File name: Pandora256s1_MiamiFL-FIU_20250106_L2Fit_fout2c2d20230424p1-8.txt File generation date: 20250107T053229.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v2d20230424.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20250106_L1_smca1c2d20230424p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20250106 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0391 305.1801 305.3211 305.4621 305.6031 305.7441 305.8850 306.0260 306.1669 306.3078 306.4487 306.5896 306.7305 306.8714 307.0122 307.1531 307.2939 307.4347 307.5756 307.7164 307.8572 307.9979 308.1387 308.2795 308.4202 308.5610 308.7017 308.8424 308.9831 309.1238 309.2645 309.4051 309.5458 309.6864 309.8271 309.9677 310.1083 310.2489 310.3895 310.5301 310.6706 310.8112 310.9517 311.0923 311.2328 311.3733 311.5138 311.6543 311.7948 311.9352 312.0757 312.2161 312.3565 312.4969 312.6374 312.7777 312.9181 313.0585 313.1989 313.3392 313.4795 313.6199 313.7602 313.9005 314.0408 314.1810 314.3213 314.4616 314.6018 314.7420 314.8823 315.0225 315.1627 315.3029 315.4430 315.5832 315.7233 315.8635 316.0036 316.1437 316.2838 316.4239 316.5640 316.7041 316.8441 316.9842 317.1242 317.2642 317.4042 317.5442 317.6842 317.8242 317.9642 318.1041 318.2441 318.3840 318.5239 318.6638 318.8037 318.9436 319.0835 319.2233 319.3632 319.5030 319.6429 319.7827 319.9225 320.0623 320.2020 320.3418 320.4816 320.6213 320.7610 320.9008 321.0405 321.1802 321.3199 321.4595 321.5992 321.7388 321.8785 322.0181 322.1577 322.2973 322.4369 322.5765 322.7161 322.8556 322.9952 323.1347 323.2742 323.4137 323.5532 323.6927 323.8322 323.9716 324.1111 324.2505 324.3900 324.5294 324.6688 324.8082 324.9476 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250106T130947.7Z 9137.548469 63 1 54.48 2 78.83 121.80 135.55 51.86 0.00 1 0.00 1 0 17 2.110e-01 7.827e-03 2.372e-02 1.230e-03 5.527732e-01 6.222939e-04 5.812319e-03 -6.000000e+00 1.187233e-01 224.40 -2.00 3.16 -2.00 319.83 0.00e+00 1.051752e-03 2.024143e-04 1.021927e-03 -6.000000e+00 5.436363e-03 288.07 -2.00 20.00 -2.00 319.07 0.00e+00 4.982 0.001 302.00 328.00 3 1.2489e+00 1.8185e-03 5.5546e-02 -6.0000e+00 2.9211e-01 1.4147e-02 2.2132e-03 2.6166e-02 -6.0000e+00 3.1798e-01 -3.8929e-02 1.8597e-03 1.2906e-02 -6.0000e+00 1.9056e-01 9.6834e-03 9.6616e-04 3.6434e-03 -6.0000e+00 8.1548e-02 6.3097e-04 -7.3870e-04 3.3668e-05 4.2864e-05 -6.0000e+00 5.6947e-03 1.7272e-02 -6.4178e-05 11 8 0 10 0 0 99.98 26.03 0.47 0.01727 0.01172 183 19 1 5 0 297.700 34.50 19.99 26.03 27.42 6.1 937.18 -64882 -51263 -66201 -64943 -89371 -66584 -81685 -74544 -62167 -61015 -54889 -49428 -44068 -40482 -22062 -13947 -22791 -16154 -13356 -10241 -14139 -22378 -12324 -8624 -15261 -13533 -4983 -14374 -10808 -12182 -3909 -3620 1053 -3284 -1650 -5383 -3626 -1073 906 -168 -228 3250 1698 4147 465 1055 2500 1735 2338 405 1423 2454 2861 2201 1629 2488 3137 833 394 1254 761 2109 2550 2966 1439 823 -362 -163 792 880 1480 284 581 597 -369 -1386 -1827 -2835 -2098 -1637 -1378 -1719 -1584 -1716 -1168 -750 16 237 530 950 529 253 -41 -551 -328 82 522 572 70 -275 -525 -1116 -828 -233 -1180 -1073 -777 -339 204 670 594 625 309 112 -379 -43 168 378 254 118 -1 515 602 418 359 124 12 553 331 15 -82 -104 -495 -224 -149 -118 354 366 121 -58 -248 -367 -429 -825 -664 -1072 -1013 -1630 -951 -1480 -1449 -1223 -1296 -1146 -1085 -1131 -1263 -709 -490 -979 -713 -620 -488 -723 -1248 -654 -484 -998 -925 -319 -978 -690 -835 -287 -311 99 -346 -164 -552 -405 -139 142 -29 -45 659 367 897 106 243 576 413 573 107 413 785 913 768 605 956 1236 336 156 485 306 921 1156 1492 764 425 -185 -85 450 534 986 200 405 395 -226 -830 -1023 -1610 -1218 -1112 -1012 -1438 -1353 -1557 -1063 -728 16 247 550 945 491 233 -36 -500 -311 89 610 718 90 -354 -667 -1291 -935 -267 -1399 -1345 -1025 -452 280 1017 942 989 486 176 -564 -63 252 565 405 188 -2 826 935 628 542 180 17 809 518 26 -142 -191 -914 -437 -298 -239 732 770 255 -118 -495 -697 -830 SS 20250106T131410.1Z 9137.551506 66 1 3.08 2 78.00 122.38 134.79 52.87 0.00 1 0.00 1 0 17 1.727e-01 9.088e-03 1.056e-01 5.718e-03 5.228858e-01 2.876900e-03 5.436477e-03 -6.000000e+00 9.727420e-02 224.40 -2.00 3.16 -2.00 319.57 0.00e+00 8.110117e-04 8.614414e-04 5.401216e-04 -6.000000e+00 4.449505e-03 288.07 -2.00 20.00 -2.00 318.80 0.00e+00 4.662 0.001 302.00 328.00 3 1.6522e+00 8.2373e-03 5.1938e-02 -6.0000e+00 2.3934e-01 -7.4581e-03 9.8987e-03 2.4193e-02 -6.0000e+00 2.6046e-01 -2.0620e-02 7.9966e-03 1.2068e-02 -6.0000e+00 1.5610e-01 3.4048e-03 4.1877e-03 3.6100e-03 -6.0000e+00 6.6854e-02 5.9126e-04 3.1505e-04 1.5740e-04 3.8692e-05 -6.0000e+00 4.6598e-03 1.4710e-02 7.8084e-05 12 9 1 12 1 1 34.46 26.03 0.47 0.01471 0.01708 6 13 1 5 0 439.900 34.75 20.00 26.03 27.60 6.1 938.35 -19912 -54921 12775 -67221 -68195 -29577 -61576 -71955 -49273 -58062 -15493 -76603 -52125 -34385 -16524 -1502 -7461 -6456 9029 -19051 2517 -16227 37 7391 -12678 -6549 -8015 -8232 -5076 -11948 -7796 1299 3777 318 -5164 -1496 -7699 10657 -1213 3527 -1746 -1540 6693 7002 1471 1262 4155 -1690 2171 2852 -42 1895 3628 2347 341 662 3305 -1431 333 532 116 1161 1912 1889 513 443 -528 -1166 1111 -188 1536 751 -821 627 430 -89 -2245 -2066 -1703 -1282 -1098 -2032 -2410 -1649 -754 -462 687 823 74 911 771 1889 -250 -814 -275 -381 569 824 -794 131 -254 -1181 -657 -222 -1246 -997 -879 -11 398 364 916 629 574 104 -153 -572 85 -30 433 18 -143 323 181 87 179 190 87 775 565 327 -416 -153 -752 74 -15 180 726 120 33 288 -641 -305 -668 -222 -1011 128 -1462 -1369 -396 -1236 -1846 -1154 -1619 -294 -2947 -1918 -1323 -654 -60 -354 -331 428 -1264 139 -1086 2 449 -1025 -530 -670 -666 -385 -1019 -735 130 423 39 -648 -179 -1086 1491 -214 712 -418 -394 1655 1768 397 347 1125 -453 629 795 -13 652 1338 950 137 277 1389 -630 141 222 50 547 1006 1024 292 243 -284 -643 658 -121 1072 553 -608 436 275 -55 -1319 -1211 -1096 -899 -834 -1764 -2151 -1547 -710 -464 720 887 80 942 742 1772 -228 -760 -267 -400 678 1055 -1057 172 -327 -1393 -755 -260 -1516 -1280 -1133 -15 559 541 1413 1011 912 158 -228 -856 128 -45 663 29 -230 503 286 132 261 278 124 1135 883 543 -723 -269 -1383 138 -28 362 1485 243 67 579 -1235 -578 -1244 SS 20250106T131900.7Z 9137.554869 69 1 54.44 2 77.08 123.03 133.94 53.96 0.00 1 0.00 1 0 17 1.143e-01 7.359e-03 6.323e-03 5.866e-04 4.911198e-01 2.935236e-04 5.185034e-03 -6.000000e+00 6.434333e-02 224.40 -2.00 3.16 -2.00 319.09 0.00e+00 1.104034e-03 7.449068e-05 5.328059e-04 -6.000000e+00 2.945577e-03 288.07 -2.00 20.00 -2.00 318.29 0.00e+00 4.355 0.001 302.00 328.00 3 5.1836e-01 8.1639e-04 4.8591e-02 -6.0000e+00 1.5831e-01 -3.6372e-03 9.5462e-04 2.2711e-02 -6.0000e+00 1.7231e-01 -2.6124e-02 7.0550e-04 1.1193e-02 -6.0000e+00 1.0327e-01 7.6680e-03 3.7378e-04 3.2451e-03 -6.0000e+00 4.4204e-02 2.5323e-03 -4.6517e-04 1.6157e-05 3.6206e-05 -6.0000e+00 3.0849e-03 1.6496e-02 -1.6036e-05 11 8 0 10 0 0 99.83 26.04 0.44 0.01650 0.01300 477 49 1 5 0 114.110 34.50 20.00 26.04 27.77 6.1 939.29 -40602 -31375 -37988 -33960 -41519 -42728 -47971 -35890 -33648 -32156 -32698 -30193 -19709 -17736 -11465 -6237 -4774 -5270 -3068 -3754 -5165 -5791 -3633 -2182 -3805 -3227 -2147 -5125 -5190 -3923 -1874 616 1357 -896 -3213 -3554 -2886 -1060 449 1000 343 1271 1418 1361 1361 1411 1145 1064 482 991 1590 2063 2441 2253 1601 1626 1337 710 323 576 874 1571 2419 2181 1266 366 -466 -513 321 693 525 501 358 183 -321 -1012 -1467 -2002 -1949 -1621 -1388 -1695 -2203 -1682 -1116 -653 3 324 567 763 531 125 -283 -179 -68 -114 428 642 184 -271 -565 -959 -620 -284 -924 -1024 -785 -520 219 605 639 509 354 160 -145 93 76 246 233 121 -2 443 471 477 469 102 282 789 435 173 -58 -174 -346 -46 -60 -172 257 288 -24 -137 -273 -394 -543 -1006 -819 -1130 -940 -1128 -1146 -1468 -1115 -1165 -1188 -1255 -1233 -877 -958 -710 -429 -357 -430 -263 -342 -491 -555 -356 -229 -400 -357 -239 -566 -608 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