File name: Pandora142s1_MexicoCity-UNAM_20250522_L2Fit_fwvt1c13d20231028p1-8.txt
File generation date: 20250523T064006.5Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c13p1-8
Local principal investigator: Michel Grutter de la Mora
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 142
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora142_OF_v4d20200821.txt
Instrument calibration file used: Pandora142s1_CF_v13d20231028.txt
Level 1 file used: Pandora142s1_MexicoCity-UNAM_20250522_L1_smca1c13d20231028p1-8.txt
Full location name: Centro de Ciencias de la Atmosfera, UNAM
Short location name: MexicoCity-UNAM
Country of location: Mexico
Location latitude [deg]: 19.3262
Location longitude [deg]: -99.1761
Location altitude [m]: 2280
Local noon date: 20250522
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 12 "Modification of session 11 "Modification of session 10, but different Reference day.""
First and last pixel inside fitting window: 1653 1802
Nominal wavelengths inside fitting window [nm]: 492.0134 492.1348 492.2563 492.3777 492.4991 492.6205 492.7418 492.8632 492.9845 493.1058 493.2271 493.3484 493.4697 493.5909 493.7121 493.8334 493.9546 494.0757 494.1969 494.3180 494.4392 494.5603 494.6814 494.8025 494.9235 495.0446 495.1656 495.2866 495.4076 495.5286 495.6495 495.7705 495.8914 496.0123 496.1332 496.2541 496.3750 496.4958 496.6166 496.7374 496.8582 496.9790 497.0998 497.2205 497.3412 497.4619 497.5826 497.7033 497.8240 497.9446 498.0652 498.1858 498.3064 498.4270 498.5475 498.6681 498.7886 498.9091 499.0296 499.1501 499.2705 499.3910 499.5114 499.6318 499.7522 499.8725 499.9929 500.1132 500.2335 500.3538 500.4741 500.5944 500.7146 500.8349 500.9551 501.0753 501.1955 501.3156 501.4358 501.5559 501.6760 501.7961 501.9162 502.0363 502.1563 502.2763 502.3964 502.5163 502.6363 502.7563 502.8762 502.9962 503.1161 503.2360 503.3558 503.4757 503.5955 503.7154 503.8352 503.9549 504.0747 504.1945 504.3142 504.4339 504.5536 504.6733 504.7930 504.9126 505.0323 505.1519 505.2715 505.3911 505.5107 505.6302 505.7497 505.8693 505.9888 506.1082 506.2277 506.3471 506.4666 506.5860 506.7054 506.8248 506.9441 507.0635 507.1828 507.3021 507.4214 507.5407 507.6599 507.7792 507.8984 508.0176 508.1368 508.2560 508.3751 508.4942 508.6134 508.7325 508.8516 508.9706 509.0897 509.2087 509.3277 509.4467 509.5657 509.6847 509.8036 509.9226
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20250522T125832.7Z 9273.540656 168 1 48.36 2 77.73 72.33 29.95 129.92 0.00 1 0.00 1 0 15 4.298e-03 4.283e-03 7.260e-04 7.250e-04 4.543337e+03 4.716276e+01 3.001520e+02 -6.000000e+00 2.478718e+02 282.02 -2.00 20.00 -2.00 505.32 0.00e+00 2.307334e-03 2.031005e-05 1.261035e-04 -6.000000e+00 1.222894e-04 282.02 -2.00 20.00 -2.00 500.68 0.00e+00 2.753636e-01 1.450415e-02 4.175754e-02 -6.000000e+00 8.693553e-02 228.47 -2.00 3.11 -2.00 502.24 0.00e+00 4.576 0.000 489.00 513.00 1 6.6831e+00 1.1129e-03 6.7878e-03 -6.0000e+00 6.6822e-03 -4.2698e-02 2.8047e-04 9.1481e-04 -6.0000e+00 1.7083e-03 1.4028e-03 4.7334e-04 8.0129e-05 5.8413e-05 -6.0000e+00 4.9147e-04 6.6828e-03 -3.9627e-06 11 8 0 10 0 0 93.64 24.65 1.31 0.00668 0.00997 24 6 1 4 0 2014.890 27.26 20.00 24.65 23.84 34.9 780.94 -260 -498 -224 -87 -183 96 340 127 288 73 43 -53 -161 -314 -79 -78 -26 -43 299 42 163 235 318 414 464 405 