.70 -2.00 20.00 -2.00 505.32 0.00e+00 4.507740e-03 4.921141e-06 2.478508e-04 -6.000000e+00 7.529131e-05 280.70 -2.00 20.00 -2.00 500.72 0.00e+00 5.864246e-01 3.511305e-03 5.677676e-02 -6.000000e+00 5.370086e-02 227.77 -2.00 3.11 -2.00 502.27 0.00e+00 9.362 0.004 489.00 513.00 1 2.5239e+00 2.6942e-04 1.2739e-02 -6.0000e+00 4.1258e-03 -3.3570e-02 6.7707e-05 1.2190e-03 -6.0000e+00 1.0552e-03 5.0365e-02 2.4960e-04 1.9412e-05 1.0717e-04 -6.0000e+00 3.0349e-04 7.2620e-03 -2.0578e-05 12 1 1 12 1 1 45.74 23.83 1.09 0.00726 0.00899 281 171 1 4 0 69.380 26.51 19.99 23.83 15.81 34.6 781.73 -465 -325 -165 20 55 324 493 450 413 332 166 39 -106 -179 -145 -155 -177 -29 177 23 90 239 284 291 445 258 128 75 -74 -306 -166 -135 -184 89 21 -219 -175 72 -8 0 72 85 102 188 197 262 164 66 -90 -220 -422 -397 -449 -406 -299 -184 -113 9 120 290 329 417 153 236 217 85 -43 -120 -82 -170 -137 -172 -299 -236 -119 -314 -326 -321 -241 -371 -357 -427 -420 -336 -244 -349 -248 -110 -32 66 79 178 272 158 161 120 -42 -149 -205 -379 -460 -478 -475 -341 -460 -490 -276 -137 -23 147 109 139 255 472 468 597 660 549 359 407 360 257 341 401 189 188 280 106 89 256 24 -54 56 -83 -148 4 -80 -281 -21 45 55 100 174 37 -59 -60 -128 -259 -234 -282 -434 -305 -155 20 54 319 495 457 419 334 165 39 -102 -177 -142 -152 -170 -29 178 23 89 239 284 292 449 262 129 75 -73 -303 -161 -131 -182 88 21 -225 -179 73 -8 0 72 87 102 191 202 270 169 67 -90 -222 -418 -385 -433 -394 -297 -182 -114 9 124 299 340 433 156 240 225 87 -44 -120 -81 -167 -133 -168 -295 -235 -119 -312 -320 -319 -238 -365 -351 -424 -408 -329 -241 -347 -247 -109 -32 66 80 175 271 158 159 119 -41 -143 -197 -360 -437 -461 -459 -339 -455 -488 -273 -134 -23 145 109 142 257 480 480 616 684 571 372 417 363 257 340 401 191 191 284 107 91 259 24 -53 56 -83 -145 4 -81 -290 -21 46 57 105 182 39 -62 -62 -130 -259 -238 -287 SQ 20250409T130053.2Z 9230.542283 181 1 11.85 2 82.12 84.46 124.43 294.81 0.00 1 0.00 1 0 15 2.151e-03 2.150e-03 2.288e-04 2.286e-04 4.084368e+03 1.457821e+01 2.776380e+02 -6.000000e+00 1.234001e+02 280.70 -2.00 20.00 -2.00 505.30 0.00e+00 3.166340e-03 6.370941e-06 1.761338e-04 -6.000000e+00 6.099798e-05 280.70 -2.00 20.00 -2.00 500.63 0.00e+00 4.307381e-01 4.570439e-03 4.194238e-02 -6.000000e+00 4.349674e-02 227.77 -2.00 3.11 -2.00 502.20 0.00e+00 6.827 0.001 489.00 513.00 1 2.8851e+00 3.5044e-04 9.2449e-03 -6.0000e+00 3.3420e-03 -2.5138e-02 8.8738e-05 9.0209e-04 -6.0000e+00 8.5442e-04 4.7831e-02 -4.6294e-04 2.5354e-05 7.7176e-05 -6.0000e+00 2.4592e-04 1.3236e-02 -3.1758e-05 12 1 1 12 1 1 98.77 23.83 0.86 0.01324 0.01003 149 150 1 4 0 78.960 26.51 20.00 23.83 16.61 34.7 781.78 -229 -235 -73 63 16 249 444 393 353 307 183 62 -58 -107 -29 -139 -126 5 125 8 -25 178 222 228 399 260 -9 3 -44 -247 -74 -50 -112 57 -43 -284 -201 36 -18 1 77 155 86 160 161 147 97 36 -54 -199 -350 -262 -353 -326 -219 -152 -175 -109 25 225 279 306 128 119 141 28 -38 -86 -64 -97 -142 -153 -304 -165 -87 -280 -333 -267 -125 -211 -268 -325 -428 -193 -169 -270 -231 -149 36 51 31 94 139 72 68 56 -132 -154 -159 -273 -303 -396 -365 -308 -438 -432 -218 -50 8 157 116 70 208 344 404 496 508 423 267 341 300 223 312 361 182 159 260 120 69 249 130 56 113 -4 -85 61 -46 -230 -43 61 28 66 124 -1 -110 -69 -110 -188 -162 -231 -218 -225 -70 62 16 253 447 399 359 311 183 63 -58 -105 -28 -136 -125 5 126 8 -25 184 224 230 405 265 -9 3 -44 -244 -74 -49 -110 57 -44 -292 -206 37 -18 1 77 156 88 165 165 151 100 36 -55 -199 -350 -256 -343 -319 -219 -153 -180 -110 26 228 284 313 131 122 143 28 -38 -86 -64 -95 -139 -150 -300 -164 -88 -279 -329 -260 -120 -203 -258 -315 -418 -190 -168 -270 -231 -146 35 50 31 94 141 74 68 55 -131 -149 -151 -262 -290 -377 -357 -303 -440 -436 -218 -49 8 156 115 71 211 353 409 504 519 432 271 342 304 223 312 362 183 161 263 122 70 251 130 55 110 -4 -83 61 -46 -231 -43 63 29 67 126 -1 -112 -69 -111 -187 -159 -227 SQ 20250409T131140.7Z 9230.549777 183 1 6.64 2 79.58 85.32 126.67 296.37 0.00 1 0.00 1 0 15 1.986e-03 1.992e-03 1.300e-04 1.299e-04 3.168826e+03 8.127108e+00 2.178557e+02 -6.000000e+00 1.139237e+02 280.70 -2.00 20.00 -2.00 505.28 0.00e+00 2.427252e-03 3.608058e-06 1.349713e-04 -6.000000e+00 5.631945e-05 280.70 -2.00 20.00 -2.00 500.60 0.00e+00 3.081512e-01 2.594683e-03 3.257610e-02 -6.000000e+00 4.016857e-02 227.77 -2.00 3.11 -2.00 502.17 0.00e+00 5.320 0.001 489.00 513.00 1 1.2210e+00 1.9905e-04 7.1748e-03 -6.0000e+00 3.0861e-03 -2.3616e-02 5.0530e-05 7.0475e-04 -6.0000e+00 7.8931e-04 3.0416e-01 2.8154e-05 1.4455e-05 5.8578e-05 -6.0000e+00 2.2705e-04 1.9164e-02 -9.0328e-05 10 0 0 10 0 0 31.16 23.80 0.80 0.01916 0.01936 546 135 1 4 0 11.870 26.51 20.00 23.80 17.77 34.9 781.76 -232 -93 -48 83 21 225 398 334 311 243 107 49 -69 -91 -58 -66 -110 27 146 -11 11 175 236 257 347 224 -8 -24 -56 -217 -2 25 -119 107 -43 -323 -243 -16 -26 -6 76 107 62 123 128 109 91 12 -91 -175 -305 -244 -296 -307 -179 -177 -199 -110 1 166 250 285 70 124 130 45 -45 -71 -24 -120 -78 -115 -243 -148 -103 -296 -285 -200 -103 -167 -222 -283 -357 -235 -188 -248 -227 -88 4 42 37 79 171 24 39 45 -128 -118 -133 -175 -240 -377 -378 -281 -500 -473 -239 -62 78 179 108 83 198 323 351 406 453 383 252 338 343 247 270 310 163 176 275 91 88 196 77 2 160 19 -75 97 -52 -280 -91 21 18 95 114 18 -93 -77 -98 -148 -93 -168 -221 -90 -46 81 22 223 402 341 317 246 107 49 -69 -91 -58 -65 -111 26 147 -11 11 181 244 266 362 233 -9 -25 -56 -214 -2 24 -117 108 -45 -328 -247 -17 -27 -6 78 110 62 125 131 112 93 12 -91 -177 -302 -236 -284 -297 -177 -180 -200 -112 1 169 254 292 72 127 132 45 -44 -69 -24 -119 -77 -114 -243 -145 -101 -289 -284 -197 -100 -162 -217 -278 -354 -227 -183 -243 -223 -87 4 41 37 79 174 24 40 44 -125 -113 -129 -167 -229 -366 -364 -278 -506 -481 -240 -62 77 179 105 82 200 329 360 418 469 396 260 344 344 245 267 307 163 176 275 91 88 194 76 2 153 18 -72 94 -52 -282 -93 21 18 96 115 18 -94 -77 -100 -148 -92 -166 SQ 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