File name: Pandora157s1_MexicoCity-Vallejo_20231223_L2Fit_fwvt1c1d20210802p1-8.txt File generation date: 20240202T185653.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c1p1-8 Local principal investigator: Michel Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 157 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora157_OF_v5d20190315.txt Instrument calibration file used: Pandora157s1_CF_v1d20210802.txt Level 1 file used: Pandora157s1_MexicoCity-Vallejo_20231223_L1_smca1c1d20210802p1-8.txt Full location name: Vallejo, Secretaria de Medio Ambiente, SEDEMA Short location name: MexicoCity-Vallejo Country of location: Mexico Location latitude [deg]: 19.4830 Location longitude [deg]: -99.1470 Location altitude [m]: 2255 Local noon date: 20231223 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 1647 1796 Nominal wavelengths inside fitting window [nm]: 492.1139 492.2344 492.3549 492.4754 492.5959 492.7164 492.8368 492.9573 493.0777 493.1981 493.3185 493.4389 493.5592 493.6796 493.7999 493.9202 494.0405 494.1608 494.2811 494.4013 494.5215 494.6417 494.7619 494.8821 495.0023 495.1224 495.2425 495.3626 495.4827 495.6028 495.7229 495.8429 495.9629 496.0830 496.2030 496.3229 496.4429 496.5628 496.6828 496.8027 496.9226 497.0424 497.1623 497.2822 497.4020 497.5218 497.6416 497.7614 497.8811 498.0009 498.1206 498.2403 498.3600 498.4797 498.5994 498.7190 498.8386 498.9582 499.0778 499.1974 499.3170 499.4365 499.5560 499.6756 499.7950 499.9145 500.0340 500.1534 500.2729 500.3923 500.5117 500.6310 500.7504 500.8697 500.9891 501.1084 501.2277 501.3470 501.4662 501.5855 501.7047 501.8239 501.9431 502.0623 502.1814 502.3006 502.4197 502.5388 502.6579 502.7770 502.8960 503.0151 503.1341 503.2531 503.3721 503.4911 503.6100 503.7290 503.8479 503.9668 504.0857 504.2046 504.3234 504.4423 504.5611 504.6799 504.7987 504.9175 505.0362 505.1549 505.2737 505.3924 505.5111 505.6297 505.7484 505.8670 505.9856 506.1042 506.2228 506.3414 506.4600 506.5785 506.6970 506.8155 506.9340 507.0525 507.1709 507.2893 507.4078 507.5262 507.6445 507.7629 507.8813 507.9996 508.1179 508.2362 508.3545 508.4727 508.5910 508.7092 508.8274 508.9456 509.0638 509.1820 509.3001 509.4182 509.5364 509.6544 509.7725 509.8906 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20231223T133610.9Z 8757.566793 163 1 5.81 2 84.64 117.18 131.75 321.75 0.00 1 0.00 1 0 15 3.807e-03 3.790e-03 1.664e-03 1.663e-03 4.168215e+03 9.952742e+01 2.940549e+02 -6.000000e+00 2.047957e+02 279.89 -2.00 20.00 -2.00 505.32 0.00e+00 4.989594e-03 4.517786e-05 2.752036e-04 -6.000000e+00 1.052040e-04 279.89 -2.00 20.00 -2.00 500.75 0.00e+00 5.792243e-01 3.217225e-02 5.225825e-02 -6.000000e+00 7.479973e-02 223.67 -2.00 3.11 -2.00 502.29 0.00e+00 9.376 0.004 489.00 513.00 1 4.9956e+00 2.4560e-03 1.2953e-02 -6.0000e+00 5.7166e-03 -3.5861e-02 6.3766e-04 1.0372e-03 -6.0000e+00 1.5058e-03 4.2246e-03 1.3426e-03 1.5363e-04 1.0022e-04 -6.0000e+00 3.6101e-04 5.5847e-03 -2.6098e-05 12 9 1 12 1 1 61.18 18.25 1.83 0.00558 0.01490 3 7 1 7 0 1448.990 20.87 15.00 18.25 19.43 23.8 782.01 -1045 -309 -175 356 639 556 513 639 494 674 203 33 -227 -296 -261 -140 -111 -206 251 141 399 71 237 208 381 607 56 -9 -158 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-159 -31 -100 21 136 319 529 830 649 842 462 625 357 -57 475 311 43 318 325 131 249 93 -336 205 428 6 -334 88 156 -134 203 210 431 416 175 41 -226 -69 -278 -147 -436 -433 -260 SQ 20231223T134756.4Z 8757.574958 166 1 27.19 2 82.19 118.31 133.31 324.65 0.00 1 0.00 1 0 15 2.572e-03 2.572e-03 1.327e-04 1.326e-04 3.437731e+03 7.856991e+00 2.422644e+02 -6.000000e+00 1.383660e+02 279.89 -2.00 20.00 -2.00 505.31 