File name: Pandora142s1_MexicoCity-UNAM_20250522_L2Fit_fout2c13d20231028p1-8.txt
File generation date: 20250523T064434.9Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c13p1-8
Local principal investigator: Michel Grutter de la Mora
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 142
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora142_OF_v4d20200821.txt
Instrument calibration file used: Pandora142s1_CF_v13d20231028.txt
Level 1 file used: Pandora142s1_MexicoCity-UNAM_20250522_L1_smca1c13d20231028p1-8.txt
Full location name: Centro de Ciencias de la Atmosfera, UNAM
Short location name: MexicoCity-UNAM
Country of location: Mexico
Location latitude [deg]: 19.3262
Location longitude [deg]: -99.1761
Location altitude [m]: 2280
Local noon date: 20250522
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 12 "Modification of session 11 "Modification of session 10, but different Reference day.""
First and last pixel inside fitting window: 236 378
Nominal wavelengths inside fitting window [nm]: 305.0157 305.1568 305.2979 305.4390 305.5801 305.7212 305.8622 306.0033 306.1443 306.2853 306.4263 306.5673 306.7083 306.8493 306.9903 307.1312 307.2722 307.4131 307.5540 307.6949 307.8358 307.9767 308.1176 308.2585 308.3993 308.5402 308.6810 308.8218 308.9626 309.1034 309.2442 309.3850 309.5258 309.6665 309.8073 309.9480 310.0887 310.2294 310.3701 310.5108 310.6515 310.7922 310.9328 311.0735 311.2141 311.3547 311.4953 311.6359 311.7765 311.9171 312.0577 312.1982 312.3388 312.4793 312.6198 312.7603 312.9008 313.0413 313.1818 313.3222 313.4627 313.6031 313.7436 313.8840 314.0244 314.1648 314.3052 314.4455 314.5859 314.7263 314.8666 315.0069 315.1472 315.2875 315.4278 315.5681 315.7084 315.8487 315.9889 316.1291 316.2694 316.4096 316.5498 316.6900 316.8302 316.9703 317.1105 317.2506 317.3908 317.5309 317.6710 317.8111 317.9512 318.0913 318.2314 318.3714 318.5115 318.6515 318.7915 318.9315 319.0715 319.2115 319.3515 319.4915 319.6314 319.7714 319.9113 320.0512 320.1911 320.3310 320.4709 320.6108 320.7506 320.8905 321.0303 321.1702 321.3100 321.4498 321.5896 321.7294 321.8691 322.0089 322.1486 322.2884 322.4281 322.5678 322.7075 322.8472 322.9869 323.1266 323.2662 323.4059 323.5455 323.6851 323.8247 323.9643 324.1039 324.2435 324.3831 324.5226 324.6622 324.8017 324.9412
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250522T131911.1Z 9273.554989 176 1 47.92 2 73.07 73.67 26.41 137.65 0.00 1 0.00 1 0 17 6.303e-02 7.354e-03 3.396e-02 2.797e-03 4.020868e-01 1.416135e-03 4.195867e-03 -6.000000e+00 3.601788e-02 228.47 -2.00 3.11 -2.00 319.43 0.00e+00 2.537694e-03 3.777965e-04 3.208854e-04 -6.000000e+00 1.583342e-03 282.02 -2.00 20.00 -2.00 318.73 0.00e+00 3.385 0.000 302.00 328.00 3 4.3592e+00 3.9926e-03 3.2010e-02 -6.0000e+00 8.9656e-02 -4.8493e-03 4.6759e-03 1.9215e-02 -6.0000e+00 9.7347e-02 -3.7826e-03 3.5899e-03 9.2964e-03 -6.0000e+00 5.7939e-02 -4.1505e-03 1.8831e-03 3.7600e-03 -6.0000e+00 2.4487e-02 3.0500e-04 -4.8840e-04 8.1583e-05 3.4221e-05 -6.0000e+00 1.6951e-03 8.6410e-03 0.0000e+00 11 8 0 10 0 0 88.09 24.64 0.17 0.00864 0.00497 29 7 1 5 0 1652.120 27.26 20.00 24.64 24.35 34.9 781.13 -24767 -2808 10457 -17166 -9326 -23576 5523 -28418 4917 -12183 15704 -30295 -1277 -13583 12008 -7686 7986 -7618 8991 -9373 13061 -2311 8170 -4192 8132 -9562 5222 -12060 9429 -5489 4748 -2155 -1132 -2714 1210 -3395 -2099 -1851 -357 62 -1530 -1392 -456 2000 137 1059 -2991 1826 -2848 212 -762 539 44 2739 -524 3018 -1213 1788 -842 1749 -1169 2827 -353 2092 -193 1943 -281 1005 979 1079 1121 329 280 395 366 -204 -64 -1233 -399 -1594 239 -1610 -892 -2284 -792 -1398 496 -284 920 -170 1016 -143 1133 183 1565 -30 994 395 537 -762 -316 -501 272 -747 -554 -1101 -936 -746 -219 184 -62 360 -98 60 -8 236 -421 670 -650 -284 -584 381 -499 757 361 1233 391 1225 437 583 -164 486 -313 471 -56 64 52 205 -498 -256 -474 -150 -126 -642 -68 238 -506 -230 -630 119 -928 130 -412 424 -1306 -48 -698 574 -520 506 -603 643 -846 974 -200 649 -401 732 -1079 518 -1375 824 -560 480 -264 -154 -403 166 -469 -307 -314 -72 14 -406 -393 -133 584 41 318 -937 544 -894 66 -256 196 17 1119 -232 1324 -551 815 -386 771 -545 1367 -189 1198 -117 1094 -152 548 550 690 795 240 204 285 246 -124 -37 -684 -232 -1043 176 -1313 -783 -2140 -780 -1443 530 -316 1018 -185 1041 -137 988 158 1428 -31 1124 492 720 -1029 -400 -596 297 -837 -672 -1381 -1229 -1033 -313 284 -101 599 -161 95 -11 335 -599 986 -1006 -464 -969 613 -787 1165 530 1720 540 1701 647 916 -277 828 -554 864 -106 128 105 420 -1030 -525 -931 -288 -236
SS 20250522T133021.5Z 9273.562749 179 1 48.02 2 70.54 74.35 24.71 142.64 0.00 1 0.00 1 0 25 2.551e-02 5.435e-03 1.567e-02 1.904e-03 3.529803e-01 9.584799e-04 3.717742e-03 -6.000000e+00 1.457665e-02 228.47 -2.00 3.11 -2.00 318.93 0.00e+00 3.121768e-03 2.191433e-04 2.560781e-04 -6.000000e+00 6.407803e-04 282.02 -2.00 20.00 -2.00 318.22 0.00e+00 2.969 0.000 302.00 328.00 3 4.0559e+00 2.6431e-03 2.8107e-02 -6.0000e+00 3.6284e-02 -1.6181e-02 3.0420e-03 1.7056e-02 -6.0000e+00 3.9396e-02 4.5582e-03 2.1591e-03 8.2027e-03 -6.0000e+00 2.3448e-02 -6.7042e-03 1.1340e-03 3.8073e-03 -6.0000e+00 9.9107e-03 6.0153e-04 -2.5381e-04 5.5525e-05 3.3869e-05 -6.0000e+00 6.8600e-04 8.2681e-03 0.0000e+00 11 1 0 11 8 0 97.29 24.63 0.20 0.00827 0.00636 46 11 1 5 0 1043.750 27.26 20.00 24.63 24.81 34.9 781.17 -2336 3002 9502 -6313 -3519 -9477 -12285 -11159 -3504 -3797 -6816 -11325 -488 -3804 -1401 -1809 -513 -1276 -68 -913 -1383 -1036 1825 2301 3827 -277 2532 14 -707 1257 3917 3516 1188 -78 -3110 -2595 -2983 -98 -1030 -886 -1474 -783 -1678 -347 -1019 -66 -477 -915 -1465 273 334 859 -281 666 316 164 1045 846 628 372 377 1496 856 1757 616 433 331 170 1052 1152 177 164 -7 364 408 219 190 -1206 48 -700 -109 -1435 -1702 -1593 -1034 -730 -324 142 433 400 789 795 655 554 740 365 777 704 155 -258 -153 -514 -786 -355 -878 -1124 -940 -450 -328 89 148 310 -11 28 -173 143 -241 312 54 18 -534 -287 -151 212 590 712 744 696 753 645 323 139 -29 115 -188 19 50 23 -280 -42 -401 -308 -157 -77 108 342 -260 -131 -351 -484 -482 -157 -183 -342 -613 -27 -254 -109 -162 -49 -131 -7 -104 -163 -121 209 286 495 -38 352 2 -93 161 532 536 206 -14 -573 -457 -565 -20 -258 -263 -490 -274 -598 -129 -385 -25 -181 -345 -554 103 134 360 -127 318 158 84 542 440 321 189 197 832 528 1133 412 283 202 102 661 797 137 133 -6 285 297 148 117 -719 29 -496 -85 -1266 -1577 -1548 -1066 -782 -365 165 504 451 848 783 614 506 719 385 893 881 210 -348 -194 -615 -905 -402 -1085 -1434 -1253 -629 -472 138 238 511 -18 43 -255 198 -334 449 81 29 -872 -460 -235 323 853 1013 1007 953 1084 1009 524 234 -49 202 -342 37 99 44 -551 -82 -755 -571 -283
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