File name: Pandora256s1_MiamiFL-FIU_20240628_L2Fit_fout2c2d20230424p1-8.txt File generation date: 20240629T053124.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v2d20230424.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240628_L1_smca1c2d20230424p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240628 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0391 305.1801 305.3211 305.4621 305.6031 305.7441 305.8850 306.0260 306.1669 306.3078 306.4487 306.5896 306.7305 306.8714 307.0122 307.1531 307.2939 307.4347 307.5756 307.7164 307.8572 307.9979 308.1387 308.2795 308.4202 308.5610 308.7017 308.8424 308.9831 309.1238 309.2645 309.4051 309.5458 309.6864 309.8271 309.9677 310.1083 310.2489 310.3895 310.5301 310.6706 310.8112 310.9517 311.0923 311.2328 311.3733 311.5138 311.6543 311.7948 311.9352 312.0757 312.2161 312.3565 312.4969 312.6374 312.7777 312.9181 313.0585 313.1989 313.3392 313.4795 313.6199 313.7602 313.9005 314.0408 314.1810 314.3213 314.4616 314.6018 314.7420 314.8823 315.0225 315.1627 315.3029 315.4430 315.5832 315.7233 315.8635 316.0036 316.1437 316.2838 316.4239 316.5640 316.7041 316.8441 316.9842 317.1242 317.2642 317.4042 317.5442 317.6842 317.8242 317.9642 318.1041 318.2441 318.3840 318.5239 318.6638 318.8037 318.9436 319.0835 319.2233 319.3632 319.5030 319.6429 319.7827 319.9225 320.0623 320.2020 320.3418 320.4816 320.6213 320.7610 320.9008 321.0405 321.1802 321.3199 321.4595 321.5992 321.7388 321.8785 322.0181 322.1577 322.2973 322.4369 322.5765 322.7161 322.8556 322.9952 323.1347 323.2742 323.4137 323.5532 323.6927 323.8322 323.9716 324.1111 324.2505 324.3900 324.5294 324.6688 324.8082 324.9476 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240628T110305.5Z 8945.460480 208 1 54.82 2 84.68 66.73 26.53 182.07 0.00 1 0.00 1 0 33 7.558e-01 8.424e-02 3.479e-01 1.588e-02 9.741970e-01 8.792062e-03 1.038402e-02 -6.000000e+00 4.385010e-01 228.97 -2.00 3.16 -2.00 322.18 0.00e+00 -2.286360e-02 4.647446e-03 5.025750e-03 -6.000000e+00 2.095976e-02 294.28 -2.00 20.00 -2.00 321.57 0.00e+00 9.349 0.007 302.00 328.00 3 1.6591e-01 3.5406e-02 1.1837e-01 -6.0000e+00 1.0877e+00 1.9033e+00 4.5316e-02 1.0226e-01 -6.0000e+00 1.1821e+00 -1.9417e+00 2.7065e-02 2.3869e-02 -6.0000e+00 7.0649e-01 6.1588e-01 1.2897e-02 2.5205e-02 -6.0000e+00 3.0175e-01 1.3809e-05 4.0292e-03 4.0607e-04 3.0268e-04 -6.0000e+00 2.0739e-02 1.5532e-02 2.3738e-05 12 8 8 10 0 0 15.16 25.57 1.33 0.01553 0.04581 28 3 1 5 0 1957.750 33.75 20.00 25.57 34.29 5.6 986.21 156838 67013 -5763 -35779 71901 112356 -46334 13854 -12666 -56515 29483 100393 207015 -37063 36834 298538 35406 42340 116569 111369 -6045 -32752 58198 900000 17692 32357 900000 -39173 158364 34604 900000 36612 99187 900000 52640 213199 206368 188488 209111 66157 68029 224028 900000 900000 50133 23888 126669 73111 900000 53125 50397 86466 175962 36196 71321 46833 233442 113423 38728 169998 45582 18961 47282 32567 11804 70120 32380 32450 59245 51917 90143 40614 32897 13975 19305 19414 -2284 -93168 -96793 4529 49515 39558 39735 20609 11913 12387 14048 13067 4554 26396 12189 8107 25253 5450 33601 15421 6187 8374 6614 -1396 10767 -9882 -5191 11148 -4772 -2009 13166 -7071 3758 6435 977 5218 -2407 -2056 -3146 -2018 -2124 851 -558 -1566 -3645 1317 2567 -2804 -944 1347 -4664 1606 4254 33 -351 121 741 -1844 1063 -1975 1289 1669 -931 -2184 805 10 1720 2426 2262 -365 -2516 1415 1738 -3193 604 -801 -5801 1285 2259 3202 -3909 2020 4618 2091 2322 2951 2819 -459 -3086 2373 900000 1368 2184 900000 -4131 2450 1508 900000 1956 3068 900000 2295 3298 3192 2916 3235 5014 5472 3812 900000 900000 3877 2254 4115 4071 900000 4027 4365 5751 5171 4647 6840 6013 4694 7193 4673 4996 4512 2610 5485 4836 2209 7158 4908 5270 8339 8914 11294 8418 6971 3221 3673 3243 -452 -48422 -60487 1226 10033 10157 11125 7396 4938 5346 6128 5760 2120 9268 4581 3047 8125 2360 12838 8325 4278 6489 5586 -1253 7861 -7841 -3605 6725 -3617 -1557 