File name: Pandora256s1_MiamiFL-FIU_20240122_L2Fit_fout2c2d20230424p1-8.txt File generation date: 20240313T193401.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v2d20230424.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240122_L1_smca1c2d20230424p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240122 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0391 305.1801 305.3211 305.4621 305.6031 305.7441 305.8850 306.0260 306.1669 306.3078 306.4487 306.5896 306.7305 306.8714 307.0122 307.1531 307.2939 307.4347 307.5756 307.7164 307.8572 307.9979 308.1387 308.2795 308.4202 308.5610 308.7017 308.8424 308.9831 309.1238 309.2645 309.4051 309.5458 309.6864 309.8271 309.9677 310.1083 310.2489 310.3895 310.5301 310.6706 310.8112 310.9517 311.0923 311.2328 311.3733 311.5138 311.6543 311.7948 311.9352 312.0757 312.2161 312.3565 312.4969 312.6374 312.7777 312.9181 313.0585 313.1989 313.3392 313.4795 313.6199 313.7602 313.9005 314.0408 314.1810 314.3213 314.4616 314.6018 314.7420 314.8823 315.0225 315.1627 315.3029 315.4430 315.5832 315.7233 315.8635 316.0036 316.1437 316.2838 316.4239 316.5640 316.7041 316.8441 316.9842 317.1242 317.2642 317.4042 317.5442 317.6842 317.8242 317.9642 318.1041 318.2441 318.3840 318.5239 318.6638 318.8037 318.9436 319.0835 319.2233 319.3632 319.5030 319.6429 319.7827 319.9225 320.0623 320.2020 320.3418 320.4816 320.6213 320.7610 320.9008 321.0405 321.1802 321.3199 321.4595 321.5992 321.7388 321.8785 322.0181 322.1577 322.2973 322.4369 322.5765 322.7161 322.8556 322.9952 323.1347 323.2742 323.4137 323.5532 323.6927 323.8322 323.9716 324.1111 324.2505 324.3900 324.5294 324.6688 324.8082 324.9476 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240122T124945.6Z 8787.534556 203 1 54.22 2 82.40 116.25 119.33 328.67 0.00 1 0.00 1 0 17 5.951e-01 2.439e-02 2.997e-01 8.698e-03 6.930643e-01 4.780437e-03 6.968089e-03 -6.000000e+00 3.400382e-01 224.51 -2.00 3.16 -2.00 321.43 0.00e+00 -9.242944e-03 2.573975e-03 3.960748e-03 -6.000000e+00 1.730028e-02 287.73 -2.00 20.00 -2.00 320.82 0.00e+00 7.020 0.003 302.00 328.00 3 2.2799e+00 1.7814e-02 8.1920e-02 -6.0000e+00 8.3624e-01 3.4823e-01 2.4956e-02 5.3269e-02 -6.0000e+00 9.1410e-01 -4.2263e-01 2.3728e-02 1.7166e-02 -6.0000e+00 5.4505e-01 1.5868e-01 1.0984e-02 1.1961e-02 -6.0000e+00 2.3631e-01 2.7839e-05 -7.6806e-04 2.5197e-04 7.4325e-05 -6.0000e+00 1.6526e-02 1.2989e-02 2.4707e-05 12 8 8 10 0 0 99.94 26.15 0.74 0.01299 0.00722 35 4 1 5 0 1549.000 34.75 20.00 26.15 25.75 5.7 938.00 900000 -122755 900000 900000 -64414 900000 -149081 -98804 -96573 -109030 121783 -125451 900000 -124369 -91459 