File name: Pandora157s1_MexicoCity-Vallejo_20231205_L2Fit_fout2c1d20210802p1-8.txt
File generation date: 20231206T065455.0Z
Data description: Level 2 spectral fitting results file
Data file version: fout2c1p1-8
Local principal investigator: Michel Grutter
Network principal investigator: Alexander Cede
Instrument type: Pandora
Instrument number: 157
Spectrometer number: 1
Processing software version used: BlickP v1.8.49
Instrument operation file used: Pandora157_OF_v5d20190315.txt
Instrument calibration file used: Pandora157s1_CF_v1d20210802.txt
Level 1 file used: Pandora157s1_MexicoCity-Vallejo_20231205_L1_smca1c1d20210802p1-8.txt
Full location name: Vallejo, Secretaria de Medio Ambiente, SEDEMA
Short location name: MexicoCity-Vallejo
Country of location: Mexico
Location latitude [deg]: 19.4830
Location longitude [deg]: -99.1470
Location altitude [m]: 2255
Local noon date: 20231205
Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method)
Data caveats: None
First and last pixel inside fitting window: 221 363
Nominal wavelengths inside fitting window [nm]: 305.0872 305.2277 305.3682 305.5086 305.6490 305.7894 305.9298 306.0702 306.2106 306.3510 306.4914 306.6317 306.7721 306.9124 307.0527 307.1930 307.3333 307.4736 307.6139 307.7542 307.8944 308.0347 308.1749 308.3151 308.4553 308.5955 308.7357 308.8759 309.0161 309.1563 309.2964 309.4365 309.5767 309.7168 309.8569 309.9970 310.1371 310.2771 310.4172 310.5573 310.6973 310.8373 310.9773 311.1173 311.2573 311.3973 311.5373 311.6773 311.8172 311.9572 312.0971 312.2370 312.3769 312.5168 312.6567 312.7966 312.9364 313.0763 313.2161 313.3560 313.4958 313.6356 313.7754 313.9152 314.0550 314.1947 314.3345 314.4742 314.6139 314.7537 314.8934 315.0331 315.1728 315.3124 315.4521 315.5917 315.7314 315.8710 316.0106 316.1502 316.2898 316.4294 316.5690 316.7086 316.8481 316.9877 317.1272 317.2667 317.4062 317.5457 317.6852 317.8247 317.9641 318.1036 318.2430 318.3825 318.5219 318.6613 318.8007 318.9401 319.0794 319.2188 319.3581 319.4975 319.6368 319.7761 319.9154 320.0547 320.1940 320.3333 320.4725 320.6118 320.7510 320.8902 321.0294 321.1686 321.3078 321.4470 321.5862 321.7253 321.8645 322.0036 322.1427 322.2818 322.4209 322.5600 322.6991 322.8382 322.9772 323.1163 323.2553 323.3943 323.5333 323.6723 323.8113 323.9503 324.0892 324.2282 324.3671 324.5060 324.6449 324.7838 324.9227
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Column 1: Two letter code of measurement routine
Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601)
Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement
Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.)
Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.)
