File name: Pandora256s1_MiamiFL-FIU_20250305_L2Fit_fout2c2d20230424p1-8.txt File generation date: 20250306T053704.9Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.74 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v2d20230424.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20250305_L1_smca1c2d20230424p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20250305 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0391 305.1801 305.3211 305.4621 305.6031 305.7441 305.8850 306.0260 306.1669 306.3078 306.4487 306.5896 306.7305 306.8714 307.0122 307.1531 307.2939 307.4347 307.5756 307.7164 307.8572 307.9979 308.1387 308.2795 308.4202 308.5610 308.7017 308.8424 308.9831 309.1238 309.2645 309.4051 309.5458 309.6864 309.8271 309.9677 310.1083 310.2489 310.3895 310.5301 310.6706 310.8112 310.9517 311.0923 311.2328 311.3733 311.5138 311.6543 311.7948 311.9352 312.0757 312.2161 312.3565 312.4969 312.6374 312.7777 312.9181 313.0585 313.1989 313.3392 313.4795 313.6199 313.7602 313.9005 314.0408 314.1810 314.3213 314.4616 314.6018 314.7420 314.8823 315.0225 315.1627 315.3029 315.4430 315.5832 315.7233 315.8635 316.0036 316.1437 316.2838 316.4239 316.5640 316.7041 316.8441 316.9842 317.1242 317.2642 317.4042 317.5442 317.6842 317.8242 317.9642 318.1041 318.2441 318.3840 318.5239 318.6638 318.8037 318.9436 319.0835 319.2233 319.3632 319.5030 319.6429 319.7827 319.9225 320.0623 320.2020 320.3418 320.4816 320.6213 320.7610 320.9008 321.0405 321.1802 321.3199 321.4595 321.5992 321.7388 321.8785 322.0181 322.1577 322.2973 322.4369 322.5765 322.7161 322.8556 322.9952 323.1347 323.2742 323.4137 323.5532 323.6927 323.8322 323.9716 324.1111 324.2505 324.3900 324.5294 324.6688 324.8082 324.9476 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250305T121904.0Z 9195.513241 54 1 53.79 2 82.25 100.35 122.04 33.44 0.00 1 0.00 1 0 17 5.205e-01 2.465e-02 2.476e-01 7.214e-03 6.909223e-01 4.017429e-03 6.890989e-03 -6.000000e+00 3.031180e-01 226.50 -2.00 3.16 -2.00 321.36 0.00e+00 -1.741725e-02 2.065780e-03 6.239017e-03 -6.000000e+00 1.625103e-02 288.37 -2.00 20.00 -2.00 320.72 0.00e+00 6.897 0.003 302.00 328.00 3 2.2239e+00 1.4453e-02 8.9806e-02 -6.0000e+00 7.5260e-01 2.6061e-01 2.0433e-02 7.7198e-02 -6.0000e+00 8.2426e-01 -3.8659e-01 1.9890e-02 1.7197e-02 -6.0000e+00 4.8470e-01 1.4950e-01 9.2806e-03 2.2631e-02 -6.0000e+00 2.0722e-01 3.5214e-05 -4.4883e-04 2.1091e-04 1.4064e-04 -6.0000e+00 1.4578e-02 1.4660e-02 5.0964e-05 12 8 8 10 0 0 98.76 26.47 0.88 0.01466 0.01129 24 2 1 5 0 2241.070 35.00 20.01 26.47 29.23 6.1 947.74 900000 -54478 900000 -112467 -191988 900000 900000 1522 -76066 900000 