File name: Pandora256s1_MiamiFL-FIU_20240903_L2Fit_fout2c2d20230424p1-8.txt File generation date: 20240904T075025.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v2d20230424.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20240903_L1_smca1c2d20230424p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20240903 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0391 305.1801 305.3211 305.4621 305.6031 305.7441 305.8850 306.0260 306.1669 306.3078 306.4487 306.5896 306.7305 306.8714 307.0122 307.1531 307.2939 307.4347 307.5756 307.7164 307.8572 307.9979 308.1387 308.2795 308.4202 308.5610 308.7017 308.8424 308.9831 309.1238 309.2645 309.4051 309.5458 309.6864 309.8271 309.9677 310.1083 310.2489 310.3895 310.5301 310.6706 310.8112 310.9517 311.0923 311.2328 311.3733 311.5138 311.6543 311.7948 311.9352 312.0757 312.2161 312.3565 312.4969 312.6374 312.7777 312.9181 313.0585 313.1989 313.3392 313.4795 313.6199 313.7602 313.9005 314.0408 314.1810 314.3213 314.4616 314.6018 314.7420 314.8823 315.0225 315.1627 315.3029 315.4430 315.5832 315.7233 315.8635 316.0036 316.1437 316.2838 316.4239 316.5640 316.7041 316.8441 316.9842 317.1242 317.2642 317.4042 317.5442 317.6842 317.8242 317.9642 318.1041 318.2441 318.3840 318.5239 318.6638 318.8037 318.9436 319.0835 319.2233 319.3632 319.5030 319.6429 319.7827 319.9225 320.0623 320.2020 320.3418 320.4816 320.6213 320.7610 320.9008 321.0405 321.1802 321.3199 321.4595 321.5992 321.7388 321.8785 322.0181 322.1577 322.2973 322.4369 322.5765 322.7161 322.8556 322.9952 323.1347 323.2742 323.4137 323.5532 323.6927 323.8322 323.9716 324.1111 324.2505 324.3900 324.5294 324.6688 324.8082 324.9476 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240903T145119.5Z 9012.618976 173 1 55.23 2 40.10 110.89 46.34 107.15 0.00 1 0.00 1 0 17 8.575e-03 6.895e-03 1.904e-03 1.348e-03 1.664953e-01 6.913150e-04 1.814180e-03 -6.000000e+00 4.894732e-03 227.88 -2.00 3.16 -2.00 314.76 0.00e+00 5.541147e-04 5.961623e-05 2.704621e-05 -6.000000e+00 2.271770e-04 294.57 -2.00 20.00 -2.00 314.02 0.00e+00 1.306 0.000 302.00 328.00 3 5.4392e+00 1.7658e-03 1.5040e-02 -6.0000e+00 1.2112e-02 3.4526e-02 1.9645e-03 7.7034e-03 -6.0000e+00 1.3132e-02 9.2115e-04 1.1258e-03 3.7395e-03 -6.0000e+00 7.8808e-03 -6.3119e-03 4.9561e-04 1.0737e-03 -6.0000e+00 3.3742e-03 5.3625e-04 2.9009e-04 3.7961e-05 1.3840e-05 -6.0000e+00 2.3160e-04 1.3173e-02 5.9186e-05 11 9 0 11 8 0 99.48 25.27 0.48 0.01317 0.01535 17 2 1 5 0 3248.640 33.50 20.00 25.27 35.83 5.7 994.16 -233 736 265 -2076 -2222 -415 -1552 -497 138 -541 -1359 -1635 101 -778 235 117 453 -137 780 1156 914 183 797 