File name: Pandora157s1_MexicoCity-Vallejo_20230730_L2Fit_fwvt1c1d20210802p1-8.txt
File generation date: 20230802T120304.1Z
Data description: Level 2 spectral fitting results file
Data file version: fwvt1c1p1-8
Local principal investigator: Michel Grutter
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 157
Spectrometer number: 1
Processing software version used: BlickP v1.8.49
Instrument operation file used: Pandora157_OF_v5d20190315.txt
Instrument calibration file used: Pandora157s1_CF_v1d20210802.txt
Level 1 file used: Pandora157s1_MexicoCity-Vallejo_20230730_L1_smca1c1d20210802p1-8.txt
Full location name: Vallejo, Secretaria de Medio Ambiente, SEDEMA
Short location name: MexicoCity-Vallejo
Country of location: Mexico
Location latitude [deg]: 19.4830
Location longitude [deg]: -99.1470
Location altitude [m]: 2255
Local noon date: 20230730
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 1647 1796
Nominal wavelengths inside fitting window [nm]: 492.1139 492.2344 492.3549 492.4754 492.5959 492.7164 492.8368 492.9573 493.0777 493.1981 493.3185 493.4389 493.5592 493.6796 493.7999 493.9202 494.0405 494.1608 494.2811 494.4013 494.5215 494.6417 494.7619 494.8821 495.0023 495.1224 495.2425 495.3626 495.4827 495.6028 495.7229 495.8429 495.9629 496.0830 496.2030 496.3229 496.4429 496.5628 496.6828 496.8027 496.9226 497.0424 497.1623 497.2822 497.4020 497.5218 497.6416 497.7614 497.8811 498.0009 498.1206 498.2403 498.3600 498.4797 498.5994 498.7190 498.8386 498.9582 499.0778 499.1974 499.3170 499.4365 499.5560 499.6756 499.7950 499.9145 500.0340 500.1534 500.2729 500.3923 500.5117 500.6310 500.7504 500.8697 500.9891 501.1084 501.2277 501.3470 501.4662 501.5855 501.7047 501.8239 501.9431 502.0623 502.1814 502.3006 502.4197 502.5388 502.6579 502.7770 502.8960 503.0151 503.1341 503.2531 503.3721 503.4911 503.6100 503.7290 503.8479 503.9668 504.0857 504.2046 504.3234 504.4423 504.5611 504.6799 504.7987 504.9175 505.0362 505.1549 505.2737 505.3924 505.5111 505.6297 505.7484 505.8670 505.9856 506.1042 506.2228 506.3414 506.4600 506.5785 506.6970 506.8155 506.9340 507.0525 507.1709 507.2893 507.4078 507.5262 507.6445 507.7629 507.8813 507.9996 508.1179 508.2362 508.3545 508.4727 508.5910 508.7092 508.8274 508.9456 509.0638 509.1820 509.3001 509.4182 509.5364 509.6544 509.7725 509.8906
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Water vapor effective temperature [K]
Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Nitrogen dioxide effective temperature [K]
Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 49: Ozone effective temperature [K]
Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 57: Lower limit used for wavelength scaling [nm]
Column 58: Upper limit used for wavelength scaling [nm]
Column 59: Order of smoothing polynomial
Column 60: Smoothing polynomial coefficient, order 0
Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 65: Smoothing polynomial coefficient, order 1
Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 70: Mean value of measured data inside fitting window [same units as measurements]
Column 71: Wavelength change polynomial coefficient, order 0
Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 85: Wavelength effective temperature [°C], 999=no effective temperature given
Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 89: Number of bright count cycles
Column 90: Number of dark count cycles
Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 94: Integration time [ms]
Column 95: Temperature at electronics board [°C], 999=no temperature signal
Column 96: Spectrometer control temperature [°C], 999=no temperature signal
Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 98: Temperature in head sensor [°C], 999=no temperature signal
Column 99: Humidity in head sensor [%], -9=no humidity signal
Column 100: Pressure in head sensor [hPa], -9=no pressure signal
Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SQ 20230730T133827.9Z 8611.568379 172 1 50.43 2 71.36 76.38 140.17 249.45 0.00 1 0.00 1 0 15 2.382e-03 2.386e-03 8.181e-04 8.156e-04 4.084957e+03 5.049280e+01 2.850728e+02 -6.000000e+00 1.296479e+02 282.75 -2.00 20.00 -2.00 505.26 0.00e+00 1.022452e-03 2.223967e-05 6.100157e-05 -6.000000e+00 6.627857e-05 282.75 -2.00 20.00 -2.00 500.36 0.00e+00 2.159130e-01 1.609909e-02 3.017993e-02 -6.000000e+00 4.687646e-02 226.53 -2.00 3.11 -2.00 501.97 0.00e+00 3.091 0.000 489.00 513.00 1 6.2759e+00 1.2311e-03 4.4805e-03 -6.0000e+00 3.5855e-03 -6.0656e-04 3.2109e-04 7.2042e-04 -6.0000e+00 9.4358e-04 2.5349e-03 1.2987e-03 7.4670e-05 3.9204e-05 -6.0000e+00 2.2593e-04 5.8742e-03 1.0376e-05 10 0 0 10 0 0 98.82 18.72 2.04 0.00587 0.01488 24 5 1 7 0 2100.720 21.17 15.00 18.72 25.64 22.5 785.41 -407 -420 -83 321 394 335 179 305 305 121 -159 27 -127 -151 -218 58 -56 -312 127 191 130 70 148 196 197 197 51 -117 72 -388 -374 260 -134 -190 65 111 -66 -185 -36 -206 -38 -17 991 334 155 70 164 -127 -116 -80 -505 -393 -348 -282 -318 -308 30 16 95 108 92 259 38 129 361 154 -25 -159 -119 -34 -237 0 -128 -256 -194 -263 -12 -204 -297 -64 -215 -205 24 -338 -74 -76 -53 -124 19 29 336 10 -147 200 119 -65 80 -190 -134 -308 -210 -57 -204 -525 -68 -158 -72 -20 -99 -106 -147 -25 98 -28 528 558 456 109 416 231 118 427 92 47 131 144 -43 256 191 -439 -13 81 -360 13 207 -177 -133 144 272 249 254 243 114 282 -87 -259 -278 -126 -254 -362 -395 -415 -84 331 412 355 191 327 324 128 -167 28 -130 -153 -221 59 -57 -329 135 204 139 75 157 209 211 211 54 -123 74 -390 -374 260 -137 -200 69 117 -70 -193 -37 -212 -40 -18 1031 351 164 74 172 -132 -119 -80 -496 -379 -336 -276 -316 -313 31 16 98 111 94 266 39 132 369 155 -25 -157 -116 -33 -229 0 -125 -253 -192 -258 -11 -195 -282 -61 -205 -196 23 -329 -72 -74 -51 -122 19 29 329 10 -147 199 118 -63 77 -178 -123 -281 -192 -53 -193 -514 -67 -156 -71 -20 -95 -103 -144 -24 98 -28 530 560 462 111 419 230 116 415 89 46 128 140 -42 249 185 -427 -12 77 -340 13 193 -167 -127 139 265 245 250 240 113 280 -87 -256 -271 -120 -241 -343
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SQ 20230730T134919.8Z 8611.575924 178 1 8.39 2 68.87 77.08 142.44 249.26 0.00 1 0.00 1 0 15 1.818e-03 1.817e-03 3.740e-04 3.732e-04 3.900437e+03 2.278192e+01 2.756513e+02 -6.000000e+00 9.892530e+01 282.75 -2.00 20.00 -2.00 505.25 0.00e+00 1.069850e-03 1.017665e-05 6.377195e-05 -6.000000e+00 5.057238e-05 282.75 -2.00 20.00 -2.00 500.39 0.00e+00 1.944621e-01 7.353931e-03 2.853178e-02 -6.000000e+00 3.576708e-02 226.53 -2.00 3.11 -2.00 501.98 0.00e+00 2.748 0.000 489.00 513.00 1 3.4172e+00 5.6266e-04 4.1465e-03 -6.0000e+00 2.7358e-03 1.0323e-02 1.4682e-04 6.7978e-04 -6.0000e+00 7.1993e-04 4.5953e-02 1.2328e-03 3.4126e-05 4.0086e-05 -6.0000e+00 1.7239e-04 3.2687e-03 2.8626e-05 12 1 1 12 1 1 20.55 18.72 2.09 0.00327 0.01182 64 82 1 7 0 126.250 21.17 15.00 18.72 26.06 22.5 785.50 -277 -80 -138 300 343 302 264 210 245 189 -56 -95 -30 -212 -180 -16 58 -219 -68 252 80 156 235 -17 234 230 -75 -141 122 -225 -235 128 2 -293 18 210 -103 -76 -80 -21 -160 50 77 95 186 159 176 -4 -224 -101 -304 -290 -160 -256 -263 -216 -61 31 89 108 34 104 146 80 92 164 -9 -243 -236 40 -115 -70 1 -216 -252 24 13 -173 -113 -24 -295 -204 109 -139 -117 -119 -36 -61 -36 74 240 17 -112 121 135 -66 -13 -183 -159 -124 -96 52 -119 -535 -284 -220 -229 85 77 -79 -112 97 96 128 410 383 318 81 267 43 32 354 301 -151 39 -20 -4 219 226 -284 -46 104 -120 -15 380 -93 -150 129 129 99 285 183 192 114 -120 -253 -319 -70 -73 -25 -274 -80 -140 311 356 320 278 222 257 199 -58 -97 -31 -215 -183 -16 59 -231 -71 266 84 164 248 -18 249 244 -79 -147 124 -229 -237 130 2 -306 18 219 -109 -79 -83 -21 -164 52 81 99 194 166 182 -4 -229 -102 -298 -284 -156 -254 -264 -219 -63 32 92 111 35 105 148 81 95 165 -9 -243 -233 39 -112 -68 1 -212 -249 24 13 -167 -110 -23 -282 -197 105 -136 -114 -117 -35 -60 -35 72 236 17 -111 120 135 -64 -12 -174 -150 -116 -89 49 -115 -528 -280 -217 -223 83 74 -77 -109 96 96 129 405 381 318 82 266 43 31 341 294 -146 38 -20 -3 212 219 -276 -45 99 -114 -14 355 -89 -143 125 127 97 279 180 190 113 -119 -250 -309 -68 -69 -24
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