File name: Pandora157s1_MexicoCity-Vallejo_20230706_L2Fit_fout2c1d20210802p1-8.txt File generation date: 20230709T084902.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Michel Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 157 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora157_OF_v5d20190315.txt Instrument calibration file used: Pandora157s1_CF_v1d20210802.txt Level 1 file used: Pandora157s1_MexicoCity-Vallejo_20230706_L1_smca1c1d20210802p1-8.txt Full location name: Vallejo, Secretaria de Medio Ambiente, SEDEMA Short location name: MexicoCity-Vallejo Country of location: Mexico Location latitude [deg]: 19.4830 Location longitude [deg]: -99.1470 Location altitude [m]: 2255 Local noon date: 20230706 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0872 305.2277 305.3682 305.5086 305.6490 305.7894 305.9298 306.0702 306.2106 306.3510 306.4914 306.6317 306.7721 306.9124 307.0527 307.1930 307.3333 307.4736 307.6139 307.7542 307.8944 308.0347 308.1749 308.3151 308.4553 308.5955 308.7357 308.8759 309.0161 309.1563 309.2964 309.4365 309.5767 309.7168 309.8569 309.9970 310.1371 310.2771 310.4172 310.5573 310.6973 310.8373 310.9773 311.1173 311.2573 311.3973 311.5373 311.6773 311.8172 311.9572 312.0971 312.2370 312.3769 312.5168 312.6567 312.7966 312.9364 313.0763 313.2161 313.3560 313.4958 313.6356 313.7754 313.9152 314.0550 314.1947 314.3345 314.4742 314.6139 314.7537 314.8934 315.0331 315.1728 315.3124 315.4521 315.5917 315.7314 315.8710 316.0106 316.1502 316.2898 316.4294 316.5690 316.7086 316.8481 316.9877 317.1272 317.2667 317.4062 317.5457 317.6852 317.8247 317.9641 318.1036 318.2430 318.3825 318.5219 318.6613 318.8007 318.9401 319.0794 319.2188 319.3581 319.4975 319.6368 319.7761 319.9154 320.0547 320.1940 320.3333 320.4725 320.6118 320.7510 320.8902 321.0294 321.1686 321.3078 321.4470 321.5862 321.7253 321.8645 322.0036 322.1427 322.2818 322.4209 322.5600 322.6991 322.8382 322.9772 323.1163 323.2553 323.3943 323.5333 323.6723 323.8113 323.9503 324.0892 324.2282 324.3671 324.5060 324.6449 324.7838 324.9227 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230706T141048.3Z 8587.590837 260 1 25.49 2 62.65 73.90 75.28 245.73 0.00 1 0.00 1 0 25 1.033e-02 5.709e-03 1.693e-03 5.990e-04 2.660339e-01 3.138551e-04 2.852445e-03 -6.000000e+00 6.187559e-03 226.94 -2.00 3.11 -2.00 317.08 0.00e+00 2.031172e-03 4.313186e-05 1.038548e-04 -6.000000e+00 2.739441e-04 282.79 -2.00 20.00 -2.00 316.36 0.00e+00 2.166 0.000 302.00 328.00 3 1.7644e+00 8.2227e-04 2.0613e-02 -6.0000e+00 1.5325e-02 1.6340e-02 9.2160e-04 1.2399e-02 -6.0000e+00 1.6610e-02 -3.1370e-03 5.4714e-04 6.0111e-03 -6.0000e+00 9.9060e-03 -4.8957e-03 2.6306e-04 2.3320e-03 -6.0000e+00 4.1711e-03 1.2204e-02 -4.5699e-05 