File name: Pandora157s1_MexicoCity-Vallejo_20230817_L2Fit_fout2c1d20210802p1-8.txt File generation date: 20230819T055800.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Michel Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 157 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora157_OF_v5d20190315.txt Instrument calibration file used: Pandora157s1_CF_v1d20210802.txt Level 1 file used: Pandora157s1_MexicoCity-Vallejo_20230817_L1_smca1c1d20210802p1-8.txt Full location name: Vallejo, Secretaria de Medio Ambiente, SEDEMA Short location name: MexicoCity-Vallejo Country of location: Mexico Location latitude [deg]: 19.4830 Location longitude [deg]: -99.1470 Location altitude [m]: 2255 Local noon date: 20230817 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0872 305.2277 305.3682 305.5086 305.6490 305.7894 305.9298 306.0702 306.2106 306.3510 306.4914 306.6317 306.7721 306.9124 307.0527 307.1930 307.3333 307.4736 307.6139 307.7542 307.8944 308.0347 308.1749 308.3151 308.4553 308.5955 308.7357 308.8759 309.0161 309.1563 309.2964 309.4365 309.5767 309.7168 309.8569 309.9970 310.1371 310.2771 310.4172 310.5573 310.6973 310.8373 310.9773 311.1173 311.2573 311.3973 311.5373 311.6773 311.8172 311.9572 312.0971 312.2370 312.3769 312.5168 312.6567 312.7966 312.9364 313.0763 313.2161 313.3560 313.4958 313.6356 313.7754 313.9152 314.0550 314.1947 314.3345 314.4742 314.6139 314.7537 314.8934 315.0331 315.1728 315.3124 315.4521 315.5917 315.7314 315.8710 316.0106 316.1502 316.2898 316.4294 316.5690 316.7086 316.8481 316.9877 317.1272 317.2667 317.4062 317.5457 317.6852 317.8247 317.9641 318.1036 318.2430 318.3825 318.5219 318.6613 318.8007 318.9401 319.0794 319.2188 319.3581 319.4975 319.6368 319.7761 319.9154 320.0547 320.1940 320.3333 320.4725 320.6118 320.7510 320.8902 321.0294 321.1686 321.3078 321.4470 321.5862 321.7253 321.8645 322.0036 322.1427 322.2818 322.4209 322.5600 322.6991 322.8382 322.9772 323.1163 323.2553 323.3943 323.5333 323.6723 323.8113 323.9503 324.0892 324.2282 324.3671 324.5060 324.6449 324.7838 324.9227 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20230817T154547.7Z 8629.656802 151 1 49.73 2 42.28 91.43 57.02 88.32 0.00 1 0.00 1 0 17 8.584e-03 6.133e-03 2.965e-03 1.602e-03 1.677421e-01 8.422380e-04 1.835052e-03 -6.000000e+00 5.134399e-03 226.40 -2.00 3.11 -2.00 315.98 0.00e+00 1.757672e-03 8.913851e-05 1.077118e-04 -6.000000e+00 2.277331e-04 282.76 -2.00 20.00 -2.00 315.31 0.00e+00 1.350 0.000 302.00 328.00 3 4.5710e+00 2.1739e-03 1.2932e-02 -6.0000e+00 1.2701e-02 4.4677e-02 2.4241e-03 8.0349e-03 -6.0000e+00 1.3771e-02 -2.2358e-03 1.3912e-03 3.8104e-03 -6.0000e+00 8.2161e-03 -5.6281e-03 6.2791e-04 1.7045e-03 -6.0000e+00 3.4635e-03 1.6246e-03 2.1083e-04 