File name: Pandora256s1_MiamiFL-FIU_20241127_L2Fit_fout2c2d20230424p1-8.txt File generation date: 20241128T051552.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v2d20230424.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20241127_L1_smca1c2d20230424p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20241127 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0391 305.1801 305.3211 305.4621 305.6031 305.7441 305.8850 306.0260 306.1669 306.3078 306.4487 306.5896 306.7305 306.8714 307.0122 307.1531 307.2939 307.4347 307.5756 307.7164 307.8572 307.9979 308.1387 308.2795 308.4202 308.5610 308.7017 308.8424 308.9831 309.1238 309.2645 309.4051 309.5458 309.6864 309.8271 309.9677 310.1083 310.2489 310.3895 310.5301 310.6706 310.8112 310.9517 311.0923 311.2328 311.3733 311.5138 311.6543 311.7948 311.9352 312.0757 312.2161 312.3565 312.4969 312.6374 312.7777 312.9181 313.0585 313.1989 313.3392 313.4795 313.6199 313.7602 313.9005 314.0408 314.1810 314.3213 314.4616 314.6018 314.7420 314.8823 315.0225 315.1627 315.3029 315.4430 315.5832 315.7233 315.8635 316.0036 316.1437 316.2838 316.4239 316.5640 316.7041 316.8441 316.9842 317.1242 317.2642 317.4042 317.5442 317.6842 317.8242 317.9642 318.1041 318.2441 318.3840 318.5239 318.6638 318.8037 318.9436 319.0835 319.2233 319.3632 319.5030 319.6429 319.7827 319.9225 320.0623 320.2020 320.3418 320.4816 320.6213 320.7610 320.9008 321.0405 321.1802 321.3199 321.4595 321.5992 321.7388 321.8785 322.0181 322.1577 322.2973 322.4369 322.5765 322.7161 322.8556 322.9952 323.1347 323.2742 323.4137 323.5532 323.6927 323.8322 323.9716 324.1111 324.2505 324.3900 324.5294 324.6688 324.8082 324.9476 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241127T121935.7Z 9097.513608 142 1 55.09 2 84.50 116.81 47.66 137.45 0.00 1 0.00 1 0 17 6.735e-01 3.053e-02 3.220e-01 1.167e-02 8.683743e-01 6.399566e-03 8.580743e-03 -6.000000e+00 3.810521e-01 225.07 -2.00 3.16 -2.00 322.06 0.00e+00 -1.070922e-02 3.572135e-03 8.940888e-03 -6.000000e+00 1.752103e-02 289.88 -2.00 20.00 -2.00 321.49 0.00e+00 9.131 0.007 302.00 328.00 3 3.5773e-01 2.5596e-02 1.1719e-01 -6.0000e+00 9.3917e-01 1.3216e+00 3.2796e-02 9.8101e-02 -6.0000e+00 1.0225e+00 -1.6893e+00 2.2024e-02 2.7721e-02 -6.0000e+00 6.1195e-01 6.4449e-01 1.0476e-02 1.3853e-02 -6.0000e+00 2.6251e-01 1.9790e-05 -4.1290e-04 3.0939e-04 8.7553e-05 -6.0000e+00 1.8596e-02 1.4992e-02 4.5415e-05 12 9 8 11 8 0 2.12 26.23 1.22 0.01499 0.01189 38 4 1 5 0 1449.560 34.75 19.99 26.23 27.63 6.0 939.63 40937 -7496 96842 8937 -59485 113284 -22145 -72572 -64839 -54727 43339 21118 37351 -41619 -5951 85231 45345 