File name: Pandora256s1_MiamiFL-FIU_20240207_L2Fit_fout2c2d20230424p1-8.txt File generation date: 20240313T190058.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v2d20230424.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240207_L1_smca1c2d20230424p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240207 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0391 305.1801 305.3211 305.4621 305.6031 305.7441 305.8850 306.0260 306.1669 306.3078 306.4487 306.5896 306.7305 306.8714 307.0122 307.1531 307.2939 307.4347 307.5756 307.7164 307.8572 307.9979 308.1387 308.2795 308.4202 308.5610 308.7017 308.8424 308.9831 309.1238 309.2645 309.4051 309.5458 309.6864 309.8271 309.9677 310.1083 310.2489 310.3895 310.5301 310.6706 310.8112 310.9517 311.0923 311.2328 311.3733 311.5138 311.6543 311.7948 311.9352 312.0757 312.2161 312.3565 312.4969 312.6374 312.7777 312.9181 313.0585 313.1989 313.3392 313.4795 313.6199 313.7602 313.9005 314.0408 314.1810 314.3213 314.4616 314.6018 314.7420 314.8823 315.0225 315.1627 315.3029 315.4430 315.5832 315.7233 315.8635 316.0036 316.1437 316.2838 316.4239 316.5640 316.7041 316.8441 316.9842 317.1242 317.2642 317.4042 317.5442 317.6842 317.8242 317.9642 318.1041 318.2441 318.3840 318.5239 318.6638 318.8037 318.9436 319.0835 319.2233 319.3632 319.5030 319.6429 319.7827 319.9225 320.0623 320.2020 320.3418 320.4816 320.6213 320.7610 320.9008 321.0405 321.1802 321.3199 321.4595 321.5992 321.7388 321.8785 322.0181 322.1577 322.2973 322.4369 322.5765 322.7161 322.8556 322.9952 323.1347 323.2742 323.4137 323.5532 323.6927 323.8322 323.9716 324.1111 324.2505 324.3900 324.5294 324.6688 324.8082 324.9476 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240207T123141.9Z 8803.522012 96 1 53.33 2 84.53 109.98 67.71 140.21 0.00 1 0.00 1 0 25 6.690e-01 4.576e-02 3.285e-01 1.494e-02 9.543060e-01 8.626764e-03 9.565051e-03 -6.000000e+00 3.864064e-01 224.93 -2.00 3.16 -2.00 322.18 0.00e+00 -1.757844e-02 4.912262e-03 1.861532e-02 -6.000000e+00 1.997576e-02 287.71 -2.00 20.00 -2.00 321.63 0.00e+00 9.172 0.007 302.00 328.00 3 5.0579e-01 3.4537e-02 1.6312e-01 -6.0000e+00 9.4924e-01 1.6108e+00 4.4344e-02 1.8691e-01 -6.0000e+00 1.0378e+00 -1.9113e+00 3.0049e-02 5.1425e-02 -6.0000e+00 6.1923e-01 7.0838e-01 1.4418e-02 2.0345e-02 -6.0000e+00 2.6967e-01 1.3352e-05 -9.1468e-04 4.0161e-04 8.5851e-05 -6.0000e+00 1.9626e-02 1.5905e-02 -6.1436e-05 12 8 8 10 0 0 63.99 25.75 1.45 0.01591 0.00903 24 2 1 5 0 2221.780 34.50 20.00 25.75 18.25 5.8 888.35 141063 302058 155549 166854 -5391 900000 -13423 5475 4127 5066 900000 -7400 17798 -77128 -10727 900000 9511 -7036 224825 900000 -23744 -53259 -18898 900000 10627 -11374 900000 -23861 146493 -44663 900000 156330 27244 192469 37259 900000 900000 900000 900000 106298 42705 900000 900000 900000 8457 18088 252460 900000 900000 59547 42351 180015 900000 64798 3616 731 202143 60035 15181 187132 1778 -3662 27332 28202 21546 60541 25946 14217 48513 13298 66172 16296 7567 882 -13162 13738 4620 -31468 -18446 7984 52221 -3072 28802 9880 -1171 9259 305 -4918 -10532 13767 -155 -12523 4418 333 -2877 6038 -1879 -3491 -130 -11080 8797 -10286 -15066 11562 -18325 -3001 8094 6997 5734 -1347 -722 6770 -2674 2775 -6176 -2110 -1633 3083 -1465 1304 1464 9179 6964 2780 -1786 5675 -5942 -1190 891 -5057 -1067 -98 701 1402 818 -1825 1869 2536 -280 -61 -441 -1362 -1970 2048 4386 2259 2423 -192 900000 -496 188 158 201 900000 -342 705 -8756 -694 900000 