File name: Pandora157s1_MexicoCity-Vallejo_20200110_L2Fit_fwvt1c6d20191023p1-8.txt File generation date: 20240926T180237.7Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c6p1-8 Local principal investigator: Michel Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 157 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora157_OF_v4d20190315.txt Instrument calibration file used: Pandora157s1_CF_v6d20191023.txt Level 1 file used: Pandora157s1_MexicoCity-Vallejo_20200110_L1_smca1c6d20191023p1-8.txt Full location name: Vallejo, Secretaria de Medio Ambiente, SEDEMA Short location name: MexicoCity-Vallejo Country of location: Mexico Location latitude [deg]: 19.4830 Location longitude [deg]: -99.1470 Location altitude [m]: 2255 Local noon date: 20200110 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Update on session 3 based on session 2 for SO2 First and last pixel inside fitting window: 1646 1796 Nominal wavelengths inside fitting window [nm]: 492.0156 492.1362 492.2568 492.3773 492.4979 492.6184 492.7389 492.8594 492.9798 493.1003 493.2207 493.3411 493.4615 493.5819 493.7023 493.8226 493.9430 494.0633 494.1836 494.3039 494.4241 494.5444 494.6646 494.7848 494.9050 495.0252 495.1454 495.2655 495.3856 495.5058 495.6259 495.7459 495.8660 495.9861 496.1061 496.2261 496.3461 496.4661 496.5860 496.7060 496.8259 496.9458 497.0657 497.1856 497.3055 497.4253 497.5452 497.6650 497.7848 497.9045 498.0243 498.1440 498.2638 498.3835 498.5032 498.6229 498.7425 498.8622 498.9818 499.1014 499.2210 499.3406 499.4601 499.5797 499.6992 499.8187 499.9382 500.0577 500.1771 500.2965 500.4160 500.5354 500.6548 500.7741 500.8935 501.0128 501.1321 501.2514 501.3707 501.4900 501.6092 501.7285 501.8477 501.9669 502.0861 502.2052 502.3244 502.4435 502.5626 502.6817 502.8008 502.9198 503.0389 503.1579 503.2769 503.3959 503.5149 503.6338 503.7528 503.8717 503.9906 504.1095 504.2283 504.3472 504.4660 504.5848 504.7036 504.8224 504.9412 505.0599 505.1787 505.2974 505.4161 505.5347 505.6534 505.7720 505.8907 506.0093 506.1278 506.2464 506.3650 506.4835 506.6020 506.7205 506.8390 506.9575 507.0759 507.1943 507.3128 507.4311 507.5495 507.6679 507.7862 507.9045 508.0228 508.1411 508.2594 508.3777 508.4959 508.6141 508.7323 508.8505 508.9686 509.0868 509.2049 509.3230 509.4411 509.5592 509.6772 509.7953 509.9133 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Azimuth motor temperature [°C], 999=no temperature signal Column 100: Humidity in head sensor [%], -9=no humidity signal Column 101: Pressure in head sensor [hPa], -9=no pressure signal Columns 102-252: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 253-403: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SO 20200110T131813.0Z 7314.554317 232 1 32.01 2 89.69 113.51 93.77 295.81 0.00 1 0.00 1 0 62 1.242e-01 1.168e-01 1.268e-01 1.227e-01 -3.449598e+03 6.763653e+03 1.015541e+03 -6.000000e+00 6.672411e+03 279.56 -2.00 20.00 -2.00 505.18 0.00e+00 2.266945e-03 3.328652e-03 1.050658e-04 -6.000000e+00 3.425050e-03 279.56 -2.00 20.00 -2.00 500.18 0.00e+00 1.707264e+00 2.405361e+00 1.288556e-01 -6.000000e+00 2.422612e+00 223.38 -2.00 3.11 -2.00 501.79 0.00e+00 20.358 0.039 489.00 513.00 1 1.0302e+01 1.8358e-01 2.4519e-02 -6.0000e+00 1.8545e-01 1.0126e-01 4.7946e-02 1.7885e-03 -6.0000e+00 4.8280e-02 5.9947e-06 4.4954e-03 1.1625e-02 2.0607e-04 -6.0000e+00 1.1743e-02 -7.8243e-02 7.2287e-04 12 8 8 10 0 0 19.20 18.01 12.30 -0.07824 -0.04706 8 2 1 7 0 4000.000 20.67 15.00 18.01 18.61 30.80 23.2 783.06 -8326 17011 -9310 22645 8898 1945 -22 -3038 2358 15471 -21527 -8188 -336 27751 14618 11868 -2986 18112 -4434 -5881 3074 3636 -1490 5761 30504 -14025 27465 26906 -152 -5154 16462 -8644 24099 14143 4755 -26018 7881 17388 -13276 2287 -1625 -7650 -211 -667 -8536 -4204 -4191 -9771 15703 -7106 2448 -7600 276 -4970 11903 -2549 -12817 -5077 13270 -3682 11159 6110 -1416 -5217 -4361 26256 11226 6559 -5623 7535 18977 7096 -9615 15484 1908 -8652 3924 30435 -6722 6184 -11399 462 6187 -20044 -1559 -24655 3629 6967 -15671 -4586 -3494 34232 -11220 1868 -15195 -1539 14563 -6950 -9492 12780 -5815 -5601 37431 -1220 -11252 -1417 11837 -5068 9765 11614 -10933 452 -215 16622 9876 13659 -8190 12995 14622 6229 14997 -7 6426 185 6148 10236 12460 23347 -2507 6405 -3773 16474 -629 -4563 -13068 2009 -1545 -19015 3498 -17866 -10244 826 4855 10675 9275 -3824 -27 12944 -106 13814 1250 -8774 14274 -10369 19118 8850 2103 -25 -3542 2596 14736 -29001 -9512 -355 22009 13139 10934 -3241 16318 -5092 -6933 3319 3904 -1685 6084 25467 -18047 23394 22759 -163 -5616 14271 -9592 19838 13238 5000 -37241 8025 16000 -16170 2382 -1749 -8814 -229 -734 -10200 -4857 -4783 -11637 14329 -7887 2411 -8006 265 -5069 10607 -2692 -15255 -5651 12374 -4027 10516 6086 -1526 -5797 -4765 21090 10233 6171 -5858 6832 15186 6356 -10204 13045 1858 -9259 3664 21537 -6730 5423 -11961 434 5525 -23255 -1517 -30250 3387 6291 -17640 -4670 -3547 24340 -12630 1867 -17924 -1583 12603 -7301 -9891 10473 -5672 -5454 24560 -1197 -12432 -1414 10177 -5062 8311 9738 -11600 437 -214 14304 9129 12233 -9086 11698 12810 5841 12693 -6 5802 179 5637 9028 10748 18156 -2489 5858 -3781 13380 -591 -4386 -13558 1804 -1467 -21844 3260 -20694 -11047 798 4530 9456 8364 -3889 -26 10717 -98 10992 1128 SO 20200110T132215.0Z 7314.557118 236 1 32.01 2 88.82 113.85 94.59 296.16 0.00 1 0.00 1 0 15 6.867e-02 6.641e-02 7.199e-02 7.115e-02 1.124801e+03 4.012652e+03 6.359245e+01 -6.000000e+00 3.689091e+03 279.56 -2.00 20.00 -2.00 505.30 0.00e+00 4.192293e-03 1.929883e-03 1.818553e-04 -6.000000e+00 1.894755e-03 279.56 -2.00 20.00 -2.00 500.46 0.00e+00 1.172007e+00 1.381858e+00 4.650526e-02 -6.000000e+00 1.342817e+00 223.38 -2.00 3.11 -2.00 502.05 0.00e+00 18.532 0.029 489.00 513.00 1 9.9522e+00 1.0552e-01 2.1390e-02 -6.0000e+00 1.0274e-01 5.5667e-02 2.7368e-02 1.2818e-03 -6.0000e+00 2.6835e-02 1.0549e-05 3.0095e-04 6.6577e-03 5.9199e-05 -6.0000e+00 6.4970e-03 -1.8002e-02 1.6571e-04 12 9 8 11 8 0 -91.33 18.02 7.25 -0.01800 -0.01591 8 2 1 7 0 4000.000 20.67 15.00 18.02 18.76 30.80 23.3 783.04 -5799 7024 -2007 6907 -2587 1279 -5551 -1269 -13248 13492 -4599 -1282 -1744 -13019 -2899 3428 2879 -2021 2523 180 16 8813 12653 8278 -3567 4422 -7629 -4749 7846 9233 978 2102 4766 -3836 7261 -8798 2363 -10628 5172 17583 4625 385 1680 -2377 -2557 -2998 5662 -5370 3690 -6246 9928 -9840 3656 -4850 12105 4527 -8459 9433 3330 6793 -3775 -2510 -1968 -5825 260 9806 4947 4338 4456 5939 1218 -3709 -1820 -4232 4424 1983 -13494 25660 -1640 5571 -469 11682 554 -3331 -2358 1009 -4249 -4029 2067 2748 3694 2070 2602 -4758 -421 345 -6357 18803 -11536 798 6330 -10583 409 5378 3805 -1589 -798 -2947 799 -5042 6202 -3809 -1293 8464 -4623 16589 509 -6380 1832 -4640 4818 -7455 9993 1463 11806 1720 5012 -6692 9580 -3394 1371 4466 -3140 10891 -3767 -4226 -9850 -10051 877 5762 1376 12243 -13784 3131 5608 -288 -5426 4882 3321 255 -7579 -5649 6080 -1946 6363 -2703 1315 -6192 -1373 -16171 12563 -5011 -1331 -1791 -14637 -2939 3262 2784 -2082 2549 189 17 8547 11820 8109 -3934 4526 -8802 -5284 7544 8476 948 2005 4490 -4042 7095 -10205 2462 -12384 5120 15244 4530 396 1730 -2587 -2807 -3332 5771 -6059 3748 -6861 9022 -10594 3378 -4874 10483 4372 -9516 9030 3404 6698 -4105 -2707 -2124 -6553 274 9287 4840 4204 4258 5519 1172 -3709 -1797 -4333 4207 1937 -15096 19295 -1585 4977 -442 9871 524 -3291 -2327 971 -4301 -4067 1959 2586 3462 1995 2540 -5043 -428 345 -6691 15162 -12196 728 5398 -10609 374 4833 3584 -1589 -788 -2926 753 -5031 5604 -3884 -1312 7929 -4963 14615 526 -7103 1874 -4979 4659 -7980 8949 1418 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