900000 -58156 -32514 -73436 -50582 900000 -69612 4120 -30540 900000 -36479 -118068 -57818 900000 -31986 -43366 900000 -38553 20961 -12533 900000 96100 900000 94936 69820 900000 84370 357324 151701 19641 4072 91387 86826 139147 3341 8013 43743 26103 71086 6803 4357 35534 35828 3933 679 3655 34320 31478 -40651 34863 9677 -9001 3917 1400 -6148 12098 1657 1063 3041 -40 16094 7659 1315 2339 495 2052 4922 -10725 -7743 -1204 8387 -4111 1019 -1083 -210 -989 544 -658 -2676 2994 2688 -1800 420 -1358 -626 -369 342 -793 -1121 -2378 1134 -4274 -4511 3236 -4471 -2574 337 1903 3094 358 440 2122 47 1271 -2724 566 -490 1214 -89 -383 333 3333 2084 -110 266 1522 -3342 -1028 523 -1840 -1498 -68 79 -1164 761 50 1655 1008 -466 -5 159 -293 -1075 900000 -382 900000 -1004 -3429 900000 900000 11 -776 900000 900000 -668 -365 -1443 -923 900000 -1905 58 -643 900000 -870 -6462 -1907 900000 -1145 -1917 900000 -1515 412 -343 900000 1146 900000 1399 1274 900000 1480 2507 2129 1282 357 3591 3656 3417 309 697 2640 1905 3442 673 495 3341 3721 621 121 677 4937 4683 -11923 4575 1630 -1964 844 346 -1717 2751 415 280 881 -14 5285 2875 522 870 171 624 1354 -3485 -2717 -467 3466 -2215 577 -609 -126 -641 365 -458 -1893 1921 1615 -1067 261 -814 -419 -285 302 -809 -1245 -2671 1154 -4155 -4058 2739 -4421 -2647 356 2126 3762 462 633 3188 72 1886 -3996 774 -682 1740 -138 -615 524 4915 3013 -157 366 2001 -4491 -1424 810 -3295 -2715 -131 159 -2540 1752 114 3782 2357 -1101 -11 360 -629 -2273 SS 20250305T123710.6Z 9195.525818 62 1 54.49 2 78.24 102.46 119.76 37.15 0.00 1 0.00 1 0 17 1.339e-01 7.516e-03 1.337e-02 9.566e-04 5.071545e-01 4.839126e-04 5.305002e-03 -6.000000e+00 7.600110e-02 226.50 -2.00 3.16 -2.00 319.41 0.00e+00 8.412850e-04 1.340555e-04 7.929369e-04 -6.000000e+00 3.454815e-03 288.37 -2.00 20.00 -2.00 318.60 0.00e+00 4.752 0.001 302.00 328.00 3 1.0285e+00 1.3717e-03 5.2590e-02 -6.0000e+00 1.8788e-01 2.7001e-02 1.6257e-03 2.3920e-02 -6.0000e+00 2.0415e-01 -3.9284e-02 1.2623e-03 1.1730e-02 -6.0000e+00 1.2217e-01 8.9473e-03 6.6234e-04 3.3175e-03 -6.0000e+00 5.2099e-02 1.0179e-03 -1.7865e-04 2.6464e-05 3.7222e-05 -6.0000e+00 3.6152e-03 1.4550e-02 1.9214e-05 11 8 0 10 0 0 87.09 26.46 0.44 0.01455 0.01321 233 24 1 5 0 233.830 35.00 20.00 26.46 29.27 6.1 947.35 -41840 -36919 -25382 -39350 -48617 -44622 -59957 -40838 -41604 -44412 -40274 -33129 -28214 -31419 -16550 -4722 -12263 -7058 -6322 -6430 -8449 -10578 -8283 -2492 -5455 -5860 -1635 -8276 -7024 -7277 -1395 -17 2616 -1170 -4622 -3382 -3780 -2303 1114 142 1401 1102 1264 2956 1111 1701 2082 1171 1358 878 1820 2890 2220 2431 1653 1956 1803 1034 -1115 1288 639 1709 2299 2238 