File name: Pandora157s1_MexicoCity-Vallejo_20240118_L2Fit_fout2c1d20210802p1-8.txt File generation date: 20240119T065155.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Michel Grutter Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 157 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora157_OF_v5d20190315.txt Instrument calibration file used: Pandora157s1_CF_v1d20210802.txt Level 1 file used: Pandora157s1_MexicoCity-Vallejo_20240118_L1_smca1c1d20210802p1-8.txt Full location name: Vallejo, Secretaria de Medio Ambiente, SEDEMA Short location name: MexicoCity-Vallejo Country of location: Mexico Location latitude [deg]: 19.4830 Location longitude [deg]: -99.1470 Location altitude [m]: 2255 Local noon date: 20240118 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 221 363 Nominal wavelengths inside fitting window [nm]: 305.0872 305.2277 305.3682 305.5086 305.6490 305.7894 305.9298 306.0702 306.2106 306.3510 306.4914 306.6317 306.7721 306.9124 307.0527 307.1930 307.3333 307.4736 307.6139 307.7542 307.8944 308.0347 308.1749 308.3151 308.4553 308.5955 308.7357 308.8759 309.0161 309.1563 309.2964 309.4365 309.5767 309.7168 309.8569 309.9970 310.1371 310.2771 310.4172 310.5573 310.6973 310.8373 310.9773 311.1173 311.2573 311.3973 311.5373 311.6773 311.8172 311.9572 312.0971 312.2370 312.3769 312.5168 312.6567 312.7966 312.9364 313.0763 313.2161 313.3560 313.4958 313.6356 313.7754 313.9152 314.0550 314.1947 314.3345 314.4742 314.6139 314.7537 314.8934 315.0331 315.1728 315.3124 315.4521 315.5917 315.7314 315.8710 316.0106 316.1502 316.2898 316.4294 316.5690 316.7086 316.8481 316.9877 317.1272 317.2667 317.4062 317.5457 317.6852 317.8247 317.9641 318.1036 318.2430 318.3825 318.5219 318.6613 318.8007 318.9401 319.0794 319.2188 319.3581 319.4975 319.6368 319.7761 319.9154 320.0547 320.1940 320.3333 320.4725 320.6118 320.7510 320.8902 321.0294 321.1686 321.3078 321.4470 321.5862 321.7253 321.8645 322.0036 322.1427 322.2818 322.4209 322.5600 322.6991 322.8382 322.9772 323.1163 323.2553 323.3943 323.5333 323.6723 323.8113 323.9503 324.0892 324.2282 324.3671 324.5060 324.6449 324.7838 324.9227 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240118T135414.1Z 8783.579330 52 1 50.17 2 82.04 115.20 143.73 26.98 0.00 1 0.00 1 0 25 4.795e-01 2.296e-02 3.576e-01 1.670e-02 6.488668e-01 9.662319e-03 6.533051e-03 -6.000000e+00 2.900277e-01 223.35 -2.00 3.11 -2.00 321.52 0.00e+00 4.766979e-03 4.944656e-03 1.493263e-03 -6.000000e+00 1.413622e-02 279.47 -2.00 20.00 -2.00 321.00 0.00e+00 6.770 0.001 302.00 328.00 3 3.0989e+00 3.4091e-02 6.0793e-02 -6.0000e+00 7.1989e-01 2.2609e-01 4.4962e-02 3.4454e-02 -6.0000e+00 7.8744e-01 -3.3051e-01 4.3090e-02 1.6161e-02 -6.0000e+00 4.6163e-01 1.3115e-01 2.0451e-02 6.3556e-03 -6.0000e+00 1.9407e-01 6.7991e-05 -2.2541e-03 5.5986e-04 8.2309e-05 -6.0000e+00 1.5450e-02 6.4274e-03 -8.5617e-05 12 9 8 11 8 0 98.73 18.50 0.50 0.00643 -0.01051 18 4 1 8 0 2786.560 20.96 15.00 18.50 22.96 23.7 784.61 -55929 900000 -224690 900000 -31659 123379 900000 900000 900000 -109937 900000 283561 38555 -121452 900000 -41588 -73205 105162 900000 900000 -43115 -38038 -79297 -36309 -56448 59972 -41701 32675 -38203 -80453 900000 33953 -26496 171685 -33882 33622 -16219 1923 47739 2149 111133 41319 72643 31363 21850 22495 18520 -17401 22872 15021 49997 -4786 13324 3326 8995 25218 -1536 5615 -13350 18193 18786 -1099 1764 -1415 2398 12239 4987 -243 14876 1731 9905 -43 18649 -1805 259 -1608 443 10108 -2704 -4830 -932 641 -9407 -4795 -2775 -2802 -1642 805 3972 -536 -53 -615 2890 5443 -1960 534 -3545 1897 1189 288 3130 1469 -2478 -4763 -2210 -3768 -1661 -2913 904 -3 1458 -935 -801 -2727 22 -96 3660 1016 -272 1379 -1234 -405 -753 2592 3123 183 115 3210 2911 21 -1740 -620 530 879 -455 1145 -154 -225 -1366 -696 74 1062 -733 -909 900000 -8020 900000 -515 2005 900000 900000 900000 -1787 900000 4609 627 -3613 900000 -828 -2224 1709 900000 900000 -1201 -1009 -3242 -1036 -2088 975 -1376 531 -1223 -4187 900000 805 -1274 2791 -1815 939 -796 93 1778 144 2890 2271 3087 2044 1576 1645 1444 -1988 1851 1410 3678 -662 1699 500 1347 3363 -270 912 -2562 2550 2714 -212 369 -339 587 2710 1177 -62 3612 535 3115 -16 5543 -623 81 -462 118 2492 -840 -1794 -384 296 -5273 -2750 -1660 -1781 -1084 533 2542 -347 -33 -358 1567 2961 -1270 388 -3101 1764 1210 300 3041 1326 -2155 -4201 -2016 -3672 -1680 -3199 1046 -4 2059 -1437 -1246 -4213 32 -133 4921 1438 -410 2125 -1957 -627 -1126 3625 4193 247 152 4234 4241 34 -3251 -1227 1084 1901 -1061 2766 -387 -577 -3533 -1739 174 2357 -1604 SS 20240118T140935.8Z 8783.589998 57 1 10.99 2 78.79 116.74 141.97 32.11 0.00 1 0.00 1 0 25 3.274e-01 1.392e-02 1.537e-01 8.250e-03 5.005241e-01 4.405862e-03 5.255311e-03 -6.000000e+00 1.934848e-01 223.35 -2.00 3.11 -2.00 320.22 0.00e+00 2.058144e-03 1.533336e-03 1.047534e-03 -6.000000e+00 9.059918e-03 279.47 -2.00 20.00 -2.00 319.63 0.00e+00 4.973 0.001 302.00 328.00 3 3.1396e+00 1.3053e-02 4.4337e-02 -6.0000e+00 4.7590e-01 6.4876e-02 1.5880e-02 2.3422e-02 -6.0000e+00 5.1760e-01 -7.4920e-02 1.3581e-02 1.2032e-02 -6.0000e+00 3.0900e-01 2.4694e-02 6.9110e-03 3.6851e-03 -6.0000e+00 1.3157e-01 2.8624e-04 -1.5195e-03 2.6500e-04 5.5011e-05 -6.0000e+00 1.0126e-02 4.8443e-03 -3.8477e-05 12 9 9 12 1 1 79.12 18.50 0.44 0.00484 -0.00657 5 6 1 8 0 1830.000 20.96 15.00 18.50 24.12 23.8 785.13 -85355 900000 -108689 -106008 -117718 -72356 266519 -55698 -5925 -64077 900000 -37726 11764 -6625 -17783 -12134 -19525 59123 -28965 23578 -40600 27312 -43183 18512 -4463 -16234 3344 -4645 