File name: Pandora157s1_MexicoCity-Vallejo_20230704_L2Fit_fout2c1d20210802p1-8.txt
File generation date: 20230708T025504.5Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c1p1-8
Local principal investigator: Michel Grutter
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 157
Spectrometer number: 1
Processing software version used: BlickP v1.8.49
Instrument operation file used: Pandora157_OF_v5d20190315.txt
Instrument calibration file used: Pandora157s1_CF_v1d20210802.txt
Level 1 file used: Pandora157s1_MexicoCity-Vallejo_20230704_L1_smca1c1d20210802p1-8.txt
Full location name: Vallejo, Secretaria de Medio Ambiente, SEDEMA
Short location name: MexicoCity-Vallejo
Country of location: Mexico
Location latitude [deg]: 19.4830
Location longitude [deg]: -99.1470
Location altitude [m]: 2255
Local noon date: 20230704
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 221 363
Nominal wavelengths inside fitting window [nm]: 305.0872 305.2277 305.3682 305.5086 305.6490 305.7894 305.9298 306.0702 306.2106 306.3510 306.4914 306.6317 306.7721 306.9124 307.0527 307.1930 307.3333 307.4736 307.6139 307.7542 307.8944 308.0347 308.1749 308.3151 308.4553 308.5955 308.7357 308.8759 309.0161 309.1563 309.2964 309.4365 309.5767 309.7168 309.8569 309.9970 310.1371 310.2771 310.4172 310.5573 310.6973 310.8373 310.9773 311.1173 311.2573 311.3973 311.5373 311.6773 311.8172 311.9572 312.0971 312.2370 312.3769 312.5168 312.6567 312.7966 312.9364 313.0763 313.2161 313.3560 313.4958 313.6356 313.7754 313.9152 314.0550 314.1947 314.3345 314.4742 314.6139 314.7537 314.8934 315.0331 315.1728 315.3124 315.4521 315.5917 315.7314 315.8710 316.0106 316.1502 316.2898 316.4294 316.5690 316.7086 316.8481 316.9877 317.1272 317.2667 317.4062 317.5457 317.6852 317.8247 317.9641 318.1036 318.2430 318.3825 318.5219 318.6613 318.8007 318.9401 319.0794 319.2188 319.3581 319.4975 319.6368 319.7761 319.9154 320.0547 320.1940 320.3333 320.4725 320.6118 320.7510 320.8902 321.0294 321.1686 321.3078 321.4470 321.5862 321.7253 321.8645 322.0036 322.1427 322.2818 322.4209 322.5600 322.6991 322.8382 322.9772 323.1163 323.2553 323.3943 323.5333 323.6723 323.8113 323.9503 324.0892 324.2282 324.3671 324.5060 324.6449 324.7838 324.9227
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20230704T140601.4Z 8585.587516 257 1 50.02 2 63.62 73.47 102.41 246.76 0.00 1 0.00 1 0 25 1.240e-02 5.728e-03 4.508e-03 1.157e-03 2.762048e-01 6.049615e-04 2.970341e-03 -6.000000e+00 7.434354e-03 227.00 -2.00 3.11 -2.00 317.83 0.00e+00 3.625349e-03 1.010903e-04 2.221771e-04 -6.000000e+00 3.290920e-04 282.80 -2.00 20.00 -2.00 317.10 0.00e+00 2.238 0.000 302.00 328.00 3 3.2507e+00 1.6081e-03 2.1493e-02 -6.0000e+00 1.8416e-02 3.0455e-02 1.8135e-03 1.3674e-02 -6.0000e+00 1.9960e-02 -1.6187e-03 1.1142e-03 6.4143e-03 -6.0000e+00 1.1903e-02 -6.4003e-03 5.5456e-04 3.5497e-03 -6.0000e+00 5.0110e-03 2.5342e-03 -4.1834e-05 3.7436e-05 3.7475e-05 -6.0000e+00 3.8230e-04 3.5170e-03 3.1859e-05 11 1 0 11 8 0 99.58 18.97 0.38 0.00352 0.00320 67 14 1 8 0 746.410 21.38 15.00 18.97 29.29 21.4 784.04 -2443 -4673 -2666 -7761 -687 -2733 3708 -1134 -2904 -2182 -1439 95 -1727 193 -991 -549 22 876 136 -332 1077 -406 1472 1078 785 -542 -1074 -944 454 1253 367 1930 1520 -203 -2599 -521 -890 -103 -379 -1243 -793 -1195 -177 -1243 -363 -513 -1224 -132 -367 1103 838 1067 498 1270 425 714 853 259 706 751 1491 1365 1375 639 41 -198 -121 140 1129 811 -126 -30 31 -189 -206 -478 38 -374 533 -359 -497 -1569 -1691 -1339 -959 -648 -462 -7 -104 177 409 744 605 1133 1205 471 645 239 32 -682 -463 -576 13 239 -418 -1036 -897 -599 -313 234 274 52 -19 24 247 384 852 247 18 -427 -670 -407 75 295 596 696 475 1207 924 478 180 -171 31 69 100 -181 23 -36 -179 -308 -310 -143 -299 -214 -453 -256 -737 -56 -218 291 -103 -288 -222 -147 10 -214 27 -162 -99 4 172 28 -71 229 -88 316 241 183 -131 -257 -217 99 273 86 486 411 -57 -718 -141 -262 -34 -147 -541 -374 -595 -90 -648 -189 -268 -635 -66 -184 553 442 599 298 788 266 454 547 166 458 488 998 957 1042 500 33 -151 -87 99 834 666 -110 -27 28 -165 -172 -364 27 -258 380 -280 -434 -1482 -1714 -1393 -1057 -740 -555 -8 -127 210 463 789 594 1107 1201 519 767 305 42 -904 -593 -702 15 280 -524 -1353 -1228 -836 -459 354 435 85 -30 36 353 518 1129 342 26 -650 -1050 -633 112 437 839 956 626 1579 1274 692 269 -265 49 110 169 -313 41 -65 -329 -558 -543 -246 -506
SS 20230704T141205.5Z 8585.591730 260 1 49.41 2 62.25 73.77 103.66 247.14 0.00 1 0.00 1 0 25 1.063e-02 5.786e-03 3.438e-03 9.864e-04 2.642060e-01 5.157758e-04 2.848835e-03 -6.000000e+00 6.369888e-03 227.00 -2.00 3.11 -2.00 317.61 0.00e+00 3.238773e-03 8.116109e-05 2.073406e-04 -6.000000e+00 2.819992e-04 282.80 -2.00 20.00 -2.00 316.88 0.00e+00 2.137 0.000 302.00 328.00 3 3.0651e+00 1.3649e-03 2.0515e-02 -6.0000e+00 1.5779e-02 2.9147e-02 1.5364e-03 1.2945e-02 -6.0000e+00 1.7103e-02 2.1469e-04 9.3233e-04 6.0972e-03 -6.0000e+00 1.0199e-02 -6.8973e-03 4.5887e-04 3.1711e-03 -6.0000e+00 4.2930e-03 3.3626e-03 -2.3027e-04 3.1850e-05 3.3899e-05 -6.0000e+00 3.2764e-04 3.9996e-03 7.1085e-06 11 1 0 11 8 0 97.56 18.97 0.25 0.00400 0.00227 90 19 1 8 0 548.820 21.38 15.00 18.97 29.74 21.3 784.05 -1389 -936 -4293 -2818 -4682 -1997 -2116 37 -1226 -3236 -3049 -2063 -222 -2 651 -268 441 164 651 694 -471 736 859 983 91 109 -164 -541 416 850 2309 1870 1112 -1852 -1771 -986 -546 -529 -552 -531 -1282 -592 -919 -704 -679 -629 -445 -321 -358 235 1357 1100 1175 547 412 718 520 288 585 833 1050 1372 1260 817 -176 -316 -214 130 1322 866 110 -224 61 -195 -66 -35 -144 -86 96 63 -809 -1483 -1878 -1372 -990 -866 -239 -165 -12 112 494 578 592 1151 1340 734 540 496 -214 -642 -534 -572 78 371 -506 -1048 -786 -679 -123 189 89 16 -194 74 367 661 677 434 71 -455 -566 -370 66 80 628 586 780 1051 983 434 55 -226 -172 174 100 -103 -117 -39 -89 -259 -153 -278 -296 -135 -98 -467 -291 -452 -181 -202 4 -137 -381 -361 -256 -31 0 115 -52 90 35 144 158 -110 169 200 237 23 28 -42 -137 100 204 580 513 319 -553 -510 -289 -168 -189 -226 -248 -656 -308 -493 -383 -371 -343 -246 -174 -191 126 756 637 720 352 273 483 354 196 391 557 726 989 981 672 -145 -246 -160 96 1017 722 97 -208 56 -173 -56 -28 -104 -61 69 50 -714 -1411 -1920 -1438 -1100 -999 -289 -205 -15 133 563 618 599 1127 1369 806 641 631 -282 -848 -682 -694 90 434 -634 -1368 -1074 -948 -180 286 141 25 -303 110 520 879 890 592 101 -685 -878 -570 99 117 877 798 1017 1362 1339 619 81 -345 -268 275 166 -176 -206 -70 -160 -462 -264 -473 -494
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