1048 1053 797 728 -951 -47 610 1255 1658 1446 -520 -2549 -1763 -2744 -1123 -367 -494 -1177 -202 -217 -2 -100 -206 -409 -195 -490 -458 304 564 1029 688 611 723 733 458 97 924 944 1036 1737 1437 257 -420 -701 -1063 205 240 828 617 429 661 -21 -439 -1453 -1932 -1449 -1359 -433 -1233 -1830 -1640 -1119 -529 174 453 467 706 530 60 -310 -419 -190 93 629 793 479 -180 -343 -861 -907 -276 -1046 -465 -804 -250 169 592 870 483 507 92 -297 -73 -207 344 97 137 229 445 513 448 405 250 55 487 403 17 -182 -104 -255 -129 252 -38 457 186 8 -138 -254 -640 -755 -82 277 101 -754 -708 -133 -480 -169 52 -212 -523 -627 41 -332 111 60 236 -68 393 596 480 95 416 569 597 466 423 -524 -25 315 663 921 795 -297 -1377 -985 -1555 -725 -262 -383 -937 -165 -182 -1 -83 -171 -331 -161 -389 -359 246 454 864 604 549 657 675 421 88 826 870 962 1722 1422 253 -400 -645 -943 189 236 837 651 453 675 -21 -400 -1271 -1690 -1223 -1274 -423 -1258 -1991 -1767 -1284 -617 213 569 588 854 622 67 -316 -432 -204 103 726 955 608 -225 -423 -986 -1045 -313 -1299 -577 -1046 -322 226 829 1208 673 702 118 -364 -88 -249 431 125 181 310 597 671 586 501 309 65 569 499 21 -237 -137 -342 -171 353 -53 658 275 12 -202 -360 -922 -1071 SS 20240903T145535.2Z 9012.621936 176 1 17.30 2 39.20 111.78 45.45 107.90 0.00 1 0.00 1 0 17 8.630e-03 6.965e-03 1.924e-03 1.447e-03 1.641209e-01 7.433207e-04 1.798507e-03 -6.000000e+00 4.925886e-03 227.88 -2.00 3.16 -2.00 314.44 0.00e+00 4.856547e-04 6.050177e-05 1.415268e-05 -6.000000e+00 2.286224e-04 294.57 -2.00 20.00 -2.00 313.75 0.00e+00 1.289 0.000 302.00 328.00 3 4.4687e+00 1.8918e-03 1.4853e-02 -6.0000e+00 1.2189e-02 2.8276e-02 2.1016e-03 7.6145e-03 -6.0000e+00 1.3216e-02 -9.2753e-04 1.2071e-03 3.6998e-03 -6.0000e+00 7.9309e-03 -5.9368e-03 5.2769e-04 1.0625e-03 -6.0000e+00 3.3956e-03 1.4510e-03 3.3919e-04 4.0538e-05 1.3939e-05 -6.0000e+00 2.3307e-04 1.3248e-02 6.1757e-05 12 9 1 12 1 1 99.98 25.27 0.54 0.01325 0.01580 15 5 1 5 0 1080.870 33.50 20.00 25.27 36.07 5.7 995.17 755 -630 -173 -1519 -2055 -1427 -622 794 235 -219 -1806 -1342 -537 -468 1218 497 69 499 566 1038 929 398 1037 1395 1076 616 566 -139 -409 261 1312 1669 1563 -916 -2704 -2800 -2368 -1123 -295 -635 -1121 -381 -511 -207 -313 -12 -619 -742 -464 -185 446 677 964 891 659 906 538 260 330 577 523 1320 1598 1487 235 -160 -776 -948 634 550 600 652 538 745 -72 -528 -640 -1393 -909 -1016 -1099 -1604 -2153 -1589 -1133 -495 -117 192 594 703 541 124 -226 59 21 171 786 764 120 -131 -296 -616 -580 -142 -828 -871 -801 -537 145 769 641 582 515 6 -215 -1 -215 240 229 107 -3 425 380 305 545 31 73 747 171 126 43 -383 -172 75 233 -64 357 85 51 -163 -241 -630 -613 298 -254 -70 -620 -738 -514 -232 301 99 -97 -789 -579 -233 -227 607 269 38 282 308 578 526 223 583 815 658 368 355 -82 -236 144 736 926 923 -563 -1571 -1576 -1436 -735 -216 -490 -941 -315 -432 -176 -264 -10 -528 -609 -365 -151 357 573 813 785 595 826 498 241 299 520 486 1243 1546 1513 238 -154 -717 -843 585 547 624 679 561 781 -71 -491 -557 -1199 -802 -952 -1097 -1687 -2317 -1777 -1299 -583 -140 236 728 859 633 137 -236 59 22 187 904 929 149 -159 -350 -702 -657 -160 -988 -1098 -1016 -683 191 1024 889 806 703 8 -266 -1 -259 289 287 139 -4 563 509 390 682 37 86 873 212 159 55 -497 -225 102 322 -90 513 121 73 -238 -340 -867 -859 SS 20240903T151543.1Z 9012.635916 185 1 54.41 2 35.07 116.42 41.29 111.74 0.00 1 0.00 1 0 17 8.159e-03 6.639e-03 1.028e-03 7.615e-04 1.540075e-01 3.903610e-04 1.687448e-03 -6.000000e+00 4.656997e-03 227.88 -2.00 3.16 -2.00 314.51 0.00e+00 3.834898e-04 3.233735e-05 1.764454e-05 -6.000000e+00 2.161346e-04 294.57 -2.00 20.00 -2.00 313.82 0.00e+00 1.221 0.000 302.00 328.00 3 4.4211e+00 9.9476e-04 1.4027e-02 -6.0000e+00 1.1524e-02 2.5688e-02 1.1044e-03 7.1306e-03 -6.0000e+00 1.2494e-02 1.6678e-03 6.3387e-04 3.4703e-03 -6.0000e+00 7.4980e-03 -6.5493e-03 2.7864e-04 9.8257e-04 -6.0000e+00 3.2104e-03 1.6626e-03 3.2935e-04 2.1350e-05 1.3080e-05 -6.0000e+00 2.2034e-04 1.3149e-02 6.6066e-05 11 8 0 10 0 0 100.00 25.28 0.41 0.01315 0.01562 226 23 1 5 0 240.740 33.50 20.00 25.28 36.31 5.6 996.07 245 310 -196 -1721 -2405 -1406 -556 558 684 -638 -1796 -1417 -538 -399 369 441 36 22 931 883 929 591 1049 1038 541 787 494 -153 -326 563 1067 1340 1352 -986 -2542 -2145 -1984 -1269 -191 -272 -897 -464 -438 -355 -133 -109 -453 -414 -552 7 313 683 855 910 799 945 760 296 332 537 613 1177 1554 1467 473 -316 -775 -622 260 551 463 377 301 435 137 -425 -816 -1415 -950 -1265 -1274 -1561 -2076 -1613 -963 -553 -17 295 413 617 535 66 -186 23 78 301 680 769 260 -63 -298 -852 -756 -225 -900 -698 -586 -576 184 620 677 560 265 161 -187 20 -91 215 208 191 77 333 335 295 491 269 180 785 345 281 -92 -215 -323 46 145 9 265 272 -2 -59 -486 -643 -716 92 125 -80 -659 -880 -477 -195 215 268 -264 -731 -569 -232 -192 181 233 19 12 521 507 542 340 606 583 319 476 297 -92 -181 297 574 756 809 -572 -1490 -1211 -1209 -830 -138 -214 -727 -388 -374 -305 -113 -92 -371 -345 -443 5 254 585 722 801 719 860 701 273 301 483 568 1097 1549 1457 466 -300 -709 -545 237 536 467 397 318 444 138 -408 -704 -1215 -834 -1168 -1239 -1581 -2238 -1807 -1093 -641 -21 369 518 742 622 73 -197 23 82 327 772 913 326 -77 -360 -959 -854 -264 -1101 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