File name: Pandora256s1_MiamiFL-FIU_20240508_L2Fit_fout2c2d20230424p1-8.txt File generation date: 20240511T134809.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v2d20230424.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240508_L1_smca1c2d20230424p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240508 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0391 305.1801 305.3211 305.4621 305.6031 305.7441 305.8850 306.0260 306.1669 306.3078 306.4487 306.5896 306.7305 306.8714 307.0122 307.1531 307.2939 307.4347 307.5756 307.7164 307.8572 307.9979 308.1387 308.2795 308.4202 308.5610 308.7017 308.8424 308.9831 309.1238 309.2645 309.4051 309.5458 309.6864 309.8271 309.9677 310.1083 310.2489 310.3895 310.5301 310.6706 310.8112 310.9517 311.0923 311.2328 311.3733 311.5138 311.6543 311.7948 311.9352 312.0757 312.2161 312.3565 312.4969 312.6374 312.7777 312.9181 313.0585 313.1989 313.3392 313.4795 313.6199 313.7602 313.9005 314.0408 314.1810 314.3213 314.4616 314.6018 314.7420 314.8823 315.0225 315.1627 315.3029 315.4430 315.5832 315.7233 315.8635 316.0036 316.1437 316.2838 316.4239 316.5640 316.7041 316.8441 316.9842 317.1242 317.2642 317.4042 317.5442 317.6842 317.8242 317.9642 318.1041 318.2441 318.3840 318.5239 318.6638 318.8037 318.9436 319.0835 319.2233 319.3632 319.5030 319.6429 319.7827 319.9225 320.0623 320.2020 320.3418 320.4816 320.6213 320.7610 320.9008 321.0405 321.1802 321.3199 321.4595 321.5992 321.7388 321.8785 322.0181 322.1577 322.2973 322.4369 322.5765 322.7161 322.8556 322.9952 323.1347 323.2742 323.4137 323.5532 323.6927 323.8322 323.9716 324.1111 324.2505 324.3900 324.5294 324.6688 324.8082 324.9476 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240508T113406.3Z 8894.482017 57 1 54.21 2 79.07 75.93 81.62 70.45 0.00 1 0.00 1 0 17 3.740e-01 1.052e-02 4.436e-02 1.863e-03 6.275566e-01 9.711666e-04 6.539871e-03 -6.000000e+00 2.152516e-01 230.47 -2.00 3.16 -2.00 320.41 0.00e+00 9.667309e-04 3.806358e-04 1.543841e-03 -6.000000e+00 9.782620e-03 291.58 -2.00 20.00 -2.00 319.64 0.00e+00 5.081 0.001 302.00 328.00 3 1.7412e+00 3.0454e-03 5.8898e-02 -6.0000e+00 5.3657e-01 5.1790e-02 3.8754e-03 3.1256e-02 -6.0000e+00 5.8114e-01 -1.1611e-01 3.3928e-03 1.4968e-02 -6.0000e+00 3.4731e-01 4.2835e-02 1.6999e-03 3.9847e-03 -6.0000e+00 1.4727e-01 3.1955e-04 -1.2989e-03 5.0280e-05 5.0041e-05 -6.0000e+00 1.0111e-02 1.5072e-02 -1.6565e-04 12 8 8 10 0 0 99.98 26.82 0.62 0.01507 0.00531 116 12 1 5 0 467.290 35.25 20.00 26.82 33.49 5.6 984.93 -135718 -137887 -104463 -76339 -139460 -112171 -133114 -96199 -119632 -134504 -86103 -99328 -71294 -77637 -47621 -19819 -19581 -40742 -27304 -33884 -30645 -46505 -43817 -8608 -37264 -25904 -423 -28458 -22307 -16302 -9896 -4000 1071 1147 -10339 -6288 -5180 -52 4756 2055 -1798 9437 7166 10934 2918 369 3482 4552 3679 2180 2908 5272 7482 3157 3037 4795 6583 100 873 4198 -255 2076 3679 4307 2360 1865 -870 267 587 1414 1910 904 621 378 -264 -1298 -1938 -3355 -3563 -1450 -1288 -1845 -1852 -1519 -1809 -374 -278 539 733 1082 518 -262 -1001 -756 -393 -344 336 554 -16 -327 -445 -1669 -1315 -25 -1231 -1316 -312 -277 236 657 664 730 222 7 -220 -270 -184 474 296 82 103 972 580 549 457 488 -107 223 316 -114 -248 -143 -371 120 -155 -111 399 447 159 -81 -226 -495 -630 -1825 -2230 -1310 -708 -2230 -1345 -2153 -1241 -2239 -3202 -1330 -1967 -1334 -1975 -1125 -425 -473 -1348 -858 -1207 -1092 -1952 -1887 -288 -1815 -1200 -16 -1339 -965 -711 -478 -217 64 74 -721 -418 -377 -4 465 249 -256 1296 1060 1598 468 62 579 773 659 424 569 1131 1727 830 852 1384 1930 31 264 1209 -79 695 1378 1650 968 750 -354 111 269 743 1105 510 377 218 -140 -626 -878 -1560 -1857 -877 -840 -1381 -1411 -1226 -1571 -342 -250 495 671 1019 457 -218 -806 -626 -363 -342 360 677 -20 -410 -556 -1907 -1472 -28 -1414 -1603 -398 -356 330 966 1022 1181 360 11 -344 -405 -278 748 471 136 169 1536 939 858 686 706 -151 328 495 -201 -456 -265 -724 237 -328 -236 865 986 351 -171 -474 -983 -1279 SS 20240508T113911.9Z 8894.485554 60 1 3.98 2 77.96 76.43 80.57 70.90 0.00 1 0.00 1 0 25 3.083e-01 1.290e-02 2.733e-01 1.008e-02 5.742843e-01 5.419245e-03 6.375583e-03 -6.000000e+00 1.806388e-01 230.47 -2.00 3.16 -2.00 320.17 0.00e+00 -1.731538e-03 1.912818e-03 5.761210e-04 -6.000000e+00 8.307955e-03 291.58 -2.00 20.00 -2.00 319.40 0.00e+00 4.647 0.001 302.00 328.00 3 2.6512e+00 1.6246e-02 5.3739e-02 -6.0000e+00 4.5016e-01 -1.5674e-02 2.0533e-02 2.7926e-02 -6.0000e+00 4.8591e-01 -2.0885e-02 1.8271e-02 1.5729e-02 -6.0000e+00 2.8947e-01 4.5104e-03 9.3511e-03 7.7835e-03 -6.0000e+00 1.2536e-01 2.0382e-04 -9.1927e-03 2.7910e-04 7.1572e-05 -6.0000e+00 8.4874e-03 2.8675e-02 -1.7379e-03 12 9 9 12 9 1 99.55 26.82 0.56 0.02868 -0.04040 3 6 1 5 0 993.660 35.25 20.00 26.82 33.84 5.6 986.72 -160834 97414 900000 99680 161123 900000 35675 -92676 -65576 19741 -69427 -120826 58186 -24726 -4212 40499 -27720 42319 17281 11860 4801 -51047 -36451 42045 -7455 -28558 24508 -13711 14822 2051 15317 -5762 20473 -2657 57683 -5906 -3648 -13066 -5572 996 -6312 6818 -627 13759 -5324 252 5116 651 1609 1886 -896 4569 1807 1422 2984 -1304 7387 3107 -2539 3704 -1850 -619 -469 2645 -787 4114 1945 3272 1620 927 787 1833 1501 -1342 -749 -3962 -879 -2975 -4806 -801 -966 -429 -2416 -2271 131 805 -279 233 -1422 624 881 72 -1672 -903 2438 1394 349 1465 971 -1860 -529 -1952 -2313 1316 -2337 -270 -439 -1065 900 171 1222 1485 -139 704 42 642 -634 726 409 735 -780 -541 709 635 1265 518 755 -209 -344 -1031 183 -1761 -869 -245 246 -134 -175 226 128 632 385 -417 900000 -3303 957 900000 979 1583 900000 350 -1548 -966 194 -1228 -4035 572 -486 -83 597 -899 748 424 326 146 -2758 -1826 1074 -344 -1739 891 -700 553 93 707 -385 1207 -209 2380 -464 -315 -1502 -739 149 -1037 1159 -109 2325 -998 45 891 121 309 386 -210 1130 504 433 951 -455 2447 1074 -905 1224 -669 -243 -190 1156 -369 1771 839 1435 802 534 461 1111 904 -854 -435 -2134 -428 -1491 -2726 -513 -665 -334 -1941 -1934 117 764 -263 225 -1393 617 809 62 -1405 -771 2237 1385 402 1777 1275 -2495 -656 -2223 -2616 1465 -2733 -327 -563 -1465 1242 250 1930 2449 -232 1112 62 966 -974 1088 654 1226 -1317 -883 1107 956 1921 763 1072 -311 -540 -1720 329 -3236 -1653 -490 500 -288 -368 481 273 1353 782 -849 900000 SS 20240508T114305.8Z 8894.488261 63 1 54.33 2 77.11 76.81 79.76 71.24 0.00 1 0.00 1 0 17 1.892e-01 7.962e-03 1.444e-02 9.141e-04 5.480513e-01 4.692445e-04 5.723301e-03 -6.000000e+00 1.089805e-01 230.47 -2.00 3.16 -2.00 319.57 0.00e+00 1.474344e-03 1.380302e-04 1.056038e-03 -6.000000e+00 4.947004e-03 291.58 -2.00 20.00 -2.00 318.73 0.00e+00 4.361 0.001 302.00 328.00 3 1.2146e+00 1.3532e-03 5.0526e-02 -6.0000e+00 2.7167e-01 7.6063e-03 1.6188e-03 2.6298e-02 -6.0000e+00 2.9413e-01 -4.4989e-02 1.2783e-03 1.2909e-02 -6.0000e+00 1.7579e-01 1.2862e-02 6.6823e-04 3.6520e-03 -6.0000e+00 7.4615e-02 1.1544e-03 -1.6761e-04 2.4978e-05 4.1686e-05 -6.0000e+00 5.1112e-03 1.2095e-02 9.2904e-06 11 8 0 10 0 0 76.85 26.82 0.51 0.01209 0.01084 262 27 1 5 0 207.330 35.25 20.00 26.82 34.26 5.6 990.31 -60268 -68715 -57955 -58786 -60883 -68873 -70995 -62985 -51975 -59601 -51092 -47685 -37695 -34087 -23606 -11113 -13781 -11011 -8726 -10074 -10399 -13885 -11524 -4063 -10787 -8033 -4745 -10982 -8996 -7902 -3226 -2774 630 1077 -5287 -5091 -3491 -2692 817 322 1206 1077 1776 2860 1124 2021 1724 447 1538 -104 1596 2311 2268 2256 1996 2386 2468 1344 374 1413 1081 2197 2759 2809 1240 700 -42 -179 359 955 1192 738 31 255 -344 -987 -1508 -2216 -2239 -1539 -1320 -1731 -2170 -1698 -1152 -488 30 340 816 748 477 -67 -668 -352 -420 -41 249 625 17 -112 -455 -1072 -990 -206 -1033 -1083 -756 -404 162 575 606 439 302 122 -247 -45 165 336 311 216 75 566 694 487 445 170 78 643 317 121 -103 -311 -394 21 -73 -94 295 373 -16 -106 -251 -488 -498 -946 -1372 -1121 -1121 -1086 -1302 -1487 -1398 -1182 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