Column 6: Total duration of measurement set in seconds
Column 7: Data processing type index
Column 8: Solar zenith angle for center-time of measurement in degree
Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 10: Lunar zenith angle for center-time of measurement in degree
Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise
Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used
Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon
Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used
Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4)
Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error
Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done
Column 18: rms of unweighted fitting residuals, -9=fitting not successful
Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used
Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given
Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful
Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 27: Ozone effective temperature [K]
Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful
Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful
Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful
Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful
Column 38: Sulfur dioxide effective temperature [K]
Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful
Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful
Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful
Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful
Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction
Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting
Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting
Column 46: Lower limit used for wavelength scaling [nm]
Column 47: Upper limit used for wavelength scaling [nm]
Column 48: Order of smoothing polynomial
Column 49: Smoothing polynomial coefficient, order 0
Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful
Column 54: Smoothing polynomial coefficient, order 1
Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful
Column 59: Smoothing polynomial coefficient, order 2
Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful
Column 64: Smoothing polynomial coefficient, order 3
Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful
Column 69: Mean value of measured data inside fitting window [same units as measurements]
Column 70: Wavelength change polynomial coefficient, order 0
Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful
Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination
Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination
Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large
Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality
Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature
Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1)
Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined
Column 84: Wavelength effective temperature [°C], 999=no effective temperature given
Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher)
Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination
Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting
Column 88: Number of bright count cycles
Column 89: Number of dark count cycles
Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions
Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions
Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal
Column 93: Integration time [ms]
Column 94: Temperature at electronics board [°C], 999=no temperature signal
Column 95: Spectrometer control temperature [°C], 999=no temperature signal
Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal
Column 97: Temperature in head sensor [°C], 999=no temperature signal
Column 98: Humidity in head sensor [%], -9=no humidity signal
Column 99: Pressure in head sensor [hPa], -9=no pressure signal
Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting
Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given
