File name: Pandora142s1_MexicoCity-UNAM_20250525_L2Fit_fout2c13d20231028p1-8.txt
File generation date: 20250526T064410.7Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c13p1-8
Local principal investigator: Michel Grutter de la Mora
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 142
Spectrometer number: 1
Processing software version used: BlickP v1.8.75
Instrument operation file used: Pandora142_OF_v4d20200821.txt
Instrument calibration file used: Pandora142s1_CF_v13d20231028.txt
Level 1 file used: Pandora142s1_MexicoCity-UNAM_20250525_L1_smca1c13d20231028p1-8.txt
Full location name: Centro de Ciencias de la Atmosfera, UNAM
Short location name: MexicoCity-UNAM
Country of location: Mexico
Location latitude [deg]: 19.3262
Location longitude [deg]: -99.1761
Location altitude [m]: 2280
Local noon date: 20250525
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: Modification of session 12 "Modification of session 11 "Modification of session 10, but different Reference day.""
First and last pixel inside fitting window: 236 378
Nominal wavelengths inside fitting window [nm]: 305.0157 305.1568 305.2979 305.4390 305.5801 305.7212 305.8622 306.0033 306.1443 306.2853 306.4263 306.5673 306.7083 306.8493 306.9903 307.1312 307.2722 307.4131 307.5540 307.6949 307.8358 307.9767 308.1176 308.2585 308.3993 308.5402 308.6810 308.8218 308.9626 309.1034 309.2442 309.3850 309.5258 309.6665 309.8073 309.9480 310.0887 310.2294 310.3701 310.5108 310.6515 310.7922 310.9328 311.0735 311.2141 311.3547 311.4953 311.6359 311.7765 311.9171 312.0577 312.1982 312.3388 312.4793 312.6198 312.7603 312.9008 313.0413 313.1818 313.3222 313.4627 313.6031 313.7436 313.8840 314.0244 314.1648 314.3052 314.4455 314.5859 314.7263 314.8666 315.0069 315.1472 315.2875 315.4278 315.5681 315.7084 315.8487 315.9889 316.1291 316.2694 316.4096 316.5498 316.6900 316.8302 316.9703 317.1105 317.2506 317.3908 317.5309 317.6710 317.8111 317.9512 318.0913 318.2314 318.3714 318.5115 318.6515 318.7915 318.9315 319.0715 319.2115 319.3515 319.4915 319.6314 319.7714 319.9113 320.0512 320.1911 320.3310 320.4709 320.6108 320.7506 320.8905 321.0303 321.1702 321.3100 321.4498 321.5896 321.7294 321.8691 322.0089 322.1486 322.2884 322.4281 322.5678 322.7075 322.8472 322.9869 323.1266 323.2662 323.4059 323.5455 323.6851 323.8247 323.9643 324.1039 324.2435 324.3831 324.5226 324.6622 324.8017 324.9412
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20250525T131706.9Z 9276.553552 104 1 48.12 2 73.46 72.96 52.74 80.46 0.00 1 0.00 1 0 25 3.361e-02 4.902e-03 1.191e-02 9.909e-04 4.111505e-01 4.981361e-04 4.241836e-03 -6.000000e+00 1.917312e-02 228.36 -2.00 3.11 -2.00 319.40 0.00e+00 9.814296e-04 1.334926e-04 1.752633e-04 -6.000000e+00 8.441480e-04 282.12 -2.00 20.00 -2.00 318.71 0.00e+00 3.460 0.000 302.00 328.00 3 2.3170e+00 1.3961e-03 3.2545e-02 -6.0000e+00 4.7709e-02 -3.2587e-03 1.6396e-03 1.9009e-02 -6.0000e+00 5.1837e-02 5.9723e-03 1.2614e-03 9.3579e-03 -6.0000e+00 3.0855e-02 -9.3331e-03 6.6187e-04 2.8789e-03 -6.0000e+00 1.3018e-02 2.2047e-03 -1.2256e-04 2.8613e-05 2.9661e-05 -6.0000e+00 9.0421e-04 2.1207e-02 0.0000e+00 11 1 0 11 8 0 99.85 23.77 0.21 0.02121 0.02029 182 45 1 5 0 264.320 26.51 20.00 23.77 23.32 34.6 780.67 -15852 -8320 -12389 -8304 -11837 -12681 -14626 -5918 -6696 -11264 -5138 -10474 -3108 -5090 796 -2425 -330 -235 391 -1765 407 -1079 1145 -1604 922 -2321 -458 -2689 164 -1476 1161 166 301 -1070 -1928 -2812 -1975 -1298 -816 -958 -2100 -1617 -1456 -521 -725 163 -958 -133 -1071 -48 457 1037 970 1274 676 1105 251 820 284 726 905 1445 1293 1513 326 483 -41 342 609 922 719 458 258 392 168 24 -75 -66 75 -541 -595 -1211 -1379 -1618 -947 -758 -269 -110 560 282 768 553 822 642 769 273 601 304 8 -425 -347 -683 -387 -308 -885 -920 -932 -649 -137 85 120 194 107 59 -2 369 76 365 -78 -176 -506 78 -217 300 305 721 856 820 527 642 184 200 -122 157 -110 -182 44 -93 -194 -184 -283 -109 -210 -371 -207 -342 -214 -286 -295 -369 -155 -201 -382 -167 -380 -122 -246 43 -158 -23 -17 31 -149 35 -93 99 -154 92 -253 -50 -287 16 -149 126 21 42 -160 -278 -398 -302 -231 -160 -224 -555 -452 -423 -153 -214 48 -287 -39 -322 -15 150 370 373 523 292 490 115 374 127 320 410 705 700 893 199 279 -23 187 356 614 529 353 199 289 115 15 -42 -36 44 -365 -459 -1053 -1189 -1473 -916 -784 -291 -123 622 302 759 503 759 588 697 280 694 395 11 -589 -449 -808 -426 -347 -1088 -1195 -1269 -932 -193 129 197 325 175 91 -4 540 112 518 -119 -283 -822 123 -334 439 461 1038 1177 1156 815 999 306 347 -218 294 -204 -356 88 -190 -395 -363 -532 -210 -397
SS 20250525T132807.4Z 9276.561197 107 1 7.84 2 70.98 73.63 50.24 80.95 0.00 1 0.00 1 0 17 4.395e-02 9.703e-03 3.666e-02 6.229e-03 3.605695e-01 3.127058e-03 3.808496e-03 -6.000000e+00 2.506861e-02 228.36 -2.00 3.11 -2.00 318.08 0.00e+00 1.105566e-03 5.689730e-04 2.070091e-04 -6.000000e+00 1.103650e-03 282.12 -2.00 20.00 -2.00 317.37 0.00e+00 3.033 0.000 302.00 328.00 3 4.6984e+00 8.4007e-03 2.8551e-02 -6.0000e+00 6.2379e-02 1.4599e-02 9.5371e-03 1.6713e-02 -6.0000e+00 6.7775e-02 1.0079e-02 6.2289e-03 8.1218e-03 -6.0000e+00 4.0342e-02 -1.0795e-02 3.2318e-03 2.5252e-03 -6.0000e+00 1.7022e-02 2.9530e-04 -7.4300e-05 1.7553e-04 2.5949e-05 -6.0000e+00 1.1821e-03 2.0608e-02 0.0000e+00 12 9 9 12 1 1 999.00 23.76 0.24 0.02061 0.02005 2 4 1 5 0 2611.110 26.51 19.99 23.76 23.83 34.6 780.84 -3874 6781 23132 573 14516 2982 3103 -18462 12951 1689 -4238 -23112 5914 -14249 10500 1918 2484 -1007 -2654 -7342 2114 2486 -704 1955 5703 5091 -3304 -2858 670 2928 1314 3716 -5189 -4452 -2384 3788 -2586 1233 -1141 -138 -2509 1939 -610 -1226 48 -291 -2455 -875 -2055 2643 -17 1001 -947 1467 896 105 970 1507 826 -83 -1024 1939 975 2205 -596 643 587 -1468 2165 823 2101 1224 855 -1189 -1251 -1640 2226 -1209 -693 -2145 -797 -969 -1605 -1131 -1216 -1509 -156 1166 159 1768 -69 480 567 764 273 -346 236 882 498 -377 -312 477 -348 -437 -1956 -1232 -71 -376 -598 183 249 222 -67 19 -263 -368 40 753 -788 359 -759 157 -428 424 112 187 858 3763 744 -91 208 141 98 214 -126 -543 96 -98 174 -380 -169 -239 -643 -200 359 1097 33 651 143 156 -1299 751 118 -317 -2106 479 -1626 1104 251 348 -150 -425 -1287 347 405 -121 349 1046 985 -704 -579 123 544 262 806 -1324 -1189 -593 885 -678 364 -405 -56 -1124 879 -287 -591 23 -140 -1201 -417 -989 1237 -9 539 -542 873 559 66 619 955 516 -53 -662 1315 701 1697 -469 480 422 -1060 1613 675 1833 1102 771 -1050 -1046 -1294 1611 -872 -514 -1762 -718 -934 -1639 -1183 -1335 -1746 -184 1399 190 2072 -78 503 573 756 285 -390 286 1144 668 -502 -404 580 -407 -526 -2495 -1616 -95 -521 -866 274 390 350 -105 28 -374 -514 56 1067 -1172 550 -1167 238 -646 618 159 257 1139 5037 1055 -136 324 224 157 352 -218 -957 172 -178 314 -678 -291 -408 -1082
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