File name: Pandora256s1_MiamiFL-FIU_20241205_L2Fit_fout2c2d20230424p1-8.txt File generation date: 20241206T052442.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v2d20230424.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20241205_L1_smca1c2d20230424p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20241205 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0391 305.1801 305.3211 305.4621 305.6031 305.7441 305.8850 306.0260 306.1669 306.3078 306.4487 306.5896 306.7305 306.8714 307.0122 307.1531 307.2939 307.4347 307.5756 307.7164 307.8572 307.9979 308.1387 308.2795 308.4202 308.5610 308.7017 308.8424 308.9831 309.1238 309.2645 309.4051 309.5458 309.6864 309.8271 309.9677 310.1083 310.2489 310.3895 310.5301 310.6706 310.8112 310.9517 311.0923 311.2328 311.3733 311.5138 311.6543 311.7948 311.9352 312.0757 312.2161 312.3565 312.4969 312.6374 312.7777 312.9181 313.0585 313.1989 313.3392 313.4795 313.6199 313.7602 313.9005 314.0408 314.1810 314.3213 314.4616 314.6018 314.7420 314.8823 315.0225 315.1627 315.3029 315.4430 315.5832 315.7233 315.8635 316.0036 316.1437 316.2838 316.4239 316.5640 316.7041 316.8441 316.9842 317.1242 317.2642 317.4042 317.5442 317.6842 317.8242 317.9642 318.1041 318.2441 318.3840 318.5239 318.6638 318.8037 318.9436 319.0835 319.2233 319.3632 319.5030 319.6429 319.7827 319.9225 320.0623 320.2020 320.3418 320.4816 320.6213 320.7610 320.9008 321.0405 321.1802 321.3199 321.4595 321.5992 321.7388 321.8785 322.0181 322.1577 322.2973 322.4369 322.5765 322.7161 322.8556 322.9952 323.1347 323.2742 323.4137 323.5532 323.6927 323.8322 323.9716 324.1111 324.2505 324.3900 324.5294 324.6688 324.8082 324.9476 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241205T122454.0Z 9105.517291 52 1 55.70 2 84.66 118.11 133.03 98.94 0.00 1 0.00 1 0 17 8.815e-01 5.251e-02 3.478e-01 1.897e-02 8.619322e-01 1.084048e-02 8.353858e-03 -6.000000e+00 5.109020e-01 224.82 -2.00 3.16 -2.00 322.02 0.00e+00 -3.095456e-02 5.545087e-03 1.538782e-02 -6.000000e+00 2.640175e-02 289.39 -2.00 20.00 -2.00 321.41 0.00e+00 9.334 0.007 302.00 328.00 3 8.8857e-01 4.2223e-02 1.5946e-01 -6.0000e+00 1.2584e+00 1.4309e+00 5.4016e-02 1.9025e-01 -6.0000e+00 1.3803e+00 -1.7921e+00 3.4844e-02 4.1164e-02 -6.0000e+00 8.1849e-01 6.7320e-01 1.6605e-02 3.1958e-02 -6.0000e+00 3.5258e-01 9.7485e-06 6.0004e-04 5.3940e-04 2.2450e-04 -6.0000e+00 2.5932e-02 1.7788e-02 -4.9812e-05 12 8 8 10 0 0 70.24 25.87 1.66 0.01779 0.02230 19 2 1 5 0 2931.410 34.50 20.00 25.87 22.52 6.1 905.93 900000 78947 367753 348415 -9012 900000 14389 25789 37339 -8722 900000 60935 51197 -55186 31467 900000 66240 9810 174500 900000 -2659 -58416 -30103 900000 97069 -12907 900000 -43659 86942 13218 900000 191444 308665 121458 900000 900000 94895 900000 900000 46659 46532 900000 900000 900000 -10027 -10886 68607 334260 900000 81858 4092 270619 278826 38781 7880 -363 304708 75519 16467 203187 -7288 -17903 -7929 25303 -7580 63238 20552 24095 24938 3566 46197 30113 4499 1068 -11047 9216 44593 -36299 -28810 10816 67757 4092 28282 13136 -6979 5575 -9012 -2043 -14843 2492 5900 -8032 3289 -5957 4950 8787 -6669 -5487 3544 -6369 3564 -9442 -13358 13225 -20362 1285 14612 10775 8757 309 977 8223 -1959 -414 -1881 -1767 1203 793 -1702 132 502 10185 4923 -5202 -132 6392 -7625 -463 3007 -5288 -2134 1403 803 -4144 939 -1107 4272 1987 574 -1088 -1056 1165 -2314 900000 2647 6782 6426 -438 900000 603 1167 1753 -702 900000 2452 2318 -7402 1847 900000 2777 707 3218 900000 -187 -6856 -2877 900000 3580 -1493 900000 -5270 2332 687 900000 3531 5693 2647 900000 900000 2800 900000 900000 4044 4463 900000 900000 900000 -1350 -1365 3669 6165 900000 4076 491 4991 5142 4291 1279 -68 5620 6685 2399 4122 -1156 -3302 -1462 3687 -1580 6298 3146 3777 4369 888 8179 6442 1203 272 -2812 1683 5346 -10042 -8342 2494 10372 1366 8189 4724 -3282 2447 -4753 -1017 -8240 1103 2350 -3511 1286 -2758 2364 4716 -4846 -4513 2883 -5685 2689 -7279 -9855 7634 -17763 955 10106 8426 7865 348 1242 10495 -2836 -582 -2585 -2362 1589 1104 -2568 200 739 13018 6428 -7330 -172 7603 -10321 -635 4637 -9273 -4051 2787 1721 -10096 2349 -2967 11073 5334 1540 -2804 -2524 2541 -5110 SS 20241205T123632.3Z 9105.525374 55 1 54.56 2 82.36 119.52 130.55 99.76 0.00 1 0.00 1 0 25 5.466e-01 1.369e-02 1.243e-01 2.837e-03 7.257194e-01 1.493883e-03 7.516549e-03 -6.000000e+00 3.081784e-01 224.82 -2.00 3.16 -2.00 321.26 0.00e+00 -9.609630e-05 7.768821e-04 3.062937e-03 -6.000000e+00 1.416174e-02 289.39 -2.00 20.00 -2.00 320.63 0.00e+00 6.988 0.003 302.00 328.00 3 6.2441e-01 5.3417e-03 7.8436e-02 -6.0000e+00 7.5862e-01 1.9695e-01 7.4608e-03 4.0570e-02 -6.0000e+00 8.2524e-01 -3.3946e-01 7.1221e-03 1.8810e-02 -6.0000e+00 4.9481e-01 1.3658e-01 3.3373e-03 5.1050e-03 -6.0000e+00 2.1193e-01 1.5401e-04 -6.9448e-04 7.5042e-05 7.3734e-05 -6.0000e+00 1.4750e-02 1.6604e-02 2.6222e-05 12 8 8 10 0 0 65.12 25.88 0.68 0.01660 0.01139 117 12 1 5 0 466.290 34.50 20.00 25.88 23.01 6.1 910.61 -136803 -165310 -121210 -89009 -186969 -62803 -203745 -150100 -189272 -170558 -172926 -179750 -126973 -138102 -89355 -1185 -83025 -83769 -33093 -74864 -65357 -100182 -79092 33579 -76404 -59707 17477 -58121 -17724 -28115 -17109 4094 26414 10272 17837 37506 2024 30586 18768 339 5071 24323 11271 31376 7747 8433 13296 15045 14552 6269 2190 10704 14000 12042 4868 8027 13953 3437 528 11226 -1477 5555 6661 6268 3360 7120 2540 1338 3253 3623 4085 2429 668 1912 282 1345 187 -5669 -4091 -779 -113 -2342 -1186 -731 -1113 -866 133 484 -398 391 1062 -114 -774 -1843 -1238 -191 44 165 -1426 -874 -602 -1976 -2218 -58 -2896 -874 -745 -253 198 129 201 991 -86 372 -324 -70 60 83 5 109 190 1325 985 719 454 979 -51 463 556 -32 -14 105 -263 -380 67 -127 590 739 -30 -214 -407 -506 -827 -860 -1622 -823 -425 -2163 -226 -3270 -1620 -3456 -2831 -3110 -3929 -2073 -3248 -1632 -11 -1953 -2202 -568 -2051 -1664 -3603 -2429 372 -2790 -1966 271 -1849 -368 -700 -459 108 650 321 498 851 72 982 841 22 359 1534 851 1979 624 688 1060 1228 1264 642 263 1336 1871 1803 839 1410 2394 653 100 1864 -287 1110 1511 1625 954 1925 719 365 974 1253 1557 984 272 723 99 417 61 -1834 -1484 -329 -56 -1367 -693 -454 -744 -617 98 368 -305 286 722 -74 -495 -1251 -952 -170 42 182 -1624 -991 -688 -2058 -2120 -55 -3038 -953 -861 -293 253 187 305 1590 -141 590 -493 -103 89 129 8 187 321 2128 1534 1088 665 1481 -77 682 937 -57 -27 212 -565 -825 155 -294 1390 1766 -72 -519 -926 -1083 -1834 SS 20241205T125438.0Z 9105.537940 60 1 54.37 2 78.86 121.83 126.72 101.05 0.00 1 0.00 1 0 17 2.197e-01 8.377e-03 1.237e-02 7.551e-04 5.505483e-01 3.814579e-04 5.797194e-03 -6.000000e+00 1.238648e-01 224.82 -2.00 3.16 -2.00 319.70 0.00e+00 1.181222e-03 1.193917e-04 9.695231e-04 -6.000000e+00 5.691626e-03 289.39 -2.00 20.00 -2.00 318.91 0.00e+00 4.993 0.001 302.00 328.00 3 3.1705e-01 1.1074e-03 5.5567e-02 -6.0000e+00 3.0491e-01 9.8342e-04 1.3368e-03 2.5935e-02 -6.0000e+00 3.3168e-01 -4.7051e-02 1.0870e-03 1.2823e-02 -6.0000e+00 1.9887e-01 1.6269e-02 5.6725e-04 3.6706e-03 -6.0000e+00 8.5183e-02 1.6085e-03 -2.3514e-04 2.0551e-05 4.2353e-05 -6.0000e+00 5.9281e-03 1.6275e-02 2.7240e-05 11 8 0 10 0 0 21.88 25.85 0.46 0.01627 0.01451 452 46 1 5 0 120.270 34.50 20.00 25.85 24.43 6.0 919.01 -71193 -64807 -78874 -67056 -77940 -77828 -80788 -68208 -68942 -64172 -59279 -55893 -43033 -41260 -25313 -16607 -19610 -16524 -10758 -14099 -11472 -17377 -13145 -6518 -11408 -9740 -4255 -9684 -8909 -10110 -2802 -1844 -750 -2658 -2857 -3899 -3503 -1271 761 1532 984 2802 2156 2928 2106 1699 1548 1381 1113 1198 1854 2427 2308 2384 2159 2120 2457 1084 811 838 754 1820 2559 2775 1752 989 537 80 897 1205 1187 634 551 138 -541 -1031 -1767 -2307 -2087 -1649 -1485 -1774 -2280 -1986 -1178 -543 -161 562 614 708 635 -34 -367 -546 -380 -140 494 655 25 -231 -453 -1135 -837 -465 -1129 -1128 -674 -503 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