711 614 -808 -735 455 722 1055 542 147 323 -163 -1069 -2028 -2361 -2051 -1567 -1435 -1665 -1921 -1878 -1090 -505 256 525 735 910 605 -33 -400 -338 -317 110 480 709 49 -193 -571 -991 -748 -163 -958 -919 -715 -448 148 529 656 471 252 111 -260 99 107 410 298 238 72 740 529 426 258 -6 -69 648 347 -63 -241 -476 -398 -101 -34 -59 352 458 -13 -106 -181 -445 -409 -761 -740 -485 -841 -1039 -895 -1521 -983 -1153 -1375 -1240 -1038 -1021 -1457 -809 -240 -746 -444 -425 -456 -631 -810 -648 -201 -492 -563 -153 -798 -645 -700 -145 -2 345 -155 -608 -478 -538 -384 221 34 372 288 346 813 314 487 599 345 410 280 632 1101 854 1010 731 896 853 493 -530 591 306 822 1234 1330 414 368 -475 -439 275 499 753 407 110 229 -114 -680 -1205 -1401 -1332 -1109 -1173 -1451 -1725 -1785 -1045 -515 273 547 764 957 594 -32 -368 -316 -308 122 547 871 65 -255 -710 -1177 -867 -193 -1174 -1137 -930 -592 211 793 1025 736 406 170 -391 142 153 617 460 386 117 1161 807 652 379 -10 -99 953 544 -101 -420 -840 -704 -188 -66 -115 702 931 -27 -209 -351 -823 -768 SS 20250305T124222.3Z 9195.529425 65 1 54.36 2 77.10 103.07 119.07 38.17 0.00 1 0.00 1 0 17 8.807e-02 6.856e-03 7.942e-03 7.799e-04 4.688326e-01 3.925451e-04 4.932166e-03 -6.000000e+00 4.997492e-02 226.50 -2.00 3.16 -2.00 319.01 0.00e+00 9.338632e-04 9.600126e-05 5.518566e-04 -6.000000e+00 2.271987e-03 288.37 -2.00 20.00 -2.00 318.18 0.00e+00 4.361 0.001 302.00 328.00 3 1.0560e+00 1.0921e-03 4.8298e-02 -6.0000e+00 1.2354e-01 1.6994e-02 1.2716e-03 2.1908e-02 -6.0000e+00 1.3424e-01 -3.1662e-02 9.2103e-04 1.0719e-02 -6.0000e+00 8.0335e-02 7.0735e-03 4.8630e-04 3.0604e-03 -6.0000e+00 3.4256e-02 1.4961e-03 -2.3764e-04 2.1707e-05 3.2775e-05 -6.0000e+00 2.3775e-03 1.4858e-02 8.0071e-06 11 8 0 10 0 0 97.57 26.46 0.48 0.01486 0.01307 288 30 1 5 0 188.730 34.75 20.00 26.46 29.49 6.2 949.84 -28601 -28396 -13618 -29836 -33672 -32157 -36978 -32283 -27803 -25105 -22678 -23373 -14752 -12325 -9550 -4485 -5487 -4939 -3649 -3233 -2655 -6293 -3543 -1316 -3125 -2522 -1607 -4119 -3741 -3753 -714 1560 941 -331 -3871 -3245 -2341 -967 461 514 579 829 1073 1993 1179 1223 1078 931 942 654 1528 1805 2101 1678 1474 1397 1648 326 -1006 716 604 1803 2149 2101 691 268 -686 -844 531 742 815 678 171 249 -16 -642 -1622 -2107 -1755 -1678 -1277 -1667 -2097 -1637 -1033 -563 63 343 685 705 416 123 -287 -245 -242 -72 514 675 194 -174 -486 -923 -750 -165 -850 -938 -633 -431 257 592 507 469 239 55 -271 153 160 336 293 205 102 454 546 345 443 56 71 645 316 38 -195 -328 -328 -113 -54 -98 361 363 33 -122 -237 -355 -561 -737 -840 -370 -921 -981 -898 -1170 -1115 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