0.00e+00 3.606049e-03 3.599131e-06 1.984830e-04 -6.000000e+00 7.107832e-05 279.89 -2.00 20.00 -2.00 500.65 0.00e+00 4.090163e-01 2.576731e-03 3.966650e-02 -6.000000e+00 5.053533e-02 223.67 -2.00 3.11 -2.00 502.21 0.00e+00 6.880 0.001 489.00 513.00 1 2.0062e+00 1.9682e-04 9.4917e-03 -6.0000e+00 3.8622e-03 -2.2622e-02 5.1163e-05 8.0817e-04 -6.0000e+00 1.0173e-03 1.1401e-01 1.5122e-03 1.2268e-05 7.3624e-05 -6.0000e+00 2.4391e-04 3.8660e-03 -1.3043e-05 10 0 0 10 0 0 68.97 18.25 1.67 0.00387 0.01436 521 108 1 7 0 52.170 20.77 15.00 18.25 19.64 23.7 781.86 -475 -290 -203 249 422 410 424 290 407 276 -27 -128 -229 -346 -321 -150 -60 -232 37 239 75 258 312 174 320 338 11 -192 166 -208 -342 26 -23 -274 51 292 18 -100 -66 -108 -114 95 208 290 276 280 264 34 -261 -231 -428 -501 -284 -321 -260 -160 32 98 219 229 170 183 252 170 165 183 71 -288 -274 -69 -237 -217 -62 -277 -275 -123 -127 -363 -416 -197 -399 -344 -34 -227 -255 -200 -171 -113 -112 -71 174 18 -60 196 306 91 29 -248 -342 -366 -361 -183 -266 -545 -314 -221 -208 80 69 -108 -37 197 280 373 592 610 400 285 403 222 214 468 374 -51 168 114 58 353 350 -145 -17 33 -252 -151 196 -163 -204 137 169 23 201 189 141 225 -39 -247 -368 -216 -251 -293 -452 -274 -199 251 421 419 439 302 419 280 -27 -127 -223 -344 -319 -146 -59 -236 37 241 76 261 316 178 328 347 11 -194 166 -203 -331 26 -24 -279 53 302 18 -102 -67 -108 -116 97 215 296 284 288 270 35 -267 -230 -415 -491 -276 -309 -259 -164 33 100 223 233 174 188 260 176 169 183 70 -291 -273 -68 -232 -214 -62 -272 -272 -121 -126 -354 -402 -190 -388 -337 -34 -225 -249 -196 -168 -110 -109 -70 173 18 -60 195 309 91 28 -242 -327 -344 -338 -174 -255 -543 -310 -218 -209 79 67 -107 -36 197 285 382 610 633 408 291 408 227 216 465 371 -51 170 116 59 356 353 -147 -17 33 -246 -145 188 -159 -204 135 170 24 205 194 145 232 -41 -254 -372 -213 -249 -290 SQ 20231223T134823.9Z 8757.575277 166 2 27.19 2 82.09 118.36 133.37 324.76 0.00 1 0.00 1 0 15 2.603e-03 2.604e-03 1.343e-04 1.342e-04 3.464870e+03 7.981750e+00 2.459610e+02 -6.000000e+00 1.400482e+02 279.89 -2.00 20.00 -2.00 505.30 0.00e+00 3.611945e-03 3.640514e-06 1.992310e-04 -6.000000e+00 7.193954e-05 279.89 -2.00 20.00 -2.00 500.63 0.00e+00 4.017385e-01 2.609014e-03 3.965539e-02 -6.000000e+00 5.114320e-02 223.67 -2.00 3.11 -2.00 502.19 0.00e+00 6.808 0.001 489.00 513.00 1 2.0335e+00 1.9923e-04 9.4389e-03 -6.0000e+00 3.9088e-03 -2.1628e-02 5.1845e-05 8.0661e-04 -6.0000e+00 1.0294e-03 1.1187e-01 1.4866e-03 1.2422e-05 7.4021e-05 -6.0000e+00 2.4687e-04 4.1227e-03 -5.2050e-06 10 0 0 10 0 0 86.75 18.25 1.67 0.00412 0.01443 521 108 1 7 0 52.170 20.77 15.00 18.25 19.66 23.8 781.86 -434 -244 -158 302 402 377 401 328 408 310 -32 -136 -229 -358 -340 -138 -33 -271 30 252 100 247 342 217 342 365 74 -170 220 -133 -254 75 -67 -311 5 176 -61 -132 -127 -117 -129 84 211 268 258 271 264 36 -292 -257 -460 -495 -268 -305 -267 -145 4 95 212 255 162 133 251 131 161 129 13 -320 -287 -57 -244 -157 -26 -298 -318 -123 -84 -359 -396 -194 -359 -275 34 -156 -283 -231 -216 -140 -219 -59 162 10 -76 233 349 84 16 -259 -359 -368 -361 -225 -275 -605 -322 -197 -228 55 30 -79 -30 175 268 354 601 646 439 300 435 233 230 474 388 -24 208 116 32 365 364 -153 9 24 -259 -178 168 -159 -187 123 199 43 223 199 154 199 -23 -235 -371 -202 -247 -285 -410 -237 -155 303 400 383 413 339 418 313 -32 -134 -229 -355 -336 -137 -33 -274 31 260 103 256 355 220 348 372 75 -175 219 -129 -244 72 -68 -315 5 181 -63 -133 -127 -117 -130 86 217 279 264 277 276 38 -297 -254 -457 -483 -259 -301 -264 -148 4 96 215 258 165 136 258 134 164 128 13 -322 -284 -55 -238 -153 -25 -300 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