2470 204065 117692 -20620 -50189 -37834 212253 -23532 -12757 186618 -27692 86379 -44868 125047 48307 121770 107702 167970 900000 97781 900000 113109 23878 45657 251934 164451 246291 49411 16676 78161 71100 306994 16043 28521 119139 57799 26767 8469 7074 115891 29432 14721 71412 -9350 -5719 11371 1452 -166 35902 23098 6506 15582 12349 35691 14443 -1089 -2225 -6389 12592 -7605 -25770 -7400 -7668 8710 -2228 16502 -950 836 2633 1845 -755 -800 -1312 338 -2232 -1043 -2975 -3316 -1495 -3362 -459 -4968 -1860 1153 -5577 -10318 1295 -8772 -3639 4408 2019 3672 186 -678 4442 -1675 850 -3132 1 -2266 2443 -540 70 18 5494 4723 3 -134 3393 -3101 -235 2320 -1927 66 850 -184 -2583 701 -296 2143 1545 -436 359 253 -1656 -2211 1143 -349 1503 287 -3077 1289 -733 -4354 -3890 -3057 897 568 966 -2712 -308 1940 1595 135 2322 1948 -1280 -3894 -2622 2415 -1655 -818 2123 -1719 1671 -3216 1850 1759 2355 2451 1911 900000 2225 900000 3089 1875 3169 2867 3555 2802 3036 1366 3380 3317 3493 1424 2466 4609 4472 3046 1224 1079 6066 3550 1910 4875 -1404 -885 1669 264 -32 4780 3495 1221 2979 2796 6985 3599 -307 -585 -1556 2235 -1549 -6510 -1777 -2216 2527 -834 5671 -414 381 1249 919 -393 -412 -649 153 -988 -453 -1415 -1830 -958 -2579 -397 -4476 -1795 1012 -4683 -8254 927 -7476 -3127 3722 1904 3839 212 -889 6005 -2474 1209 -4478 1 -3185 3449 -832 110 27 7644 6395 5 -180 4299 -4134 -329 3695 -3712 139 1782 -419 -6488 1839 -824 5951 4374 -1247 966 632 -3925 -5108 SS 20241127T123102.2Z 9097.521553 145 1 54.55 2 82.22 118.19 46.03 140.51 0.00 1 0.00 1 0 17 5.883e-01 1.308e-02 7.707e-02 2.308e-03 7.275824e-01 1.216211e-03 7.586155e-03 -6.000000e+00 3.320561e-01 225.07 -2.00 3.16 -2.00 321.15 0.00e+00 1.108228e-04 6.177342e-04 3.338237e-03 -6.000000e+00 1.527394e-02 289.88 -2.00 20.00 -2.00 320.51 0.00e+00 6.875 0.003 302.00 328.00 3 3.7617e-01 4.2852e-03 7.7712e-02 -6.0000e+00 8.1773e-01 1.7559e-01 5.9444e-03 4.1297e-02 -6.0000e+00 8.8926e-01 -3.0783e-01 5.6406e-03 1.8760e-02 -6.0000e+00 5.3326e-01 1.2312e-01 2.6608e-03 5.1171e-03 -6.0000e+00 2.2842e-01 2.1892e-04 -4.3518e-04 6.0572e-05 7.4494e-05 -6.0000e+00 1.5877e-02 1.5744e-02 2.7166e-05 12 8 8 10 0 0 43.69 26.23 0.62 0.01574 0.01247 159 16 1 5 0 343.070 34.75 20.00 26.23 28.33 6.0 943.66 -117680 -194686 -144853 -209051 -214135 -184853 -196749 -179426 -183509 -190329 -155280 -155154 -122686 -121572 -86879 -14946 -71226 -59477 -19131 -56435 -70479 -95659 -76910 -14596 -63183 -47204 -3933 -50962 -34021 -35330 -7888 -5891 14719 9882 -16693 11104 -9293 9348 13446 8290 8364 14555 15059 19089 2489 5461 13620 4466 20066 8027 7392 10995 12632 11146 8784 6542 