1.9100e-05 2.6349e-05 -6.0000e+00 3.1824e-04 3.3327e-03 3.7528e-05 12 1 1 12 9 1 99.47 19.02 0.28 0.00333 0.00299 151 62 1 8 0 166.500 21.38 15.00 19.02 30.24 21.5 783.31 -1288 -2619 -2957 -4693 -3830 -2581 -1688 -452 -956 -2486 -2596 -1857 -1076 172 143 -246 -77 658 912 970 683 894 1134 1151 780 585 -516 -345 255 1085 1544 1692 1030 -1206 -2050 -990 -779 -129 -11 -922 -932 -834 -681 -740 -345 -480 -539 -508 -300 368 905 820 827 887 577 697 653 390 528 699 1169 1383 1244 771 43 -405 -27 70 1352 797 110 -112 -145 -9 -171 -348 -136 -253 157 -390 -1053 -1328 -1780 -1437 -952 -814 -447 -120 -98 143 360 393 506 1052 997 560 540 315 -78 -544 -533 -579 122 414 -450 -1051 -780 -620 -176 223 155 19 50 18 225 642 781 407 241 -219 -451 -296 -1 175 552 577 680 1139 937 325 69 -340 -239 63 55 -152 -123 -2 -144 -300 -164 -294 -254 -165 -333 -379 -632 -469 -302 -207 -60 -139 -380 -402 -301 -177 32 30 -57 -19 167 241 264 189 247 318 337 239 184 -162 -103 73 305 458 544 355 -431 -713 -340 -290 -55 -5 -495 -545 -512 -396 -436 -203 -282 -338 -313 -182 224 576 514 548 615 413 509 482 288 384 508 875 1106 998 653 37 -326 -22 56 1126 687 104 -110 -143 -9 -151 -300 -107 -191 124 -341 -965 -1340 -1803 -1533 -1076 -979 -530 -145 -119 179 419 419 533 1073 1063 613 655 393 -103 -720 -668 -719 144 495 -576 -1348 -1047 -870 -259 326 238 29 76 26 314 842 1011 548 344 -312 -664 -434 -1 254 761 757 912 1517 1231 459 104 -494 -356 97 90 -244 -204 -3 -246 -505 -267 -489 -414 SS 20230706T141607.2Z 8587.594528 263 1 49.60 2 61.45 74.16 76.37 246.31 0.00 1 0.00 1 0 25 1.043e-02 5.728e-03 1.091e-03 3.649e-04 2.561497e-01 1.904652e-04 2.748009e-03 -6.000000e+00 6.247045e-03 226.94 -2.00 3.11 -2.00 317.27 0.00e+00 1.876316e-03 2.765302e-05 8.290371e-05 -6.000000e+00 2.766288e-04 282.79 -2.00 20.00 -2.00 316.55 0.00e+00 2.083 0.000 302.00 328.00 3 1.3312e+00 5.0123e-04 1.9833e-02 -6.0000e+00 1.5473e-02 1.4069e-02 5.6409e-04 1.1910e-02 -6.0000e+00 1.6772e-02 -2.8432e-03 3.3490e-04 5.8003e-03 -6.0000e+00 1.0002e-02 -5.5964e-03 1.6163e-04 2.1868e-03 -6.0000e+00 4.2102e-03 2.0410e-02 -3.1045e-04 1.1741e-05 2.5538e-05 -6.0000e+00 3.2143e-04 4.0288e-03 -1.7350e-05 10 0 0 10 0 0 75.19 19.02 0.28 0.00403 0.00170 553 115 1 8 0 89.680 21.38 14.99 19.02 30.84 21.5 783.08 -2213 -2499 -3383 -4688 -4380 -2449 -1643 -208 -465 -2179 -2197 -1287 -315 273 248 -304 -409 339 683 905 253 852 945 1080 932 418 -571 -576 -100 939 1639 1731 1118 -1154 -2031 -1059 -895 -212 -23 -714 -951 -748 -631 -737 -397 -525 -553 -366 -265 584 1102 957 976 821 512 942 511 326 528 654 1164 1472 1208 790 25 -464 16 221 1329 839 79 -119 -89 -62 -108 -360 -4 -18 346 -251 -983 -1411 -1810 -1471 -1003 -810 -485 -148 -81 21 333 458 529 1040 1025 712 609 398 -88 -543 -529 -653 21 382 -532 -1032 -718 -615 -170 259 82 -7 -35 144 267 573 825 409 185 -225 -481 -320 -27 202 653 630 692 1157 941 301 99 -256 -227 111 -42 -176 -111 -39 -196 -268 -122 -319 -195 -265 -323 -442 -582 -496 -264 -185 -26 -62 -305 -311 -190 -52 51 53 -71 -100 86 162 221 63 232 262 283 256 118 -160 -169 -28 259 474 541 340 -363 -621 -352 -294 -81 -10 -366 -533 -439 -380 -449 -241 -319 -330 -214 -152 337 662 613 606 534 343 642 354 225 359 445 815 1100 975 672 21 -374 12 163 1026 721 74 -116 -87 -59 -95 -288 -3 -14 273 -202 -893 -1412 -1796 -1537 -1110 -954 -600 -188 -102 25 379 477 550 1047 1078 758 718 514 -120 -744 -686 -787 24 445 -664 -1375 -1000 -832 -241 388 128 -12 -53 208 385 776 1099 566 254 -328 -722 -478 -39 281 930 854 899 1491 1274 438 142 -377 -343 174 -68 -304 -184 -66 -334 -452 -214 -539 -323 SS 20230706T142210.0Z 8587.598727 266 1 49.67 2 60.08 74.45 77.63 246.96 0.00 1 0.00 1 0 25 9.629e-03 5.622e-03 2.168e-03 7.093e-04 2.472529e-01 3.708455e-04 2.651578e-03 -6.000000e+00 5.771919e-03 226.94 -2.00 3.11 -2.00 317.36 0.00e+00 1.656749e-03 5.449102e-05 7.222944e-05 -6.000000e+00 2.555135e-04 282.79 -2.00 20.00 -2.00 316.63 0.00e+00 1.996 0.000 302.00 328.00 3 2.5388e+00 9.7652e-04 1.9061e-02 -6.0000e+00 1.4296e-02 1.9088e-02 1.0978e-03 1.1474e-02 -6.0000e+00 1.5493e-02 -2.5470e-03 6.5532e-04 5.5916e-03 -6.0000e+00 9.2401e-03 -5.3510e-03 3.1750e-04 2.0598e-03 -6.0000e+00 3.8914e-03 6.5963e-03 1.4380e-04 2.2940e-05 2.4050e-05 -6.0000e+00 2.9679e-04 2.9441e-03 7.3432e-05 11 1 0 11 8 0 99.89 19.02 0.24 0.00294 0.00402 235 49 1 8 0 211.290 21.38 15.00 19.02 31.50 21.5 783.05 -1055 -2225 -3254 -4432 -2847 -2978 12 -75 184 -2430 -2238 -527 -870 -171 32 -200 -1053 170 637 692 432 392 793 657 590 185 -466 -808 -28 1218 1161 1770 958 -849 -2348 -566 -658 -124 -296 -947 -998 -816 -317 -825 -225 -728 -537 -231 -503 519 1115 999 870 935 670 1011 588 192 518 533 1277 1353 1165 747 -29 -366 75 312 1431 919 85 -139 -165 -24 -152 -222 -2 -89 192 -217 -871 -1391 -1838 -1346 -1013 -809 -536 -128 -103 -31 232 423 493 1026 1011 548 513 322 19 -678 -493 -621 53 489 -425 -889 -766 -594 -90 375 101 18 -28 134 285 583 795 447 125 -338 -546 -383 58 144 556 704 581 1183 960 326 86 -219 -200 42 2 -170 -63 2 -127 -284 -157 -315 -227 -121 -277 -410 -543 -315 -319 1 -9 24 -337 -312 -76 -140 -31 6 -44 -243 40 156 174 110 100 206 178 167 54 -134 -222 -7 319 320 509 295 -269 -728 -177 -217 -47 -130 -476 -533 -456 -181 -478 -130 -420 -304 -131 -281 290 647 601 554 621 459 704 415 136 360 370 912 1006 933 630 -25 -292 57 232 1114 775 76 -130 -155 -23 -132 -179 -2 -64 144 -176 -771 -1357 -1879 -1446 -1126 -958 -651 -159 -128 -37 266 453 500 1003 1030 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