900000 -63391 -78563 86108 -15551 -52834 -116103 17491 900000 -4003 -46685 900000 -93959 97796 -12939 900000 900000 69439 22448 -25801 900000 315621 264859 79585 22875 16375 108096 86812 192236 541 29302 47245 74684 62939 10969 8453 36658 43687 14906 2139 -4405 38831 3010 2280 48846 -12262 -2063 -578 342 -3502 13111 3285 1188 7996 -1195 18585 886 97 -953 -3145 1089 -4432 -11391 -7610 697 8253 -5492 7222 139 927 2048 -1230 -2669 -2587 3108 870 -4965 1658 -1040 -2404 572 -2153 -73 884 -3612 3202 -5225 -6200 4372 -4616 -1640 2877 2844 821 -1019 -947 3507 -459 1094 -2067 -148 -1968 1712 -1269 -1113 1020 3664 2795 -69 -736 2362 -1556 -9 -420 -1990 -26 -417 255 1075 -25 -738 1266 1123 -86 -426 -283 -301 -1213 900000 -1322 900000 900000 -545 900000 -2065 -988 -1115 -1594 1031 -2510 900000 -3541 -2252 900000 -1512 -2593 729 -303 -1520 -6289 266 900000 -98 -1897 900000 -5806 828 -340 900000 900000 1234 684 -1223 900000 2672 2242 2156 1336 1164 3294 3380 2603 49 1984 2679 3287 3250 1021 902 3320 4068 2031 357 -832 4963 550 403 5209 -2429 -400 -125 82 -922 2863 784 302 2112 -401 5663 338 37 -345 -1059 314 -1260 -3519 -2531 253 3262 -2864 3661 81 573 1337 -872 -1791 -1728 2073 554 -3152 957 -643 -1697 455 -1850 -71 919 -3930 3053 -4889 -5376 3449 -4297 -1571 2787 2966 963 -1373 -1423 5361 -737 1677 -3108 -209 -2868 2521 -2042 -1856 1646 5543 4123 -101 -1050 3160 -2107 -12 -674 -3365 -48 -819 525 2344 -58 -1709 2941 2656 -204 -975 -656 -658 -2605 SS 20240122T131657.8Z 8787.553447 217 1 54.27 2 76.99 119.72 122.10 334.51 0.00 1 0.00 1 0 17 9.979e-02 7.122e-03 4.077e-02 2.316e-03 4.561844e-01 1.164007e-03 4.812457e-03 -6.000000e+00 5.620917e-02 224.51 -2.00 3.16 -2.00 319.61 0.00e+00 5.216526e-05 3.483793e-04 6.333480e-04 -6.000000e+00 2.567646e-03 287.73 -2.00 20.00 -2.00 318.84 0.00e+00 4.327 0.001 302.00 328.00 3 2.9568e+00 3.3394e-03 4.7714e-02 -6.0000e+00 1.3835e-01 1.3838e-02 4.0136e-03 2.1614e-02 -6.0000e+00 1.5057e-01 4.6412e-03 3.2191e-03 1.0515e-02 -6.0000e+00 9.0208e-02 -1.2037e-02 1.6801e-03 2.9520e-03 -6.0000e+00 3.8608e-02 2.3375e-04 -6.3025e-04 6.6318e-05 3.2505e-05 -6.0000e+00 2.6929e-03 1.3211e-02 -5.0158e-05 11 8 0 10 0 0 99.99 26.16 0.41 0.01321 0.00847 168 17 1 5 0 322.980 34.75 20.00 26.16 26.14 5.6 939.77 -16445 -44094 -26567 7334 -40386 10112 -26213 -41895 -36573 -18064 -19761 -40237 -13873 -20505 -1608 3838 -20449 -13122 -5094 -10726 -9613 -18568 -4622 780 -14751 -11878 5470 -13351 -6033 -9802 2997 4701 -1252 -2199 56 3973 -1330 -315 1422 -1132 -432 2517 805 5745 -145 353 1337 1360 1027 1345 533 2970 1761 1710 989 -529 4711 -600 -253 2070 -699 1321 