5.1423e-05 1.8883e-05 -6.0000e+00 2.6453e-04 3.5569e-03 6.9118e-05 10 0 0 10 0 0 99.75 18.86 0.32 0.00356 0.00514 42 9 1 8 0 1183.790 21.27 15.00 18.86 31.69 23.3 784.86 -1354 -751 -2388 -2871 -2418 301 -101 201 100 -382 -2240 -864 1365 224 1018 -830 -63 666 790 704 390 927 803 821 388 -38 -800 -107 1022 2010 2042 694 1337 -674 -2372 -465 -931 21 -85 -817 -1330 -437 -583 -569 -962 -671 -690 -342 -359 -85 1279 902 921 984 481 588 528 574 970 816 1132 1436 1099 374 -105 -346 -196 595 1147 764 -1120 213 -139 -334 -3 2 -65 134 347 -103 -769 -1853 -1740 -1111 -1036 -824 -294 -26 -365 -251 146 507 437 1021 1550 540 341 222 -41 -685 -319 -414 312 521 -556 -934 -751 -720 -36 498 353 -15 -80 9 123 497 827 320 414 -172 -401 -197 -33 138 642 580 662 1095 875 318 116 -249 -183 238 -56 -17 -232 43 -256 -259 -268 -220 -345 -327 -191 -608 -680 -524 61 -21 46 25 -97 -575 -224 378 70 346 -306 -24 255 310 283 158 372 325 343 169 -17 -348 -44 394 758 781 284 569 -292 -1000 -193 -415 10 -49 -534 -943 -316 -431 -423 -716 -499 -500 -238 -246 -58 886 652 696 770 386 478 432 467 776 656 937 1243 1017 357 -100 -307 -162 479 965 701 -1104 216 -141 -333 -3 2 -52 102 270 -87 -711 -1862 -1834 -1210 -1198 -1002 -371 -33 -474 -318 174 554 448 998 1552 583 399 279 -53 -893 -397 -486 355 606 -687 -1214 -1007 -1005 -52 732 538 -22 -119 12 161 615 1019 404 549 -241 -583 -287 -47 190 846 736 812 1322 1098 418 157 -346 -255 341 -84 -27 -369 70 -415 -421 -423 -341 -525 SS 20230817T155122.9Z 8629.660681 154 1 49.31 2 40.97 91.94 55.74 88.78 0.00 1 0.00 1 0 17 8.542e-03 5.852e-03 3.919e-03 2.075e-03 1.640083e-01 1.088625e-03 1.793281e-03 -6.000000e+00 5.111063e-03 226.40 -2.00 3.11 -2.00 316.07 0.00e+00 2.203172e-03 1.176413e-04 1.702736e-04 -6.000000e+00 2.266602e-04 282.76 -2.00 20.00 -2.00 315.40 0.00e+00 1.323 0.000 302.00 328.00 3 4.9025e+00 2.8134e-03 1.2699e-02 -6.0000e+00 1.2643e-02 4.1199e-02 3.1394e-03 8.1431e-03 -6.0000e+00 1.3707e-02 -3.5197e-04 1.8021e-03 3.7456e-03 -6.0000e+00 8.1780e-03 -6.5171e-03 8.1520e-04 2.0221e-03 -6.0000e+00 3.4485e-03 1.1979e-03 4.5589e-04 6.6799e-05 2.1188e-05 -6.0000e+00 2.6322e-04 2.5146e-03 1.1562e-04 11 1 0 11 8 0 99.98 18.86 0.42 0.00251 0.00594 42 9 1 8 0 1173.910 21.27 15.00 18.86 32.33 23.4 784.54 -203 -1181 -2165 -3676 -1181 -2217 680 -57 646 -1567 -258 501 1087 900 55 -39 -167 970 312 803 301 655 734 717 52 772 -630 191 800 1122 1655 2387 1379 -1728 -2109 -621 45 -318 -365 -370 -1678 -566 -879 -591 -824 -459 -957 -1315 169 890 822 907 392 1119 374 763 744 268 646 1016 941 1236 1332 671 -206 -296 -21 139 1058 772 -1367 82 42 -172 -441 59 -474 241 326 -170 -734 -1193 -1932 -1242 -1043 -594 -370 133 -70 156 463 34 487 1027 1225 395 366 561 100 -441 -76 -755 270 668 -411 -924 -533 -758 74 166 97 55 69 172 -36 231 457 363 369 -310 -431 -245 -58 180 515 623 516 840 836 65 116 -225 -235 250 -75 -20 112 0 25 -393 -105 -362 -253 -47 -293 -536 -867 -246 -451 140 -13 156 -393 -63 125 295 270 18 -14 -62 363 120 315 120 258 290 296 22 329 -270 76 300 415 627 949 571 -737 -875 -252 19 -158 -209 -236 -1174 -408 -641 -438 -612 -336 -686 -913 113 590 563 653 293 859 296 608 596 214 509 800 766 1068 1211 636 -194 -262 -17 110 874 694 -1342 82 42 -170 -415 51 -376 179 249 -140 -674 -1182 -2025 -1361 -1198 -716 -470 173 -91 195 546 37 495 995 1219 423 425 697 131 -576 -95 -894 304 768 -502 -1207 -716 -1063 105 249 150 85 104 242 -48 287 566 459 491 -441 -630 -358 -83 249 683 793 635 1020 1039 86 157 -313 -332 359 -113 -31 181 0 41 -641 -169 -569 -392 SS 20230817T155710.2Z 8629.664702 157 1 49.68 2 39.60 92.49 54.41 89.26 0.00 1 0.00 1 0 17 8.620e-03 5.980e-03 3.265e-03 1.728e-03 1.595793e-01 9.061711e-04 1.743545e-03 -6.000000e+00 5.157952e-03 226.40 -2.00 3.11 -2.00 316.08 0.00e+00 2.142837e-03 9.800526e-05 1.489308e-04 -6.000000e+00 2.287455e-04 282.76 -2.00 20.00 -2.00 315.41 0.00e+00 1.297 0.000 302.00 328.00 3 4.4906e+00 2.3427e-03 1.2412e-02 -6.0000e+00 1.2759e-02 3.0472e-02 2.6139e-03 7.9094e-03 -6.0000e+00 1.3833e-02 7.6562e-04 1.5005e-03 3.6443e-03 -6.0000e+00 8.2531e-03 -6.5845e-03 6.7837e-04 1.9485e-03 -6.0000e+00 3.4800e-03 1.8693e-03 5.1871e-04 5.5680e-05 2.0463e-05 -6.0000e+00 2.6564e-04 3.0396e-03 1.2478e-04 10 0 0 10 0 0 99.99 18.86 0.42 0.00304 0.00694 108 22 1 8 0 459.870 21.27 15.00 18.86 32.79 23.4 784.54 244 -2142 -2194 -3863 -1043 -410 1739 635 579 -1354 -871 -20 908 396 88 -27 -539 580 734 928 1089 296 1664 251 487 -464 -677 -219 605 1798 1278 2664 1184 -745 -1501 -508 -1162 -80 -142 -990 -947 -1082 -591 -674 -517 -881 -887 -578 -643 625 862 727 796 781 113 670 636 346 976 625 1442 859 806 513 -442 -447 -71 566 1523 880 -143 41 29 -88 104 -271 368 28 380 -542 -663 -1371 -1776 -1651 -848 -670 -435 141 -92 47 -35 573 623 908 1297 402 822 108 -116 -651 -500 -589 182 538 -412 -933 -707 -523 -53 415 296 -67 60 -95 104 558 1035 251 97 -276 -568 -394 79 175 330 736 689 1147 719 349 206 -400 -199 154 162 -278 88 -86 -5 -242 -181 -279 -345 57 -538 -555 -920 -219 -81 359 142 139 -338 -214 -5 245 120 30 -10 -200 218 282 364 430 117 653 103 206 -200 -286 -89 229 655 482 1045 492 -315 -612 -203 -505 -40 -81 -642 -650 -775 -430 -494 -378 -640 -639 -401 -432 412 585 520 595 604 90 536 512 277 769 497 1175 734 735 486 -415 -396 -57 451 1238 793 -138 41 29 -87 96 -233 285 21 290 -447 -605 -1346 -1860 -1819 -967 -815 -546 182 -118 59 -41 624 630 877 1284 433 950 134 -152 -847 -626 -688 207 625 -505 -1221 -948 -729 -76 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