File name: Pandora157s1_MexicoCity-Vallejo_20231114_L2Fit_fout2c1d20210802p1-8.txt File generation date: 20231115T102750.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Michel Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 157 Spectrometer number: 1 Processing software version used: BlickP v1.8.49 Instrument operation file used: Pandora157_OF_v5d20190315.txt Instrument calibration file used: Pandora157s1_CF_v1d20210802.txt Level 1 file used: Pandora157s1_MexicoCity-Vallejo_20231114_L1_smca1c1d20210802p1-8.txt Full location name: Vallejo, Secretaria de Medio Ambiente, SEDEMA Short location name: MexicoCity-Vallejo Country of location: Mexico Location latitude [deg]: 19.4830 Location longitude [deg]: -99.1470 Location altitude [m]: 2255 Local noon date: 20231114 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0872 305.2277 305.3682 305.5086 305.6490 305.7894 305.9298 306.0702 306.2106 306.3510 306.4914 306.6317 306.7721 306.9124 307.0527 307.1930 307.3333 307.4736 307.6139 307.7542 307.8944 308.0347 308.1749 308.3151 308.4553 308.5955 308.7357 308.8759 309.0161 309.1563 309.2964 309.4365 309.5767 309.7168 309.8569 309.9970 310.1371 310.2771 310.4172 310.5573 310.6973 310.8373 310.9773 311.1173 311.2573 311.3973 311.5373 311.6773 311.8172 311.9572 312.0971 312.2370 312.3769 312.5168 312.6567 312.7966 312.9364 313.0763 313.2161 313.3560 313.4958 313.6356 313.7754 313.9152 314.0550 314.1947 314.3345 314.4742 314.6139 314.7537 314.8934 315.0331 315.1728 315.3124 315.4521 315.5917 315.7314 315.8710 316.0106 316.1502 316.2898 316.4294 316.5690 316.7086 316.8481 316.9877 317.1272 317.2667 317.4062 317.5457 317.6852 317.8247 317.9641 318.1036 318.2430 318.3825 318.5219 318.6613 318.8007 318.9401 319.0794 319.2188 319.3581 319.4975 319.6368 319.7761 319.9154 320.0547 320.1940 320.3333 320.4725 320.6118 320.7510 320.8902 321.0294 321.1686 321.3078 321.4470 321.5862 321.7253 321.8645 322.0036 322.1427 322.2818 322.4209 322.5600 322.6991 322.8382 322.9772 323.1163 323.2553 323.3943 323.5333 323.6723 323.8113 323.9503 324.0892 324.2282 324.3671 324.5060 324.6449 324.7838 324.9227 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231114T163324.1Z 8718.689862 157 1 17.82 2 46.08 143.38 61.85 135.37 0.00 1 0.00 1 0 17 8.636e-03 6.435e-03 2.690e-03 1.697e-03 1.640090e-01 8.950887e-04 1.820271e-03 -6.000000e+00 5.133332e-03 224.92 -2.00 3.11 -2.00 315.32 0.00e+00 5.362907e-04 8.242242e-05 1.893571e-05 -6.000000e+00 2.273118e-04 280.92 -2.00 20.00 -2.00 314.73 0.00e+00 1.440 0.000 302.00 328.00 3 4.1654e+00 2.2875e-03 1.3300e-02 -6.0000e+00 1.2663e-02 3.0267e-02 2.5455e-03 7.4871e-03 -6.0000e+00 1.3752e-02 2.3529e-03 1.4588e-03 3.7028e-03 -6.0000e+00 8.2045e-03 -6.6270e-03 6.4506e-04 1.1062e-03 -6.0000e+00 