File name: Pandora256s1_MiamiFL-FIU_20240621_L2Fit_fout2c2d20230424p1-8.txt File generation date: 20240622T052722.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v2d20230424.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240621_L1_smca1c2d20230424p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240621 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0391 305.1801 305.3211 305.4621 305.6031 305.7441 305.8850 306.0260 306.1669 306.3078 306.4487 306.5896 306.7305 306.8714 307.0122 307.1531 307.2939 307.4347 307.5756 307.7164 307.8572 307.9979 308.1387 308.2795 308.4202 308.5610 308.7017 308.8424 308.9831 309.1238 309.2645 309.4051 309.5458 309.6864 309.8271 309.9677 310.1083 310.2489 310.3895 310.5301 310.6706 310.8112 310.9517 311.0923 311.2328 311.3733 311.5138 311.6543 311.7948 311.9352 312.0757 312.2161 312.3565 312.4969 312.6374 312.7777 312.9181 313.0585 313.1989 313.3392 313.4795 313.6199 313.7602 313.9005 314.0408 314.1810 314.3213 314.4616 314.6018 314.7420 314.8823 315.0225 315.1627 315.3029 315.4430 315.5832 315.7233 315.8635 316.0036 316.1437 316.2838 316.4239 316.5640 316.7041 316.8441 316.9842 317.1242 317.2642 317.4042 317.5442 317.6842 317.8242 317.9642 318.1041 318.2441 318.3840 318.5239 318.6638 318.8037 318.9436 319.0835 319.2233 319.3632 319.5030 319.6429 319.7827 319.9225 320.0623 320.2020 320.3418 320.4816 320.6213 320.7610 320.9008 321.0405 321.1802 321.3199 321.4595 321.5992 321.7388 321.8785 322.0181 322.1577 322.2973 322.4369 322.5765 322.7161 322.8556 322.9952 323.1347 323.2742 323.4137 323.5532 323.6927 323.8322 323.9716 324.1111 324.2505 324.3900 324.5294 324.6688 324.8082 324.9476 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240621T111105.1Z 8938.466031 210 1 34.18 2 82.63 67.49 106.90 246.16 0.00 1 0.00 1 0 17 6.027e-01 2.445e-02 2.755e-01 7.904e-03 8.800424e-01 4.421245e-03 9.102530e-03 -6.000000e+00 3.496445e-01 229.25 -2.00 3.16 -2.00 321.77 0.00e+00 -4.337018e-03 2.606023e-03 5.792220e-03 -6.000000e+00 1.682195e-02 294.10 -2.00 20.00 -2.00 321.18 0.00e+00 7.197 0.003 302.00 328.00 3 1.3287e+00 1.7681e-02 8.9507e-02 -6.0000e+00 8.6834e-01 8.3664e-01 2.4239e-02 6.3434e-02 -6.0000e+00 9.4174e-01 -1.1404e+00 2.0072e-02 2.3628e-02 -6.0000e+00 5.6369e-01 4.5659e-01 9.2625e-03 8.2314e-03 -6.0000e+00 2.4030e-01 4.6113e-05 -1.3105e-03 2.0229e-04 8.6191e-05 -6.0000e+00 1.6764e-02 1.4044e-02 -7.4355e-05 12 9 9 12 1 1 97.88 26.91 0.62 0.01404 0.00420 24 4 1 5 0 1367.180 35.25 19.99 26.91 33.11 5.6 979.40 -76871 -95857 -162334 900000 -100044 900000 -155364 -62081 -132963 -12207 18753 -74229 900000 -134019 -73559 -18099 900000 -73739 41439 231497 -48272 -73360 23358 900000 862 -30253 50348 -95258 900000 -10565 113505 -5429 283407 72733 66327 65954 111511 77495 236138 59251 17741 147227 105901 900000 10807 35813 86341 49552 104296 9265 12703 60780 55399 29642 27431 8195 50767 48905 13334 50536 -5511 27571 6044 14914 14379 21164 2445 7104 10448 3461 17238 7989 6802 9209 3895 422 5586 -5988 -22704 -595 6851 -1719 5664 3442 -180 -869 -1064 751 -2266 2588 -362 -1446 -2315 -2710 -1048 -1750 -2522 -775 -2485 -1676 600 -4475 -5145 698 -5063 -5714 1148 -173 -921 102 -497 319 -744 -427 -1062 -206 -313 746 870 739 1290 1604 2892 1656 1472 2809 -972 1389 757 -120 -181 810 316 -1197 483 -248 1045 450 278 -529 -235 -1664 -1325 -1130 -1878 -6248 900000 -1610 900000 -4240 -739 -3536 -103 144 -1299 900000 -6378 -2317 -380 900000 -3148 638 1782 -1784 -3332 414 900000 23 -1118 814 -6086 900000 -285 1049 -196 2182 1456 1328 1269 1459 1670 1818 2235 1134 2720 3016 900000 765 1957 2858 2441 3131 777 1154 3837 4051 3058 3083 1167 4846 4668 1714 4240 -810 3162 982 2526 2612 3568 501 1466 2333 956 4565 2405 2021 2474 987 98 1161 -1452 -7480 -190 2416 -766 2603 1725 -91 -467 -600 425 -1310 1366 -184 -774 -1237 -1413 -621 -1238 -2120 -745 -2671 -1799 590 -4134 -4321 551 -4546 -5470 1090 -182 -1000 127 -707 488 -1179 -666 -1604 -299 -463 1145 1409 1232 2083 2455 4198 2360 2035 3722 -1311 1965 1253 -214 -361 1741 677 -2804 1196 -607 2570 1125 690 -1340 -551 -3665 -2804 SS 20240621T112110.1Z 8938.473034 213 1 54.48 2 80.53 68.46 108.90 246.94 0.00 1 0.00 1 0 17 5.663e-01 1.115e-02 1.296e-01 2.513e-03 7.535623e-01 1.338645e-03 7.872972e-03 -6.000000e+00 3.242420e-01 229.25 -2.00 3.16 -2.00 321.08 0.00e+00 8.834981e-04 6.698423e-04 2.454364e-03 -6.000000e+00 1.496780e-02 294.10 -2.00 20.00 -2.00 320.38 0.00e+00 5.780 0.002 302.00 328.00 3 1.3736e+00 4.7318e-03 6.8320e-02 -6.0000e+00 8.0513e-01 1.6384e-01 6.5675e-03 3.8998e-02 -6.0000e+00 8.7265e-01 -2.2102e-01 6.2344e-03 1.8857e-02 -6.0000e+00 5.2289e-01 8.0335e-02 2.9727e-03 5.0286e-03 -6.0000e+00 2.2272e-01 2.0474e-04 -2.0248e-03 6.4993e-05 6.9816e-05 -6.0000e+00 1.5311e-02 1.7534e-02 -2.8736e-04 12 8 8 10 0 0 99.98 26.91 0.59 0.01753 0.00232 156 16 1 5 0 349.200 35.25 20.00 26.91 33.82 5.6 984.39 -204305 -170189 -188005 25303 -165371 -152325 -179464 -214365 -181470 -173479 -156988 -150260 -57276 -147197 -85110 -84630 -67893 -87477 35570 -92184 -65489 -79924 -64172 -4142 -67126 -34854 17842 -66460 -18225 -15877 8952 -16216 18069 3848 14855 -10491 12016 5942 16758 8306 2871 16640 10723 22428 -4032 3338 6345 3970 13631 5632 3103 8540 6061 5074 5146 850 11597 1632 1683 6608 -1003 543 3397 3872 2050 4583 -579 2740 2802 3194 2342 2091 303 751 -1166 365 -1378 -3401 -5049 -1028 -223 -1545 -966 -1219 -376 -344 295 -76 -24 1756 1168 -43 -895 -853 -335 -233 30 -28 -658 -468 -464 -1989 -1268 -225 -1894 -1721 -1174 -158 371 743 431 598 162 80 -153 -155 311 473 250 341 172 1048 963 433 10 337 -352 817 138 69 -343 -152 -566 -510 169 -288 506 653 81 -67 -174 -464 -509 -1775 -1251 -1801 62 -1256 -1008 -1715 -3362 -2357 -2295 -1885 -1951 -379 -3138 -1251 -1514 -1181 -2079 270 -2665 -1492 -2115 -1541 -61 -2040 -820 254 -2133 -357 -335 180 -513 478 127 426 -386 392 248 780 511 212 1162 838 1599 -379 299 569 382 1269 620 396 1172 946 880 957 174 2205 342 341 1247 -211 125 871 1024 588 1269 -169 814 932 1227 1004 938 136 315 -453 125 -454 -1181 -2036 -479 -122 -903 -620 -835 -274 -267 238 -63 -20 1374 858 -30 -618 -619 -275 -207 31 -31 -802 -569 -527 -2214 -1277 -226 -2078 -1993 -1330 -191 495 1047 682 945 259 125 -243 -238 479 763 402 564 280 1725 1526 667 14 484 -495 1207 220 126 -652 -309 -1157 -1114 372 -669 1192 1556 192 -153 -390 -980 -1045 SS 20240621T112933.0Z 8938.478855 218 1 54.48 2 78.77 69.25 110.56 247.57 0.00 1 0.00 1 0 17 3.877e-01 9.989e-03 2.082e-02 9.790e-04 6.583646e-01 5.088086e-04 6.924215e-03 -6.000000e+00 2.223869e-01 229.25 -2.00 3.16 -2.00 320.20 0.00e+00 1.082716e-03 1.892038e-04 2.092150e-03 -6.000000e+00 1.025246e-02 294.10 -2.00 20.00 -2.00 319.38 0.00e+00 4.952 0.001 302.00 328.00 3 6.4112e-01 1.5649e-03 5.8674e-02 -6.0000e+00 5.5222e-01 6.4398e-02 1.9652e-03 3.3226e-02 -6.0000e+00 5.9819e-01 -1.1473e-01 1.6883e-03 1.5676e-02 -6.0000e+00 3.5846e-01 4.3228e-02 8.6099e-04 4.1460e-03 -6.0000e+00 1.5292e-01 1.0340e-03 -3.0335e-04 2.5587e-05 5.3015e-05 -6.0000e+00 1.0476e-02 1.3247e-02 8.4127e-07 12 8 8 10 0 0 74.36 26.91 0.47 0.01325 0.01097 311 32 1 5 0 175.160 35.25 20.00 26.91 34.46 5.6 989.09 -137991 -123827 -128111 -114983 -127422 -137747 -136350 -130584 -118658 -112118 -104965 -99862 -69368 -69578 -45374 -33659 -31481 -28660 -22684 -29110 -27132 -27559 -29973 -15236 -23579 -14718 -12562 -25143 -26314 -20173 -9592 -10669 -4270 -3217 -4376 -8421 -4815 -1086 1981 1875 2949 4445 3608 6210 3252 2218 2984 2372 2889 2213 3327 3824 3487 3411 3343 3001 3369 2008 1512 2305 728 1786 3303 3326 1978 1295 547 455 1661 1790 1595 1271 867 952 -340 -603 -1636 -2524 -2148 -1743 -1566 -1613 -2125 -1690 -1419 -570 -103 418 433 821 539 53 -784 -987 -840 -277 174 461 -311 -404 -687 -1380 -1020 -587 -1122 -1201 -807 -356 214 723 615 572 402 88 -132 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