33484 -13837 16394 -6713 2287 7888 -2194 13305 -22940 10120 -5201 3631 -271 1898 -3941 -991 9256 1577 13949 -5515 7098 5869 18761 6348 586 4028 784 7642 -889 1262 -4836 3189 2001 2677 5494 1216 2193 983 4824 941 3666 -859 2138 1229 -1029 1288 -2853 258 -4333 1775 -1551 -358 -1893 -1130 -1471 -2563 -103 -2681 1391 -1959 -147 -1404 -1016 1416 -648 1171 611 1068 830 -421 -85 -1574 372 -2305 1856 834 347 -2048 -406 -1077 -214 -585 -875 599 -500 838 38 1172 953 1406 -447 -226 710 -728 1241 208 1633 -33 555 1228 -32 556 23 884 -285 -416 -354 -1069 151 125 420 -649 -457 -340 377 -1842 900000 -3428 -3165 -3703 -1458 2143 -1149 -83 -1680 900000 -910 210 -173 -619 -460 -879 1353 -1635 839 -2751 980 -3160 799 -257 -1094 187 -275 1355 -935 924 -542 188 639 -193 1023 -2722 1028 -733 547 -47 343 -788 -197 1679 313 2495 -1204 1405 1238 3810 1585 167 1183 250 2357 -302 422 -1674 1024 673 972 2129 530 977 434 2008 414 1704 -460 1213 728 -620 731 -1576 127 -2094 801 -775 -201 -1225 -807 -1138 -2118 -87 -2469 1295 -1922 -143 -1334 -913 1178 -527 942 529 1020 886 -500 -107 -2011 450 -2652 1954 888 388 -2471 -505 -1416 -298 -879 -1400 977 -823 1329 58 1696 1384 2084 -699 -369 1162 -1187 1935 320 2393 -48 778 1739 -48 912 40 1596 -539 -815 -728 -2294 327 276 926 -1423 -964 -692 748 SS 20240118T141923.2Z 8783.596796 63 1 34.33 2 76.73 117.79 140.72 35.14 0.00 1 0.00 1 0 25 6.589e-02 6.896e-03 3.171e-02 2.266e-03 4.289502e-01 1.194007e-03 4.539346e-03 -6.000000e+00 3.892318e-02 223.35 -2.00 3.11 -2.00 319.75 0.00e+00 2.361679e-03 3.556539e-04 4.017094e-04 -6.000000e+00 1.723775e-03 279.47 -2.00 20.00 -2.00 319.13 0.00e+00 4.255 0.000 302.00 328.00 3 2.4327e+00 3.4061e-03 3.7965e-02 -6.0000e+00 9.5730e-02 2.0664e-02 4.0312e-03 2.0307e-02 -6.0000e+00 1.0411e-01 -2.4070e-02 3.1923e-03 9.9402e-03 -6.0000e+00 6.2128e-02 3.6340e-04 1.6554e-03 3.7625e-03 -6.0000e+00 2.6251e-02 1.0819e-03 -9.1903e-04 7.3620e-05 4.3882e-05 -6.0000e+00 2.0288e-03 4.3176e-03 -1.1210e-04 12 9 1 12 1 1 84.11 18.50 0.37 0.00432 -0.00259 48 15 1 8 0 700.380 20.96 15.00 18.50 24.81 23.7 784.69 -16224 -26948 1983 -22828 -24629 -34667 -3343 -23316 -19620 -12456 -23968 -15152 -17022 -192 -5388 -1794 -4730 -3741 613 -3405 2558 -3269 1438 -6699 -4492 -4425 -6175 -1704 -4317 2858 1128 2893 289 -2338 -1322 -3153 -3517 -640 1909 75 638 -1974 -204 -977 528 674 -874 2442 430 4008 1209 930 688 1687 442 -40 563 -205 1097 -255 1538 993 673 788 618 883 788 1858 1733 1336 392 -447 -823 -1277 10 -443 1121 516 1005 -105 -862 -1417 -2130 -961 -1373 -656 -834 193 -263 409 506 1453 1554 1769 1902 522 664 41 -386 -1224 -719 -368 592 892 -1043 -1360 -945 -662 -237 75 -244 -290 -376 60 817 896 1323 525 267 -481 -752 -318 -197 20 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