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SS 20231205T144316.2Z 8739.613383 291 1 49.70 2 68.85 124.75 28.48 249.16 0.00 1 0.00 1 0 25 1.587e-02 6.338e-03 8.263e-03 1.752e-03 2.876697e-01 9.069917e-04 3.098463e-03 -6.000000e+00 9.411617e-03 224.17 -2.00 3.11 -2.00 318.30 0.00e+00 1.088020e-03 1.706385e-04 1.198208e-04 -6.000000e+00 4.167916e-04 280.32 -2.00 20.00 -2.00 317.61 0.00e+00 2.747 0.000 302.00 328.00 3 3.4331e+00 2.4275e-03 2.4699e-02 -6.0000e+00 2.3183e-02 2.5015e-02 2.7578e-03 1.3206e-02 -6.0000e+00 2.5187e-02 -1.8177e-03 1.7635e-03 6.5074e-03 -6.0000e+00 1.5031e-02 -6.8164e-03 8.9522e-04 2.1046e-03 -6.0000e+00 6.3497e-03 1.4579e-03 -2.2485e-04 5.7364e-05 2.6758e-05 -6.0000e+00 4.8876e-04 3.3743e-03 2.7607e-05 11 1 0 11 8 0 99.87 18.48 0.35 0.00337 0.00168 80 17 1 8 0 621.150 20.96 15.01 18.48 25.94 24.0 785.54 -2953 -5050 -9671 -5495 -6460 -2401 -2445 1693 -2140 -2170 -4946 -1510 -2970 -999 609 281 -353 944 -474 1617 55 -851 657 219 987 -1177 -1110 -1811 397 1073 1402 2033 741 -1046 -1422 396 -285 937 338 -1457 -1109 -842 -1001 -781 -248 -915 -643 24 -9 922 1359 957 1132 909 773 539 682 -34 687 720 1052 1366 1374 800 -724 -503 530 674 1782 693 -703 -147 -13 38 -78 -57 381 512 1126 47 -657 -1265 -1661 -1115 -922 -802 -742 -244 -371 -308 451 951 1072 1428 1569 347 472 48 -497 -933 -331 -532 454 755 -630 -972 -844 -610 -121 170 -101 -117 -121 2 422 810 1119 726 199 -520 -780 -550 -125 120 450 609 1089 1475 995 364 27 -281 -3 324 121 -118 -276 -23 -428 -297 -179 -207 18 -204 -385 -778 -399 -436 -152 -164 121 -174 -184 -438 -137 -309 -118 80 41 -55 151 -80 276 10 -152 118 42 196 -245 -228 -358 73 197 273 429 170 -248 -327 90 -71 268 115 -563 -467 -372 -456 -359 -114 -421 -291 11 -4 408 630 477 598 505 444 318 407 -20 402 422 635 881 958 592 -544 -357 350 438 1220 532 -578 -125 -11 32 -61 -41 255 329 752 34 -541 -1154 -1587 -1122 -986 -913 -866 -291 -443 -355 496 956 1026 1329 1531 365 551 60 -663 -1245 -416 -637 514 866 -779 -1281 -1134 -857 -178 259 -162 -191 -194 4 600 1114 1516 1023 290 -808 -1248 -873 -192 178 651 839 1431 1932 1378 543 42 -450 -4 550 211 -216 -524 -45 -813 -568 -332 -368 32
SS 20231205T145403.8Z 8739.620877 294 1 5.56 2 66.78 126.25 30.86 251.45 0.00 1 0.00 1 0 17 2.232e-02 9.953e-03 2.296e-02 7.743e-03 2.689301e-01 4.029551e-03 2.919794e-03 -6.000000e+00 1.323296e-02 224.17 -2.00 3.11 -2.00 317.20 0.00e+00 1.561538e-03 5.688227e-04 8.480460e-05 -6.000000e+00 5.861502e-04 280.32 -2.00 20.00 -2.00 316.52 0.00e+00 2.518 0.000 302.00 328.00 3 4.4068e+00 1.0526e-02 2.2732e-02 -6.0000e+00 3.2596e-02 5.2990e-02 1.1835e-02 1.2239e-02 -6.0000e+00 3.5418e-02 -1.6215e-02 7.0565e-03 6.0685e-03 -6.0000e+00 2.1136e-02 -4.5250e-04 3.4212e-03 2.0231e-03 -6.0000e+00 8.9255e-03 6.6518e-04 -8.6862e-04 2.4729e-04 2.4798e-05 -6.0000e+00 6.8753e-04 3.8641e-03 -4.7882e-05 12 9 9 12 1 1 999.00 18.48 0.44 0.00386 -0.00266 1 4 1 8 0 2774.190 20.96 15.00 18.48 26.54 24.0 785.69 -2972 -1428 4908 -6702 -2426 1894 -2870 -6209 -689 -13572 -1247 6889 1837 -455 -6537 -773 -1750 -3543 -1999 -1157 2830 2772 4274 3121 -2696 -3881 -2210 2530 3281 1247 1968 4123 1248 2493 -931 1673 -3253 1016 33 606 -1293 126 -1000 916 932 -1552 -52 -768 -929 762 -924 2451 -356 1408 187 -650 1723 276 723 1675 1674 1008 686 926 -648 -1363 840 795 1336 2059 1023 384 -552 -499 -2248 -746 -653 1930 -485 806 -1283 -1029 -2735 -1455 -1169 -739 -345 -770 -57 -977 179 1536 -433 2439 448 -876 736 -903 140 278 -669 -744 -489 1118 -1172 -641 -159 -1290 495 2008 608 1383 -415 70 -102 208 2176 -292 -644 -1005 -572 -213 920 -264 -45 2185 423 619 438 -813 -573 -17 83 339 334 -211 121 3 -250 -225 -255 -439 -121 -355 -181 593 -853 -271 198 -333 -814 -93 -2128 -177 948 299 -86 -1458 -178 -428 -908 -524 -309 745 731 1131 873 -819 -1222 -681 717 881 340 564 1253 407 822 -307 536 -1174 400 15 310 -721 72 -594 540 550 -936 -31 -448 -536 437 -560 1530 -237 965 132 -469 1229 198 516 1184 1222 778 562 789 -554 -1129 649 609 1071 1764 944 365 -529 -465 -2022 -616 -507 1427 -375 669 -1173 -1013 -2857 -1572 -1317 -869 -419 -959 -71 -1187 206 1653 -447 2422 465 -983 879 -1152 185 366 -856 -906 -576 1318 -1465 -832 -212 -1793 707 2950 930 2128 -632 102 -143 280 2854 -400 -915 -1491 -862 -318 1347 -379 -63 2898 552 811 593 -1161 -842 -25 125 529 537 -353 205 5 -432 -386 -430 -721 -197
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