242 -220 -132 -230 26 -11 -120 167 12 -187 -196 11 -33 -20 97 36 32 244 204 315 -74 39 -124 -228 -554 -350 -456 -253 -350 -126 -141 -215 -106 241 287 347 3864 -54 -11 -118 -118 -217 -400 -321 -310 -319 -170 -444 -450 -513 1025 -592 -332 -448 -389 -621 -169 -327 -340 -368 -265 -177 104 37 83 158 331 28 324 15 121 -216 -198 -355 -409 -204 -397 -264 -470 -370 -245 -130 -18 298 33 236 293 449 526 553 476 482 345 290 323 313 386 349 25 193 43 -130 30 310 -76 -191 75 -64 -253 -92 -376 -355 30 -48 185 69 200 -18 11 -149 -99 -325 -134 -218 -239 -464 -213 -85 -178 96 343 130 294 74 43 -52 -157 -303 -76 -75 -25 -42 303 43 169 243 330 431 466 408 244 -229 -134 -228 26 -10 -119 170 12 -191 -199 11 -33 -20 96 36 32 249 211 326 -77 40 -125 -225 -556 -343 -443 -248 -351 -124 -142 -220 -108 247 295 357 3857 -56 -11 -120 -118 -215 -393 -312 -299 -309 -166 -439 -448 -508 987 -571 -317 -427 -371 -599 -163 -320 -336 -367 -264 -176 103 37 83 162 328 28 330 15 119 -208 -187 -330 -381 -193 -388 -266 -466 -368 -242 -128 -17 292 32 238 299 463 546 577 500 507 361 300 329 316 387 352 25 197 44 -132 30 313 -76 -189 73 -62 -249 -92 -382 -354 31 -49 189 71 207 -19 11 -153 -100 -322 -136 -222
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SQ 20250522T132015.5Z 9273.555734 177 1 48.11 2 72.83 73.73 26.24 138.10 0.00 1 0.00 1 0 15 2.086e-03 2.089e-03 1.280e-04 1.279e-04 3.556934e+03 8.136083e+00 2.395770e+02 -6.000000e+00 1.203141e+02 282.02 -2.00 20.00 -2.00 505.30 0.00e+00 1.449266e-03 3.571821e-06 8.181585e-05 -6.000000e+00 5.935845e-05 282.02 -2.00 20.00 -2.00 500.63 0.00e+00 1.216156e-01 2.556618e-03 3.140568e-02 -6.000000e+00 4.219860e-02 228.47 -2.00 3.11 -2.00 502.19 0.00e+00 3.340 0.000 489.00 513.00 1 3.4072e+00 1.9604e-04 4.8940e-03 -6.0000e+00 3.2435e-03 -3.4890e-02 4.9638e-05 7.0551e-04 -6.0000e+00 8.2922e-04 4.3572e-02 1.3617e-04 1.4149e-05 4.0975e-05 -6.0000e+00 2.3855e-04 7.2283e-03 -9.3484e-06 10 0 0 10 0 0 97.95 24.64 0.93 0.00723 0.00817 590 146 1 4 0 81.520 27.26 20.00 24.64 24.38 34.9 781.15 -301 -186 -113 -16 -60 198 370 291 259 194 92 1 -102 -141 -74 -76 -58 29 113 -47 8 202 244 271 404 207 -8 -57 -104 -200 44 62 -17 91 -62 -319 -233 37 23 26 143 186 123 168 142 163 85 -36 -103 -202 -345 -211 -289 -235 -169 -179 -175 -84 59 239 306 362 118 164 128 44 -11 -69 -72 -75 -49 -96 -265 -215 -145 -326 -349 -247 -92 -225 -240 -311 -346 -220 -202 -281 -232 -36 44 86 72 105 171 16 85 64 -101 -157 -116 -150 -238 -330 -388 -362 -549 -508 -234 -24 112 214 124 92 220 367 393 481 471 345 223 328 348 273 288 332 134 140 235 51 37 178 -25 -20 120 -10 -52 57 -110 -262 -75 72 18 94 93 -38 -146 -132 -118 -158 -102 -183 -280 -174 -109 -16 -59 199 378 301 268 200 94 1 -101 -137 -72 -74 -58 29 116 -47 8 205 248 276 413 212 -8 -57 -107 -201 43 61 -17 90 -63 -330 -240 37 23 26 144 187 125 173 148 170 89 -37 -104 -199 -346 -207 -281 -230 -169 -177 -178 -86 61 246 315 373 122 169 131 45 -11 -68 -70 -73 -47 -92 -259 -212 -144 -322 -340 -237 -87 -214 -229 -299 -335 -215 -199 -280 -232 -36 44 86 73 104 171 16 84 64 -99 -152 -110 -140 -222 -314 -381 -353 -548 -509 -232 -23 109 211 124 93 225 379 408 486 478 350 226 338 354 275 288 334 135 142 238 51 38 179 -25 -20 116 -10 -51 56 -111 -259 -75 73 18 96 96 -39 -150 -134 -118 -155 -102 -184
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