3.4609e-03 2.3261e-03 -4.0852e-04 5.3976e-05 1.6221e-05 -6.0000e+00 2.6603e-04 4.9010e-03 -3.3923e-05 12 9 1 12 1 1 -69.75 18.76 0.27 0.00490 0.00183 12 7 1 8 0 1370.220 21.17 15.00 18.76 29.77 24.1 785.80 -532 -1435 -2335 -3025 -2217 -275 279 1295 975 -880 -1435 278 -130 1432 704 -110 -99 765 1094 1063 627 373 700 792 861 205 -828 -726 987 1253 1877 2066 1126 -1808 -2134 25 -1242 -270 -346 -911 -1255 -922 -499 -793 -365 -578 -685 -532 -439 458 642 580 367 975 -72 879 897 48 791 882 1093 1264 1092 570 -285 -409 56 405 1574 909 -239 -84 -424 261 -398 -46 164 -114 588 -79 -475 -1585 -2076 -1270 -789 -817 -497 -295 -219 -196 78 590 384 940 1143 645 558 198 -213 -810 -278 -525 163 585 -580 -1197 -577 -582 137 409 347 125 -80 356 243 424 922 617 58 -490 -431 -438 165 7 549 832 680 1081 728 193 174 -345 -112 113 -76 -160 5 -3 -360 -243 -41 -443 -240 -157 -449 -727 -890 -596 -70 74 369 300 -283 -460 89 -45 534 287 -48 -44 342 499 496 297 176 334 392 436 106 -423 -354 450 562 858 978 562 -913 -1050 12 -642 -156 -227 -663 -965 -736 -399 -639 -291 -463 -534 -404 -327 337 487 457 300 810 -61 758 780 42 676 754 963 1150 1047 561 -279 -380 49 347 1380 861 -242 -87 -443 265 -391 -42 138 -93 484 -70 -453 -1623 -2217 -1400 -910 -983 -622 -374 -277 -243 92 653 403 953 1176 702 650 242 -272 -1032 -341 -617 185 679 -709 -1526 -756 -786 190 577 502 182 -113 484 310 519 1120 768 75 -668 -600 -612 226 10 710 1044 824 1307 904 248 230 -465 -150 157 -108 -236 8 -5 -556 -370 -61 -654 -352 SS 20231114T163910.1Z 8718.693867 161 1 14.62 2 45.28 144.93 60.94 136.37 0.00 1 0.00 1 0 17 8.914e-03 6.759e-03 2.763e-03 1.807e-03 1.626966e-01 9.549522e-04 1.798006e-03 -6.000000e+00 5.299043e-03 224.92 -2.00 3.11 -2.00 315.15 0.00e+00 4.997504e-04 8.506889e-05 1.696133e-05 -6.000000e+00 2.346428e-04 280.92 -2.00 20.00 -2.00 314.57 0.00e+00 1.419 0.000 302.00 328.00 3 4.1604e+00 2.4360e-03 1.3127e-02 -6.0000e+00 1.3072e-02 3.2420e-02 2.7091e-03 7.3985e-03 -6.0000e+00 1.4196e-02 -2.1338e-04 1.5518e-03 3.6585e-03 -6.0000e+00 8.4693e-03 -5.4591e-03 6.8257e-04 1.0847e-03 -6.0000e+00 3.5728e-03 2.3808e-03 -3.7577e-04 5.7300e-05 1.6055e-05 -6.0000e+00 2.7461e-04 4.3249e-03 -4.4913e-05 12 9 1 12 1 1 82.77 18.76 0.38 0.00432 0.00150 10 8 1 8 0 1328.410 21.17 15.00 18.76 29.88 24.3 785.52 -1124 -984 -1915 -3307 -957 -288 925 776 1190 -1988 -421 380 1063 1618 -669 125 -694 1285 -58 1517 519 1003 1713 585 1140 -44 -842 -578 1556 401 2221 1484 1021 -1436 -2195 -353 -1299 441 -585 -1099 -1152 -954 -501 -712 -476 -948 -559 -1027 -249 123 836 548 246 1074 -17 912 96 205 455 379 1608 1534 1011 453 -218 -485 42 339 1257 1022 1160 60 -254 -33 -501 14 85 -280 248 -344 -662 -1557 -1789 -1568 -875 -824 -426 -182 -111 -129 91 521 475 1562 1200 714 367 280 221 -857 -296 -600 183 461 -637 -1171 -898 -565 74 354 117 -67 -47 311 335 540 1030 458 59 -549 -293 -206 49 94 717 614 702 1211 591 235 -40 -205 -590 360 -121 -199 -36 -113 -62 -470 -99 -244 -102 -352 -324 -627 -1028 -267 -78 260 237 385 -679 -140 128 382 634 -291 56 -325 602 -28 733 256 490 841 301 599 -24 -448 -292 741 187 1043 730 527 -747 -1115 -177 -694 261 -392 -818 -906 -771 -410 -587 -389 -770 -444 -799 -189 92 643 440 203 909 -15 794 84 180 393 329 1422 1410 973 450 -216 -456 37 292 1127 978 1174 63 -266 -34 -492 13 73 -230 208 -309 -637 -1595 -1912 -1743 -1007 -991 -528 -230 -140 -159 107 578 497 1584 1245 778 426 342 281 -1082 -362 -701 208 532 -776 -1477 -1170 -757 101 500 168 -97 -66 418 427 663 1241 568 77 -742 -406 -285 67 126 923 765 853 1446 728 300 -52 -272 -798 493 -171 -291 -54 -171 -95 -710 -146 -358 -146 SS 20231114T164357.4Z 8718.697192 164 1 49.23 2 44.65 146.27 60.20 137.23 0.00 1 0.00 1 0 17 1.021e-02 6.321e-03 4.923e-03 2.616e-03 1.614654e-01 1.366260e-03 1.784578e-03 -6.000000e+00 6.070468e-03 224.92 -2.00 3.11 -2.00 316.07 0.00e+00 8.865184e-04 1.464279e-04 2.071164e-05 -6.000000e+00 2.687344e-04 280.92 -2.00 20.00 -2.00 315.41 0.00e+00 1.404 0.000 302.00 328.00 3 5.2440e+00 3.5217e-03 1.3021e-02 -6.0000e+00 1.4975e-02 4.1361e-02 3.9330e-03 7.4278e-03 -6.0000e+00 1.6260e-02 1.9462e-03 2.2612e-03 3.6536e-03 -6.0000e+00 9.7012e-03 -7.5590e-03 1.0237e-03 1.2022e-03 -6.0000e+00 4.0941e-03 8.1265e-04 6.8220e-05 8.4228e-05 1.5718e-05 -6.0000e+00 3.1442e-04 3.8462e-03 3.9518e-05 11 1 0 11 8 0 97.52 18.76 0.33 0.00385 0.00436 21 4 1 8 0 2343.950 21.17 15.00 18.76 30.10 24.2 785.56 -3088 -237 -3591 -3964 -2637 1156 2565 519 -529 -614 -1806 389 -165 586 1241 746 -705 2177 -661 1985 509 338 1389 1049 1474 -687 -269 -686 -289 1426 2772 925 1287 -787 -2444 -675 -837 -66 -681 -758 -1355 -317 -54 -643 -1088 -986 -163 -781 -407 380 897 428 49 1572 -48 769 92 219 1026 1259 1151 1169 1318 843 -573 -252 -6 217 1227 1421 114 143 -338 -506 -3 -397 -576 610 308 -354 -806 -1570 -1462 -975 -1064 -890 68 -139 -486 -22 -141 692 3 1043 1162 403 406 329 46 -751 -297 -493 284 212 -923 -1085 -628 -519 45 604 319 317 -7 125 239 302 633 415 171 -435 -526 -192 256 177 577 724 1014 1179 271 465 104 -205 -407 261 47 -263 -221 184 -335 -319 -113 -226 -224 -742 -58 -900 -932 -555 227 521 118 -130 -156 -460 99 -46 180 412 265 -261 800 -256 765 201 134 553 434 630 -301 -116 -280 -111 524 1031 369 534 -333 -1005 -270 -364 -32 -395 -493 -947 -228 -39 -476 -804 -720 -116 -539 -275 253 613 305 37 1202 -38 614 75 176 809 992 937 1010 1197 797 -539 -222 -5 171 1007 1267 112 144 -346 -502 -3 -341 -455 449 233 -294 -735 -1550 -1534 -1059 -1218 -1084 85 -181 -633 -27 -168 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