File name: Pandora157s1_MexicoCity-Vallejo_20230630_L2Fit_fout2c1d20210802p1-8.txt
File generation date: 20230705T121111.9Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c1p1-8
Local principal investigator: Michel Grutter
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 157
Spectrometer number: 1
Processing software version used: BlickP v1.8.49
Instrument operation file used: Pandora157_OF_v5d20190315.txt
Instrument calibration file used: Pandora157s1_CF_v1d20210802.txt
Level 1 file used: Pandora157s1_MexicoCity-Vallejo_20230630_L1_smca1c1d20210802p1-8.txt
Full location name: Vallejo, Secretaria de Medio Ambiente, SEDEMA
Short location name: MexicoCity-Vallejo
Country of location: Mexico
Location latitude [deg]: 19.4830
Location longitude [deg]: -99.1470
Location altitude [m]: 2255
Local noon date: 20230630
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 221 363
Nominal wavelengths inside fitting window [nm]: 305.0872 305.2277 305.3682 305.5086 305.6490 305.7894 305.9298 306.0702 306.2106 306.3510 306.4914 306.6317 306.7721 306.9124 307.0527 307.1930 307.3333 307.4736 307.6139 307.7542 307.8944 308.0347 308.1749 308.3151 308.4553 308.5955 308.7357 308.8759 309.0161 309.1563 309.2964 309.4365 309.5767 309.7168 309.8569 309.9970 310.1371 310.2771 310.4172 310.5573 310.6973 310.8373 310.9773 311.1173 311.2573 311.3973 311.5373 311.6773 311.8172 311.9572 312.0971 312.2370 312.3769 312.5168 312.6567 312.7966 312.9364 313.0763 313.2161 313.3560 313.4958 313.6356 313.7754 313.9152 314.0550 314.1947 314.3345 314.4742 314.6139 314.7537 314.8934 315.0331 315.1728 315.3124 315.4521 315.5917 315.7314 315.8710 316.0106 316.1502 316.2898 316.4294 316.5690 316.7086 316.8481 316.9877 317.1272 317.2667 317.4062 317.5457 317.6852 317.8247 317.9641 318.1036 318.2430 318.3825 318.5219 318.6613 318.8007 318.9401 319.0794 319.2188 319.3581 319.4975 319.6368 319.7761 319.9154 320.0547 320.1940 320.3333 320.4725 320.6118 320.7510 320.8902 321.0294 321.1686 321.3078 321.4470 321.5862 321.7253 321.8645 322.0036 322.1427 322.2818 322.4209 322.5600 322.6991 322.8382 322.9772 323.1163 323.2553 323.3943 323.5333 323.6723 323.8113 323.9503 324.0892 324.2282 324.3671 324.5060 324.6449 324.7838 324.9227
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20230630T130940.3Z 8581.548383 150 1 49.56 2 75.99 70.02 143.59 258.66 0.00 1 0.00 1 0 25 7.583e-02 5.007e-03 1.190e-02 6.522e-04 4.699155e-01 3.449817e-04 4.827637e-03 -6.000000e+00 4.544382e-02 227.13 -2.00 3.11 -2.00 319.97 0.00e+00 8.439320e-03 1.140363e-04 4.092367e-04 -6.000000e+00 2.011782e-03 282.83 -2.00 20.00 -2.00 319.32 0.00e+00 4.044 0.000 302.00 328.00 3 4.4115e-01 1.0071e-03 3.8450e-02 -6.0000e+00 1.1260e-01 3.4399e-02 1.2136e-03 2.4869e-02 -6.0000e+00 1.2206e-01 -3.0063e-02 1.0075e-03 1.2876e-02 -6.0000e+00 7.2780e-02 3.3641e-03 5.1689e-04 1.0047e-02 -6.0000e+00 3.0609e-02 8.3865e-03 -7.1865e-04 2.0720e-05 9.2587e-05 -6.0000e+00 2.3378e-03 6.2914e-03 -3.8140e-05 11 1 0 11 8 0 89.87 18.96 0.25 0.00629 0.00089 517 107 1 8 0 95.840 21.38 15.00 18.96 29.09 21.0 782.77 -22169 -25089 -25141 -24001 -27414 -22885 -27448 -21346 -30205 -24323 -27276 -16032 -13742 -6841 -4829 -6567 -4880 -1755 39 -1271 -916 481 -2526 65 -2906 -2924 -5371 -3607 -4786 -1008 -349 187 1614 -2032 -2166 -2845 -2434 -1529 -218 -1898 -1476 -1007 -513 -622 -635 129 97 162 -70 858 2020 1402 1565 938 1025 959 585 -327 114 490 825 1374 1479 1409 548 357 313 504 1627 1071 749 105 174 -28 44 -304 -235 -278 -230 -288 -990 -1043 -1803 -1513 -986 -661 -274 47 158 266 730 732 655 822 870 569 567 430 28 -430 -401 -542 74 436 -514 -1133 -816 -713 -232 56 27 -111 -83 141 236 520 651 299 -91 -495 -621 -360 -12 191 589 384 558 956 863 183 81 -229 -122 106 -9 -130 -48 -17 -146 -170 -25 -185 -37 -324 -429 -449 -409 -452 -351 -461 -368 -613 -486 -590 -352 -364 -212 -179 -288 -234 -89 2 -71 -52 27 -150 4 -188 -194 -366 -239 -324 -71 -28 17 162 -220 -230 -306 -285 -207 -35 -353 -302 -199 -106 -133 -139 29 22 37 -16 211 531 405 486 311 353 339 210 -118 40 174 306 556 664 686 277 176 149 243 838 620 473 69 114 -18 25 -161 -115 -137 -122 -176 -695 -819 -1545 -1374 -869 -618 -268 47 158 256 718 669 566 713 814 552 624 529 37 -573 -505 -627 80 473 -594 -1398 -1058 -979 -342 82 42 -182 -134 219 373 781 973 465 -139 -791 -1005 -570 -18 304 896 561 789 1369 1335 289 138 -411 -228 207 -19 -263 -99 -36 -308 -352 -52 -377 -74
SS 20230630T132045.2Z 8581.556078 153 1 49.54 2 73.53 70.70 146.02 258.81 0.00 1 0.00 1 0 25 3.684e-02 5.216e-03 5.075e-03 4.702e-04 4.068991e-01 2.487553e-04 4.271675e-03 -6.000000e+00 2.207609e-02 227.13 -2.00 3.11 -2.00 319.31 0.00e+00 4.578079e-03 6.578379e-05 1.706739e-04 -6.000000e+00 9.772922e-04 282.83 -2.00 20.00 -2.00 318.63 0.00e+00 3.474 0.000 302.00 328.00 3 4.0202e-01 6.9417e-04 3.2711e-02 -6.0000e+00 5.4702e-02 2.3764e-02 8.0715e-04 1.9670e-02 -6.0000e+00 5.9296e-02 -1.5916e-02 5.9968e-04 9.8414e-03 -6.0000e+00 3.5356e-02 -1.7552e-03 3.1235e-04 5.3070e-03 -6.0000e+00 1.4870e-02 1.4542e-02 -5.9697e-04 1.5129e-05 5.5877e-05 -6.0000e+00 1.1356e-03 6.0114e-03 -4.4909e-05 10 0 0 10 0 0 47.20 18.96 0.27 0.00601 0.00153 710 147 1 8 0 69.760 21.38 15.00 18.96 30.94 20.9 782.70 -11241 -11775 -8769 -12857 -16004 -13081 -13905 -7424 -13578 -10257 -12624 -6463 -6406 -4386 -1791 -1789 -761 -1215 545 -643 296 -856 127 -940 -1504 -1385 -3765 -2084 -2825 -282 -265 705 588 -1738 -2399 -2500 -1710 -1560 -63 -1033 -1075 -993 -830 -519 -201 -105 -391 65 -124 740 1310 1223 1400 1165 1019 901 801 31 526 535 1158 1646 1552 1258 346 75 279 528 1442 1042 259 -77 52 -133 -82 -501 20 -254 3 -379 -958 -1177 -1865 -1389 -1043 -849 -392 34 135 252 573 656 715 875 936 602 602 352 -5 -580 -513 -624 -17 398 -610 -1098 -797 -738 -193 170 139 -30 24 145 293 535 715 348 65 -334 -589 -293 1 234 536 474 583 1022 834 178 146 -221 -203 114 3 -147 -91 10 -171 -156 -82 -190 -124 -294 -345 -257 -374 -448 -348 -395 -219 -463 -354 -464 -247 -291 -237 -112 -127 -58 -100 47 -58 27 -79 12 -94 -159 -151 -418 -221 -299 -30 -32 94 86 -269 -365 -383 -284 -304 -14 -249 -285 -280 -243 -155 -61 -32 -120 20 -39 238 449 454 558 492 448 407 367 14 238 242 543 833 864 753 212 45 158 300 875 708 193 -60 40 -98 -56 -313 12 -144 2 -262 -756 -1035 -1634 -1285 -1024 -886 -429 38 150 272 576 609 623 826 866 624 702 456 -7 -746 -675 -758 -19 457 -749 -1438 -1096 -988 -275 260 227 -50 40 228 430 746 987 500 99 -536 -962 -470 2 350 764 701 832 1468 1185 276 243 -386 -368 215 6 -286 -184 20 -351 -313 -157 -351 -223
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