1608 1430 1158 1581 -198 -891 931 723 1323 19 149 381 -394 -1095 -1737 -2006 -1751 -1431 -726 -2185 -1454 -1389 -1074 -516 -305 248 67 1070 906 -189 31 258 -250 597 514 576 -206 -282 -79 -1276 -1049 307 -944 -1066 -262 41 305 640 475 1104 321 98 -405 -22 -88 -127 -89 11 -127 501 391 423 14 300 -281 226 312 -295 -278 -293 -349 123 8 -94 612 417 -119 10 -11 -389 -470 -230 -936 -504 96 -775 114 -462 -994 -942 -420 -482 -1300 -411 -792 -62 163 -1215 -783 -300 -705 -645 -1367 -309 54 -1293 -1073 423 -1194 -480 -833 252 445 -142 -268 6 429 -167 -46 252 -247 -105 632 195 1490 -36 89 371 380 293 363 158 947 616 644 395 -223 1940 -261 -107 846 -303 612 829 812 678 878 -107 -490 548 448 898 14 107 260 -250 -686 -1008 -1149 -1086 -941 -545 -1874 -1239 -1251 -1034 -529 -329 274 74 1131 891 -174 27 223 -237 637 579 731 -263 -383 -101 -1495 -1144 339 -1142 -1366 -351 54 432 991 746 1783 512 148 -614 -32 -127 -192 -144 18 -204 780 630 656 21 428 -388 319 486 -476 -482 -532 -619 228 16 -185 1229 857 -246 20 -21 -752 -890 SS 20240122T132737.0Z 8787.560845 220 1 54.43 2 74.92 121.18 123.03 336.93 0.00 1 0.00 1 0 17 4.080e-02 6.602e-03 2.989e-03 4.893e-04 4.013935e-01 2.436969e-04 4.283478e-03 -6.000000e+00 2.298465e-02 224.51 -2.00 3.16 -2.00 318.31 0.00e+00 9.342402e-04 4.824240e-05 2.882725e-04 -6.000000e+00 1.049802e-03 287.73 -2.00 20.00 -2.00 317.48 0.00e+00 3.770 0.000 302.00 328.00 3 8.1381e-01 6.5719e-04 4.1532e-02 -6.0000e+00 5.6574e-02 -5.4385e-03 7.5308e-04 1.8506e-02 -6.0000e+00 6.1568e-02 -6.7493e-03 4.9777e-04 9.0919e-03 -6.0000e+00 3.6887e-02 -1.3423e-03 2.6045e-04 2.6500e-03 -6.0000e+00 1.5788e-02 3.6398e-03 -3.1886e-04 1.3766e-05 2.8535e-05 -6.0000e+00 1.1010e-03 1.3256e-02 -2.3897e-05 11 8 0 10 0 0 99.93 26.17 0.42 0.01326 0.01086 665 68 1 5 0 81.840 34.75 20.00 26.17 26.37 5.6 941.40 -10936 -9371 -12627 -10310 -17096 -17380 -14418 -12908 -11741 -11407 -12637 -12198 -8857 -6568 -3154 -1115 -1403 -601 248 -633 -510 -619 -118 940 -124 -413 -117 -2337 -2085 -1155 190 1761 1325 -688 -2940 -3015 -2955 -1445 74 364 -199 357 469 588 797 759 502 359 -229 604 1197 1465 1562 1474 1173 1282 1002 434 227 313 847 1545 2119 1848 766 4 -603 -622 378 813 743 347 369 317 -144 -665 -1385 -1803 -1418 -1384 -1389 -1719 -2125 -1679 -1238 -583 -77 256 555 654 623 200 -231 -149 16 198 502 673 106 -130 -512 -955 -591 -291 -929 -1022 -709 -456 162 581 672 433 320 124 -99 56 53 201 218 122 47 356 453 472 477 153 287 759 454 200 -48 -231 -298 36 -27 -101 295 264 -30 -182 -329 -501 -532 -490 -470 -690 -529 -847 -833 -720 -722 -735 -765 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