9348 -6738 3668 7117 1180 6508 -3317 -2785 -4164 -2594 -2804 1147 -802 -2287 -5218 1870 3482 -3913 -1262 1717 -6348 2298 6389 60 -720 270 1777 -4936 2737 -5479 3526 4599 -2576 -5746 2074 25 4062 SS 20240628T111356.1Z 8945.468010 211 1 54.57 2 82.43 67.80 26.69 188.01 0.00 1 0.00 1 0 17 6.497e-01 1.563e-02 9.778e-02 2.850e-03 8.201161e-01 1.535109e-03 8.673887e-03 -6.000000e+00 3.720803e-01 228.97 -2.00 3.16 -2.00 321.45 0.00e+00 1.542730e-04 8.548342e-04 5.427239e-03 -6.000000e+00 1.719367e-02 294.28 -2.00 20.00 -2.00 320.81 0.00e+00 7.033 0.003 302.00 328.00 3 3.8289e-01 5.7929e-03 8.4477e-02 -6.0000e+00 9.2322e-01 3.6294e-01 8.2530e-03 5.4981e-02 -6.0000e+00 1.0004e+00 -5.3674e-01 7.6392e-03 2.2806e-02 -6.0000e+00 5.9968e-01 2.1610e-01 3.5292e-03 6.0094e-03 -6.0000e+00 2.5592e-01 1.6224e-04 -3.7748e-04 7.1821e-05 9.2009e-05 -6.0000e+00 1.7555e-02 1.6022e-02 -8.4732e-06 12 8 8 10 0 0 -5.68 25.57 0.57 0.01602 0.01318 126 13 1 5 0 433.060 33.75 20.00 25.57 34.78 5.6 990.56 -127707 -186395 -191025 -173763 -194141 -214256 -241330 -209853 -197483 -166329 -186736 -190851 -144667 -161678 -112781 -22834 -79111 -85606 -31229 -68739 -89104 -93130 -86081 -18738 -88593 -55043 -13452 -72119 -41234 -36885 -21317 71 10441 -3327 20687 -18427 6368 5050 18128 17264 6964 37877 20878 39381 8050 7897 7009 13862 21279 10799 11115 20060 19405 8723 14700 13375 20407 10067 7540 14869 -399 7262 6187 9700 8910 6616 3699 5832 4635 5154 7094 2949 3357 2559 719 248 -498 -3179 -7651 -718 -1252 -1802 -475 -1652 361 677 537 655 529 1290 1070 -1111 -1803 -2199 -1834 -445 -695 -31 -1440 -1693 -979 -2250 -2227 -673 -1794 -2674 -780 -863 -73 378 -4 441 56 -61 -344 240 106 180 102 545 691 1829 1615 1223 143 722 -125 622 589 289 -56 154 -213 -289 241 -361 606 543 -17 -216 -326 -800 -896 -645 -1978 -2269 -1669 -2061 -2707 -4330 -3442 -3239 -2173 -3166 -3873 -2373 -4090 -2226 -222 -1539 -1975 -451 -1510 -2427 -2615 -2369 -292 -3029 -1423 -232 -2145 -883 -831 -504 2 258 -102 477 -620 184 177 690 801 407 1748 1196 1905 535 536 493 956 1455 898 1044 1957 2115 1164 1982 1922 2825 1534 1132 2013 -65 1205 1199 2079 2058 1558 907 1482 1341 1566 2334 1053 1172 841 217 74 -142 -974 -2573 -273 -569 -954 -275 -1033 217 433 361 451 363 843 714 -719 -1160 -1388 -1330 -377 -640 -33 -1697 -2004 -1077 -2241 -2186 -655 -1751 -2789 -849 -1022 -89 527 -5 696 90 -96 -522 352 158 282 170 927 1147 2862 2440 1796 220 1071 -183 908 994 528 -108 317 -472 -650 578 -866 1471 1337 -42 -533 -749 -1724 -1989 SS 20240628T113124.3Z 8945.480143 216 1 54.43 2 78.77 69.47 27.46 197.30 0.00 1 0.00 1 0 17 3.079e-01 8.897e-03 1.696e-02 8.253e-04 6.183746e-01 4.255144e-04 6.467788e-03 -6.000000e+00 1.763403e-01 228.97 -2.00 3.16 -2.00 320.01 0.00e+00 8.356976e-04 1.471335e-04 1.598572e-03 -6.000000e+00 8.148834e-03 294.28 -2.00 20.00 -2.00 319.16 0.00e+00 4.952 0.001 302.00 328.00 3 3.6378e-01 1.2781e-03 5.7308e-02 -6.0000e+00 4.3754e-01 3.7099e-02 1.5805e-03 3.0394e-02 -6.0000e+00 4.7413e-01 -7.7977e-02 1.3293e-03 1.4512e-02 -6.0000e+00 2.8421e-01 2.8891e-02 6.8626e-04 3.8641e-03 -6.0000e+00 1.2129e-01 1.4420e-03 -1.9496e-04 2.1911e-05 4.6416e-05 -6.0000e+00 8.3202e-03 1.5988e-02 -1.4588e-05 11 9 0 11 8 0 89.39 25.55 0.45 0.01599 0.01452 422 43 1 5 0 128.960 33.75 20.00 25.55 36.55 5.6 1001.70 -96200 -98531 -106719 -88692 -106087 -106123 -109074 -104096 -101675 -87614 -88654 -71267 -62438 -54713 -37699 -24917 -23719 -24860 -17148 -22503 -24264 -23360 -21067 -12222 -17707 -15359 -9958 -15502 -17587 -14037 -9163 -5167 -3141 -3390 -6009 -8102 -5797 -2681 73 2092 2070 4474 2515 4082 2955 2589 1362 1449 1458 1963 2415 3326 3162 2399 2752 2593 2912 1774 1280 1008 1241 2268 3167 2780 1585 1023 -458 85 1341 1748 1346 889 777 618 -351 -878 -1879 -2324 -2224 -1557 -1381 -1568 -2257 -1791 -1284 -580 -127 449 545 759 391 -206 -747 -774 -583 -224 300 529 -15 -190 -568 -1220 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