11430 2575 3619 9830 -587 4545 5975 6123 2833 3467 2146 3162 3487 3080 4465 2711 559 1035 -267 -1290 -1864 -5828 -3661 -2145 -1352 -1637 -819 -950 -931 -130 -99 346 649 887 1053 -400 -1360 -1037 -1999 5 -526 207 -732 -759 -651 -1493 -1844 -840 -2344 -1666 -647 -559 311 497 484 481 28 282 -250 82 -21 -18 317 172 201 1141 1204 776 386 394 242 473 497 122 162 108 -268 -252 -103 -63 318 245 170 -88 -401 -585 -615 -578 -2431 -1186 -3166 -3423 -2164 -2835 -2504 -3057 -3728 -2272 -2585 -1878 -2381 -1526 -155 -1475 -1218 -284 -1283 -1888 -3295 -2320 -263 -2034 -1381 -76 -1526 -842 -962 -197 -175 418 318 -676 337 -383 383 657 517 593 1049 1136 1414 220 478 1128 423 1726 846 884 1436 1797 1769 1531 1227 2115 520 699 1744 -119 969 1443 1529 778 935 587 898 1105 1136 1798 1161 242 419 -99 -436 -598 -2006 -1406 -975 -721 -925 -508 -629 -661 -98 -79 280 523 686 760 -277 -929 -742 -1648 5 -540 226 -881 -914 -733 -1525 -1864 -850 -2410 -1804 -736 -687 393 712 728 771 46 446 -379 120 -31 -28 522 293 337 1820 1855 1163 598 591 355 738 832 220 305 217 -545 -548 -239 -146 753 591 407 -202 -911 -1252 -1285 SS 20241127T124813.4Z 9097.533488 150 1 54.39 2 78.85 120.37 43.79 145.46 0.00 1 0.00 1 0 17 2.313e-01 8.341e-03 1.204e-02 7.177e-04 5.597070e-01 3.638821e-04 5.893970e-03 -6.000000e+00 1.305664e-01 225.07 -2.00 3.16 -2.00 319.74 0.00e+00 1.490689e-03 1.152616e-04 1.098081e-03 -6.000000e+00 6.005102e-03 289.87 -2.00 20.00 -2.00 318.95 0.00e+00 4.986 0.001 302.00 328.00 3 2.1035e-01 1.0596e-03 5.5726e-02 -6.0000e+00 3.2154e-01 6.4395e-03 1.2825e-03 2.6422e-02 -6.0000e+00 3.4965e-01 -5.0142e-02 1.0478e-03 1.3127e-02 -6.0000e+00 2.0968e-01 1.6903e-02 5.4621e-04 3.7988e-03 -6.0000e+00 8.9822e-02 1.7751e-03 -2.3923e-04 1.9476e-05 4.4606e-05 -6.0000e+00 6.2420e-03 1.5242e-02 3.2920e-05 11 8 0 10 0 0 37.39 26.20 0.46 0.01524 0.01344 508 52 1 5 0 107.050 34.50 20.00 26.20 29.74 6.0 953.47 -82944 -73435 -80485 -72851 -85830 -74785 -84179 -73429 -73717 -60705 -66102 -59517 -38576 -33918 -26780 -20998 -16103 -16320 -11699 -13523 -13319 -17386 -14441 -6530 -10330 -9975 -6060 -10596 -11545 -8627 -7311 -2753 -664 -2163 -2203 -5739 -4326 -3012 805 1716 1576 2346 2126 3141 2174 2426 1498 1437 919 1192 1838 2287 2818 2449 2061 2472 2107 790 664 847 924 1732 2716 2846 1826 964 360 289 913 1127 1193 854 431 351 -415 -788 -1786 -2301 -2137 -1584 -1503 -1632 -2202 -1921 -1282 -697 -170 205 552 880 597 15 -482 -539 -257 -64 385 488 27 -249 -543 -1167 -824 -450 -1059 -1182 -774 -447 255 645 805 600 391 173 -82 144 45 144 80 12 -9 469 544 495 456 187 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