File name: Pandora256s1_MiamiFL-FIU_20240520_L2Fit_fout2c2d20230424p1-8.txt File generation date: 20240521T052127.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v2d20230424.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240520_L1_smca1c2d20230424p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240520 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0391 305.1801 305.3211 305.4621 305.6031 305.7441 305.8850 306.0260 306.1669 306.3078 306.4487 306.5896 306.7305 306.8714 307.0122 307.1531 307.2939 307.4347 307.5756 307.7164 307.8572 307.9979 308.1387 308.2795 308.4202 308.5610 308.7017 308.8424 308.9831 309.1238 309.2645 309.4051 309.5458 309.6864 309.8271 309.9677 310.1083 310.2489 310.3895 310.5301 310.6706 310.8112 310.9517 311.0923 311.2328 311.3733 311.5138 311.6543 311.7948 311.9352 312.0757 312.2161 312.3565 312.4969 312.6374 312.7777 312.9181 313.0585 313.1989 313.3392 313.4795 313.6199 313.7602 313.9005 314.0408 314.1810 314.3213 314.4616 314.6018 314.7420 314.8823 315.0225 315.1627 315.3029 315.4430 315.5832 315.7233 315.8635 316.0036 316.1437 316.2838 316.4239 316.5640 316.7041 316.8441 316.9842 317.1242 317.2642 317.4042 317.5442 317.6842 317.8242 317.9642 318.1041 318.2441 318.3840 318.5239 318.6638 318.8037 318.9436 319.0835 319.2233 319.3632 319.5030 319.6429 319.7827 319.9225 320.0623 320.2020 320.3418 320.4816 320.6213 320.7610 320.9008 321.0405 321.1802 321.3199 321.4595 321.5992 321.7388 321.8785 322.0181 322.1577 322.2973 322.4369 322.5765 322.7161 322.8556 322.9952 323.1347 323.2742 323.4137 323.5532 323.6927 323.8322 323.9716 324.1111 324.2505 324.3900 324.5294 324.6688 324.8082 324.9476 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240520T112952.9Z 8906.479084 186 1 53.15 2 78.87 72.86 129.59 277.80 0.00 1 0.00 1 0 17 4.368e-01 2.855e-02 2.499e-01 9.076e-03 6.525674e-01 4.837600e-03 6.837602e-03 -6.000000e+00 2.530628e-01 230.52 -2.00 3.16 -2.00 321.06 0.00e+00 1.466149e-03 2.295421e-03 2.082389e-03 -6.000000e+00 1.200818e-02 292.29 -2.00 20.00 -2.00 320.34 0.00e+00 4.995 0.001 302.00 328.00 3 4.1087e+00 1.6666e-02 5.9153e-02 -6.0000e+00 6.2919e-01 3.6296e-01 2.1499e-02 3.3197e-02 -6.0000e+00 6.8230e-01 -4.3523e-01 1.8051e-02 1.5861e-02 -6.0000e+00 4.0706e-01 1.6240e-01 8.7903e-03 4.1998e-03 -6.0000e+00 1.7164e-01 2.8563e-05 -3.5559e-03 2.5339e-04 6.3808e-05 -6.0000e+00 1.1935e-02 2.0143e-02 -5.5403e-04 12 8 8 10 0 0 99.99 27.05 0.87 0.02014 -0.00658 14 1 1 5 0 3795.890 35.25 19.99 27.05 34.04 5.5 986.46 -138919 -42105 -94348 34604 -68491 900000 -117372 -162562 -110168 -145630 -20981 -18360 58406 -57680 -77579 -77008 17814 -63957 32121 113725 -86353 -44354 -24696 900000 52686 -31319 900000 -50651 61705 16648 54814 -13067 147026 62292 19122 -17176 61001 72432 108533 32956 284 45432 93175 94406 -20451 5322 22256 34925 64376 -7249 2809 38492 41644 2543 5862 -2980 33888 39060 10868 34068 7765 2196 4527 4564 443 8205 1274 -1189 3091 2114 14981 3702 3390 -1252 -798 -417 -3747 -10018 -26647 -3209 12799 -920 -891 -3755 -2346 -2090 -945 467 -2412 3473 2439 -6483 -355 -3384 -1747 1099 -483 -1294 2503 -2227 2838 -3796 -2648 2538 -4651 -1207 2475 -1286 189 1447 1150 830 -1388 -199 76 -541 -2113 1994 -733 -301 441 2814 3048 -215 -96 3127 -1627 -508 1627 -568 -978 70 295 1106 194 -466 529 111 -278 -760 -146 -488 -693 -3351 -440 -1745 306 -826 900000 -2360 -5752 -2569 -5153 -241 -227 517 -1633 -3294 -3815 378 -3338 682 1107 -6264 -2079 -983 900000 1119 -1607 900000 -3002 1146 515 1358 -751 1951 2039 913 -1155 2050 2563 3264 2507 33 3617 4780 4844 -3311 673 2402 3398 4840 -1186 460 4903 5599 547 1286 -741 5965 6461 2298 5575 1697 556 1265 1425 151 2504 409 -403 1107 879 6016 1729 1562 -568 -327 -153 -1319 -3802 -13365 -1507 5978 -561 -594 -2482 -1634 -1546 -725 362 -1918 2499 1814 -4926 -244 -2476 -1410 907 -468 -1444 2914 -2708 3068 -3947 -2500 2302 -4881 -1294 2701 -1563 248 2100 1696 1295 -2214 -302 119 -816 -3266 3101 -1140 -484 698 4567 4762 -334 -143 4353 -2303 -745 2634 -969 -1834 138 611 2411 421 -1071 1229 262 -659 -1730 -336 -1063 -1469 SS 20240520T125446.1Z 8906.538033 237 1 8.17 2 60.28 80.51 147.51 291.70 0.00 1 0.00 1 0 17 1.536e-02 7.657e-03 9.736e-03 3.928e-03 2.808072e-01 2.002200e-03 3.009679e-03 -6.000000e+00 8.849269e-03 230.51 -2.00 3.16 -2.00 316.68 0.00e+00 9.505351e-04 2.537075e-04 9.202276e-05 -6.000000e+00 4.030649e-04 292.29 -2.00 20.00 -2.00 315.80 0.00e+00 2.008 0.000 302.00 328.00 3 4.4898e+00 5.2605e-03 2.3923e-02 -6.0000e+00 2.2056e-02 2.4542e-02 5.9056e-03 1.3124e-02 -6.0000e+00 2.3877e-02 -3.0535e-03 3.4365e-03 6.3480e-03 -6.0000e+00 1.4276e-02 -1.9402e-03 1.6364e-03 1.8112e-03 -6.0000e+00 6.0645e-03 5.6327e-04 -5.9773e-04 1.1129e-04 2.0478e-05 -6.0000e+00 4.1521e-04 4.6391e-03 -3.1193e-04 12 9 1 12 9 1 84.91 27.02 0.25 0.00464 0.00015 3 3 1 5 0 2041.860 35.25 20.00 27.02 33.37 5.6 982.95 -1059 -331 -3637 -5468 -2304 -4658 -5614 -791 -2725 -4248 -3885 -2697 2376 -1726 580 -1254 3669 -405 405 69 346 -1946 3696 3478 1735 -759 606 -944 -1808 980 2948 1913 1117 -1567 -3830 -3883 -2071 848 764 -313 -881 250 -317 828 -345 -39 715 355 210 78 -147 188 1577 704 353 1000 1241 -58 -757 466 769 765 2069 1058 -220 279 -371 -589 204 640 -52 594 189 59 17 -47 -206 -1929 -1141 -1128 -733 -1437 -1953 -1699 -1496 -829 -487 159 192 808 1194 -160 -597 400 -119 764 1165 1072 333 375 -162 -1503 -628 -132 -446 -1142 -1154 -395 -154 744 832 727 326 70 -303 -46 -489 493 413 -178 599 581 357 502 226 822 52 187 229 100 -620 -971 -515 185 205 79 710 359 -259 -122 -367 -311 -536 -144 -49 -577 -834 -333 -655 -841 -115 -452 -754 -682 -480 453 -398 151 -337 987 -118 123 22 111 -633 1159 1155 619 -288 227 -339 -612 319 1002 716 424 -631 -1481 -1463 -834 387 390 -176 -548 161 -212 553 -218 -26 471 229 134 50 -100 128 1128 536 262 753 949 -45 -577 349 591 633 1740 961 -202 236 -311 -483 177 592 -51 597 190 57 16 -40 -169 -1533 -945 -996 -689 -1503 -2085 -1898 -1700 -958 -592 198 239 963 1373 -178 -615 416 -126 843 1362 1331 441 490 -208 -1796 -737 -159 -559 -1458 -1542 -526 -215 1058 1249 1106 481 100 -418 -59 -634 662 571 -263 860 858 513 691 309 1063 67 245 306 138 -906 -1407 -757 281 318 129 1139 590 -431 -198 -593 -484 -851 SS 20240520T125918.4Z 8906.541185 240 1 7.10 2 59.27 80.90 148.42 292.74 0.00 1 0.00 1 0 17 2.412e-02 1.005e-02 1.880e-02 7.269e-03 2.771640e-01 3.699725e-03 2.966765e-03 -6.000000e+00 1.390419e-02 230.51 -2.00 3.16 -2.00 316.83 0.00e+00 5.718760e-04 4.890458e-04 3.102536e-04 -6.000000e+00 6.328030e-04 292.29 -2.00 20.00 -2.00 315.95 0.00e+00 1.949 0.000 302.00 328.00 3 5.1413e+00 9.7400e-03 2.3308e-02 -6.0000e+00 3.4656e-02 4.0378e-02 1.0939e-02 1.2866e-02 -6.0000e+00 3.7512e-02 -6.5174e-03 6.3852e-03 6.2153e-03 -6.0000e+00 2.2429e-02 -6.2806e-04 3.0678e-03 1.6946e-03 -6.0000e+00 9.5293e-03 3.1078e-04 -1.5125e-04 2.0628e-04 1.9356e-05 -6.0000e+00 6.5179e-04 1.0106e-02 5.5921e-06 12 9 9 12 1 1 999.00 27.02 0.39 0.01011 0.00897 1 2 1 5 0 3547.300 35.25 20.00 27.02 33.54 5.6 984.08 -17377 3057 1334 2027 -9424 -6466 305 -786 -2453 -204 2419 -1026 1447 -6206 -3125 -3983 -2104 -65 579 3968 1577 1079 6117 4270 3472 -332 -1808 -3939 -1802 1598 -2763 -1612 2032 424 682 -3099 -951 -422 581 -1064 -3574 -427 2666 1080 -1753 748 1681 -1342 2122 -1020 1024 524 569 318 2323 335 317 2772 415 1907 -256 1632 1027 1269 138 484 -1020 -1618 -488 424 8 -29 982 708 -789 -371 -1175 -883 -2948 -1409 148 -1145 -1838 -1384 -1680 -292 1445 -234 234 -67 19 -1018 350 59 -1083 340 344 659 554 -182 -43 -2095 -513 -722 -1119 -1283 -603 65 753 444 1636 1063 321 -49 -123 -1698 293 899 407 741 767 1162 694 422 701 266 -1267 550 114 -154 -1251 -163 104 422 -407 -117 -179 534 209 8 25 -852 -655 -2509 438 201 286 -1323 -834 39 -113 -402 -35 396 -177 274 -1332 -747 -1065 -580 -18 169 1159 482 328 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