File name: Pandora157s1_MexicoCity-Vallejo_20231217_L2Fit_fout2c1d20210802p1-8.txt File generation date: 20240202T184034.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Michel Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 157 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora157_OF_v5d20190315.txt Instrument calibration file used: Pandora157s1_CF_v1d20210802.txt Level 1 file used: Pandora157s1_MexicoCity-Vallejo_20231217_L1_smca1c1d20210802p1-8.txt Full location name: Vallejo, Secretaria de Medio Ambiente, SEDEMA Short location name: MexicoCity-Vallejo Country of location: Mexico Location latitude [deg]: 19.4830 Location longitude [deg]: -99.1470 Location altitude [m]: 2255 Local noon date: 20231217 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0872 305.2277 305.3682 305.5086 305.6490 305.7894 305.9298 306.0702 306.2106 306.3510 306.4914 306.6317 306.7721 306.9124 307.0527 307.1930 307.3333 307.4736 307.6139 307.7542 307.8944 308.0347 308.1749 308.3151 308.4553 308.5955 308.7357 308.8759 309.0161 309.1563 309.2964 309.4365 309.5767 309.7168 309.8569 309.9970 310.1371 310.2771 310.4172 310.5573 310.6973 310.8373 310.9773 311.1173 311.2573 311.3973 311.5373 311.6773 311.8172 311.9572 312.0971 312.2370 312.3769 312.5168 312.6567 312.7966 312.9364 313.0763 313.2161 313.3560 313.4958 313.6356 313.7754 313.9152 314.0550 314.1947 314.3345 314.4742 314.6139 314.7537 314.8934 315.0331 315.1728 315.3124 315.4521 315.5917 315.7314 315.8710 316.0106 316.1502 316.2898 316.4294 316.5690 316.7086 316.8481 316.9877 317.1272 317.2667 317.4062 317.5457 317.6852 317.8247 317.9641 318.1036 318.2430 318.3825 318.5219 318.6613 318.8007 318.9401 319.0794 319.2188 319.3581 319.4975 319.6368 319.7761 319.9154 320.0547 320.1940 320.3333 320.4725 320.6118 320.7510 320.8902 321.0294 321.1686 321.3078 321.4470 321.5862 321.7253 321.8645 322.0036 322.1427 322.2818 322.4209 322.5600 322.6991 322.8382 322.9772 323.1163 323.2553 323.3943 323.5333 323.6723 323.8113 323.9503 324.0892 324.2282 324.3671 324.5060 324.6449 324.7838 324.9227 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20231217T152906.3Z 8751.645212 111 1 49.68 2 61.95 131.68 116.43 99.26 0.00 1 0.00 1 0 17 1.303e-02 7.206e-03 7.229e-03 2.273e-03 2.435427e-01 1.175746e-03 2.643580e-03 -6.000000e+00 7.715108e-03 223.77 -2.00 3.11 -2.00 317.52 0.00e+00 4.678937e-04 1.783969e-04 7.020975e-05 -6.000000e+00 3.417247e-04 280.00 -2.00 20.00 -2.00 316.83 0.00e+00 2.117 0.000 302.00 328.00 3 4.2815e+00 3.0862e-03 1.9551e-02 -6.0000e+00 1.8989e-02 5.4609e-02 3.4809e-03 1.1022e-02 -6.0000e+00 2.0638e-02 -1.4665e-03 2.1017e-03 5.4763e-03 -6.0000e+00 1.2317e-02 -6.9481e-03 1.0277e-03 1.6276e-03 -6.0000e+00 5.2059e-03 1.0584e-03 3.9815e-05 