552 -483 3265 900000 -1661 -4640 -1197 900000 617 -841 900000 -1606 2127 -3125 900000 2270 1295 2795 1623 900000 900000 900000 900000 3859 3225 900000 900000 900000 774 1418 3666 900000 900000 3286 3075 3659 900000 4893 536 117 4403 5230 1896 3804 222 -511 3135 3604 3097 5802 3541 2312 6269 2800 8936 3715 1813 206 -3115 2174 751 -7631 -4500 1797 8948 -1062 8030 3544 -498 3738 139 -2400 -5337 5198 -63 -5455 1629 139 -1441 3279 -1299 -2844 -112 -10715 6515 -8200 -11354 6665 -15274 -2270 5830 5568 5237 -1539 -857 8150 -3660 3575 -8430 -2696 -2110 3988 -2090 1848 2005 12129 9050 3669 -2401 6905 -8024 -1666 1308 -9199 -2107 -209 1602 3447 2002 -4817 4839 6588 -739 -151 -1103 -3180 -4469 SS 20240207T124307.5Z 8803.529948 99 1 54.35 2 82.12 111.33 66.15 142.25 0.00 1 0.00 1 0 17 5.998e-01 1.576e-02 7.715e-02 2.535e-03 7.749464e-01 1.335606e-03 8.316772e-03 -6.000000e+00 3.383395e-01 224.93 -2.00 3.16 -2.00 321.23 0.00e+00 1.829813e-03 6.857025e-04 5.103941e-03 -6.000000e+00 1.543210e-02 287.71 -2.00 20.00 -2.00 320.62 0.00e+00 6.805 0.003 302.00 328.00 3 5.0547e-01 4.6919e-03 8.0293e-02 -6.0000e+00 8.3358e-01 3.0639e-01 6.5118e-03 4.9452e-02 -6.0000e+00 9.0697e-01 -4.3524e-01 6.1944e-03 2.2508e-02 -6.0000e+00 5.4319e-01 1.7346e-01 2.9104e-03 5.5115e-03 -6.0000e+00 2.3222e-01 1.8460e-04 -5.4733e-04 6.4549e-05 1.0435e-04 -6.0000e+00 1.6188e-02 1.4840e-02 -3.1421e-05 12 9 8 11 8 0 33.71 25.75 0.58 0.01484 0.01073 126 13 1 5 0 431.270 34.50 20.00 25.75 18.63 5.8 891.18 -166719 -166744 -114659 -180466 -192321 -154758 -233675 -188756 -194960 -188064 -146478 -165202 -134625 -157179 -131823 -29265 -76109 -57639 -41325 -60365 -68471 -85418 -60281 -12941 -62954 -58997 7938 -62666 -45219 -47058 -8288 -6153 -10016 -2447 -16681 18736 13438 16767 17081 14210 6856 32940 20350 34182 9618 11224 12826 13916 29114 9941 3790 20579 11777 12787 9307 7207 13760 5772 1235 12176 1230 3726 6614 5604 5812 6337 4006 4194 5064 3118 7570 3914 1321 3595 1076 472 -3480 -5920 -3967 -614 295 -2044 -367 -879 -976 -665 -142 -4 493 1021 775 -626 -1462 -2354 -2123 -409 -846 -474 -1346 -1110 -694 -2187 -2108 -915 -2561 -2061 -696 -358 299 339 159 813 230 103 -414 -310 103 456 195 558 627 1411 1598 989 461 484 185 687 782 52 41 -25 -150 31 -326 -56 529 610 -40 -186 -498 -598 -1048 -1499 -1761 -773 -2271 -2710 -1454 -5198 -3033 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319.12 0.00e+00 4.958 0.001 302.00 328.00 3 3.3037e-01 1.1506e-03 5.6470e-02 -6.0000e+00 3.7540e-01 3.8502e-02 1.4013e-03 2.8503e-02 -6.0000e+00 4.0842e-01 -6.8910e-02 1.1846e-03 1.4175e-02 -6.0000e+00 2.4461e-01 2.4504e-02 6.1501e-04 4.0472e-03 -6.0000e+00 1.0459e-01 1.5120e-03 -2.3973e-04 2.0668e-05 4.9201e-05 -6.0000e+00 7.2886e-03 1.4160e-02 -1.0999e-05 11 8 0 10 0 0 39.03 25.72 0.44 0.01416 0.01236 417 43 1 5 0 130.600 34.50 20.00 25.72 19.61 5.8 897.83 -84063 -87849 -88196 -85407 -100744 -88595 -94221 -83926 -84164 -78672 -74084 -70040 -57657 -51282 -34043 -24740 -26052 -20979 -14221 -16844 -16575 -21584 -15939 -11669 -12458 -12598 -8364 -14644 -14683 -10847 -7454 -2389 -3673 -4106 -5450 -4945 -6217 -1017 1118 1068 575 3666 2764 3477 2127 1901 1820 1713 1775 2049 1751 3205 2924 2911 2357 2801 2508 1125 532 1132 1005 2094 2874 2647 1800 1118 394 295 1055 1181 1522 867 490 475 -438 -876 -1838 -2372 -2326 -1229 -1331 -1622 -2183 -1814 -1152 -564 -286 342 574 770 347 8 -645 -582 -392 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