7.4121e-05 2.1663e-05 -6.0000e+00 4.0122e-04 3.8670e-03 3.9493e-05 11 9 0 11 8 0 99.94 18.29 0.45 0.00387 0.00417 60 12 1 8 0 827.790 20.87 15.00 18.29 25.96 24.3 784.94 -2846 -3744 -3857 -4018 -5454 -4105 914 -2189 -1992 -2592 -3085 -1087 -661 156 -67 272 -1251 285 2758 592 884 1164 907 1364 67 -1960 286 -167 872 1685 2408 1678 608 -1246 -1156 499 95 399 911 -817 -637 -1019 -859 -1200 -200 -786 -575 -884 -1256 1100 920 973 709 1552 440 766 573 192 1057 537 1857 1398 869 644 -519 27 528 342 1410 1481 -2087 -34 -272 -202 -294 -306 494 331 758 -218 -453 -1783 -1603 -1386 -930 -774 -712 -61 -163 -217 319 740 819 1820 1639 346 800 328 -399 -691 -348 -621 584 843 -731 -1228 -886 -641 42 675 52 -455 -405 54 531 1158 1047 521 450 -615 -628 -600 -262 148 483 750 1104 1805 548 372 7 -482 -235 253 131 -285 173 -206 -319 -487 3 -93 -103 -323 -458 -472 -459 -579 -417 95 -257 -254 -344 -422 -152 -101 27 -13 57 -276 64 627 141 213 280 224 351 18 -559 80 -44 218 412 612 462 179 -377 -337 143 30 145 380 -396 -335 -564 -487 -687 -113 -443 -317 -477 -669 577 506 568 438 993 293 518 393 132 707 361 1272 1026 676 525 -424 21 381 243 1049 1218 -1892 -32 -252 -180 -249 -235 350 224 530 -170 -387 -1694 -1624 -1453 -1033 -915 -870 -76 -203 -266 363 781 795 1729 1625 372 945 418 -538 -931 -441 -747 664 975 -913 -1605 -1209 -913 61 1035 85 -732 -643 80 735 1528 1365 706 636 -928 -976 -928 -394 213 672 990 1417 2291 738 523 10 -727 -362 402 219 -493 306 -374 -584 -878 5 -160 -173 SS 20231217T155825.4Z 8751.665571 126 1 49.70 2 57.01 136.98 109.88 101.02 0.00 1 0.00 1 0 25 9.432e-03 6.535e-03 6.987e-04 3.180e-04 2.075548e-01 1.652680e-04 2.277069e-03 -6.000000e+00 5.585312e-03 223.77 -2.00 3.11 -2.00 316.49 0.00e+00 3.190539e-04 1.964781e-05 3.234625e-05 -6.000000e+00 2.473676e-04 280.00 -2.00 20.00 -2.00 315.84 0.00e+00 1.831 0.000 302.00 328.00 3 1.3547e+00 4.2710e-04 1.6828e-02 -6.0000e+00 1.3747e-02 2.3320e-02 4.7849e-04 9.3782e-03 -6.0000e+00 1.4940e-02 2.7689e-04 2.7822e-04 4.6645e-03 -6.0000e+00 8.9166e-03 -5.8471e-03 1.2963e-04 1.3572e-03 -6.0000e+00 3.7691e-03 2.6541e-02 1.3596e-04 1.0195e-05 1.8961e-05 -6.0000e+00 2.9042e-04 3.1461e-03 4.6782e-05 11 9 0 11 8 0 99.94 18.29 0.27 0.00315 0.00417 830 172 1 8 0 59.790 20.87 15.00 18.29 27.63 24.4 785.17 -1536 -2169 -3146 -3969 -3093 -1261 63 395 -157 -1717 -1337 -28 289 338 349 -351 -392 645 411 959 402 818 1277 982 737 35 -549 -339 701 1407 1858 1742 944 -1229 -1633 -142 -378 182 -168 -1094 -1214 -911 -750 -869 -403 -654 -660 -448 -162 631 970 891 894 817 423 994 552 318 628 821 1351 1340 1055 407 -298 -461 254 542 1567 702 -88 -285 -300 -171 -245 -205 311 420 699 -102 -974 -1493 -1857 -1351 -950 -972 -658 -395 -307 -166 220 494 766 1492 1210 763 596 176 -390 -839 -506 -473 425 578 -493 -1059 -660 -529 -85 282 39 -149 -119 124 440 845 1086 567 232 -371 -637 -435 -86 124 624 665 871 1506 1034 355 111 -201 -67 263 1 -217 -159 -194 -356 -374 -219 -339 -74 -278 -419 -609 -721 -522 -202 11 73 -31 -352 -273 -6 66 87 100 -106 -122 205 135 321 137 277 439 353 278 13 -210 -122 242 473 645 645 361 -482 -635 -54 -153 85 -90 -659 -795 -607 -510 -595 -274 -441 -445 -293 -103 400 637 619 639 608 325 772 436 250 486 634 1071 1105 933 369 -268 -398 207 430 1299 633 -85 -286 -301 -166 -227 -177 248 319 545 -86 -898 -1478 -1967 -1469 -1095 -1168 -814 -502 -389 -208 255 546 794 1482 1249 839 707 223 -511 -1099 -638 -568 486 674 -606 -1388 -883 -738 -121 413 59 -230 -177 176 599 1077 1391 739 315 -538 -936 -638 -125 174 845 875 1094 1865 1342 481 154 -288 -97 387 2 -346 -263 -320 -593 -614 -356 -533 -116 SS 20231217T160740.6Z 8751.671997 129 1 50.56 2 55.55 138.83 107.82 101.59 0.00 1 0.00 1 0 25 9.447e-03 6.708e-03 3.223e-04 1.641e-04 1.998249e-01 8.579795e-05 2.203199e-03 -6.000000e+00 5.592562e-03 223.77 -2.00 3.11 -2.00 316.12 0.00e+00 2.854371e-04 9.342040e-06 2.650299e-05 -6.000000e+00 2.477316e-04 280.00 -2.00 20.00 -2.00 315.48 0.00e+00 1.763 0.000 302.00 328.00 3 2.7182e-01 2.2032e-04 1.6205e-02 -6.0000e+00 1.3765e-02 1.8380e-02 2.4631e-04 9.0269e-03 -6.0000e+00 1.4961e-02 3.5057e-04 1.4262e-04 4.4969e-03 -6.0000e+00 8.9289e-03 -5.5188e-03 6.5380e-05 1.3031e-03 -6.0000e+00 3.7733e-03 8.3893e-02 -2.4667e-04 5.2722e-06 1.8579e-05 -6.0000e+00 2.9091e-04 3.4074e-03 -1.8773e-05 11 8 0 10 0 0 94.01 18.30 0.28 0.00341 0.00155 1816 377 1 8 0 27.310 20.87 15.00 18.30 28.53 24.4 785.16 -1224 -2283 -2933 -4282 -2679 -969 345 747 -17 -1459 -1382 202 448 706 432 -240 -175 607 647 753 412 838 1293 1081 834 100 -544 -354 651 1601 1940 1876 928 -1314 -1586 -239 -247 204 42 -1077 -1211 -961 -861 -873 -482 -666 -708 -433 -262 663 999 815 824 824 520 910 506 230 586 810 1318 1331 997 371 -421 -440 159 633 1601 722 -170 -316 -308 -198 -268 -302 302 420 767 -170 -957 -1471 -1806 -1328 -937 -956 -680 -400 -331 -190 223 474 846 1515 1287 775 566 154 -437 -866 -523 -412 499 669 -509 -1030 -697 -519 -71 271 49 -153 -90 134 498 931 1112 632 260 -379 -644 -435 -86 129 614 638 874 1502 1022 277 41 -249 -48 208 -30 -262 -166 -177 -348 -369 -181 -296 -70 -245 -489 -627 -948 -532 -183 68 162 -4 -361 -341 51 112 197 134 -80 -61 215 236 281 156 316 493 431 348 43 -230 -141 242 577 721 741 389 -565 -657 -97 -109 104 23 -684 -836 -690 -632 -645 -353 -484 -502 -297 -175 439 685 592 630 655 425 756 394 193 485 669 1117 1108 890 348 -392 -382 138 532 1406 652 -168 -325 -317 -197 -249 -255 250 329 617 -151 -881 -1487 -1954 -1508 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