File name: Pandora256s1_MiamiFL-FIU_20250419_L2Fit_fout2c2d20230424p1-8.txt File generation date: 20250420T052604.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v2d20230424.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20250419_L1_smca1c2d20230424p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20250419 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0391 305.1801 305.3211 305.4621 305.6031 305.7441 305.8850 306.0260 306.1669 306.3078 306.4487 306.5896 306.7305 306.8714 307.0122 307.1531 307.2939 307.4347 307.5756 307.7164 307.8572 307.9979 308.1387 308.2795 308.4202 308.5610 308.7017 308.8424 308.9831 309.1238 309.2645 309.4051 309.5458 309.6864 309.8271 309.9677 310.1083 310.2489 310.3895 310.5301 310.6706 310.8112 310.9517 311.0923 311.2328 311.3733 311.5138 311.6543 311.7948 311.9352 312.0757 312.2161 312.3565 312.4969 312.6374 312.7777 312.9181 313.0585 313.1989 313.3392 313.4795 313.6199 313.7602 313.9005 314.0408 314.1810 314.3213 314.4616 314.6018 314.7420 314.8823 315.0225 315.1627 315.3029 315.4430 315.5832 315.7233 315.8635 316.0036 316.1437 316.2838 316.4239 316.5640 316.7041 316.8441 316.9842 317.1242 317.2642 317.4042 317.5442 317.6842 317.8242 317.9642 318.1041 318.2441 318.3840 318.5239 318.6638 318.8037 318.9436 319.0835 319.2233 319.3632 319.5030 319.6429 319.7827 319.9225 320.0623 320.2020 320.3418 320.4816 320.6213 320.7610 320.9008 321.0405 321.1802 321.3199 321.4595 321.5992 321.7388 321.8785 322.0181 322.1577 322.2973 322.4369 322.5765 322.7161 322.8556 322.9952 323.1347 323.2742 323.4137 323.5532 323.6927 323.8322 323.9716 324.1111 324.2505 324.3900 324.5294 324.6688 324.8082 324.9476 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250419T113339.3Z 9240.481705 227 1 54.20 2 82.19 81.11 57.41 199.48 0.00 1 0.00 1 0 17 5.912e-01 1.799e-02 2.474e-01 4.898e-03 7.824370e-01 2.650100e-03 7.919166e-03 -6.000000e+00 3.391789e-01 229.68 -2.00 3.16 -2.00 321.52 0.00e+00 -5.044515e-03 1.468046e-03 3.973797e-03 -6.000000e+00 1.538975e-02 290.49 -2.00 20.00 -2.00 320.90 0.00e+00 6.856 0.003 302.00 328.00 3 1.4590e+00 1.0026e-02 8.1573e-02 -6.0000e+00 8.4418e-01 3.4762e-01 1.4257e-02 5.1828e-02 -6.0000e+00 9.1508e-01 -4.9362e-01 1.3610e-02 1.9880e-02 -6.0000e+00 5.4688e-01 1.8957e-01 6.2595e-03 8.5566e-03 -6.0000e+00 2.3195e-01 6.7489e-05 -8.5508e-04 1.2904e-04 6.8343e-05 -6.0000e+00 1.5978e-02 1.8598e-02 -7.8338e-05 12 8 8 10 0 0 99.89 26.46 0.72 0.01860 0.01217 57 6 1 5 0 950.740 34.75 20.00 26.46 28.79 6.2 944.77 -175951 -116796 -180553 -169762 -101942 -119882 -226508 -232006 -202883 -111865 -161751 -119614 33326 -142317 -91427 25705 52670 -103647 -43345 -46856 -80730 -128772 -46123 86063 -56024 -49365 104484 -25106 -17559 -28992 9595 3128 53979 63813 72175 81774 26608 57632 73693 46771 10841 50220 51888 52487 -5597 21110 28345 22045 27112 -7333 8835 26425 27699 11356 18712 14209 27084 17848 -28032 20427 2180 8303 4151 378 781 10726 4935 4731 2498 3028 11698 2460 1187 3849 1510 2146 966 -5699 -2674 590 2729 -2133 79 -1379 -881 -586 945 149 -947 3075 1268 -275 -543 -1831 -3365 246 -295 137 -2243 -946 -589 -3449 -2795 304 -2305 -2865 -3510 71 986 506 448 1093 39 579 -1488 246 -51 44 75 858 471 1511 1572 336 -56 1773 -8 457 884 -54 -575 40 -308 -630 70 155 643 640 40 -81 -31 -670 -1321 -1681 -710 -2195 -1769 -487 -677 -4131 -5238 -3964 -1069 -2704 -1485 159 -3467 -1659 172 302 -3119 -766 -895 -2198 -5658 -947 534 -1606 -1415 649 -540 -335 -665 179 75 902 1036 1034 1055 661 1266 1725 1742 658 2207 2330 2356 -446 1301 1652 1421 1761 -732 848 2411 2765 1470 2422 2036 3544 2549 -6079 2634 344 1352 807 87 189 2326 1141 1157 703 983 3850 926 445 1316 478 604 260 -1696 -882 227 1213 -1045 42 -792 -540 -382 637 104 -663 1984 778 -162 -315 -1143 -2443 202 -285 140 -2548 -1061 -615 -3327 -2673 286 -2191 -2899 -3794 81 1230 667 664 1724 62 908 -2277 359 -75 68 124 1447 782 2374 2382 500 -80 2632 -12 664 1471 -97 -1144 85 -652 -1437 172 395 1566 1583 99 -203 -72 -1480 -2859 SS 20250419T114856.7Z 9240.492323 232 1 54.36 2 78.78 82.69 58.61 203.08 0.00 1 0.00 1 0 17 2.949e-01 8.560e-03 2.242e-02 1.067e-03 6.009273e-01 5.522117e-04 6.244656e-03 -6.000000e+00 1.693347e-01 229.68 -2.00 3.16 -2.00 320.03 0.00e+00 6.428196e-04 1.914998e-04 1.418277e-03 -6.000000e+00 7.676872e-03 290.49 -2.00 20.00 -2.00 319.25 0.00e+00 4.961 0.001 302.00 328.00 3 8.9505e-01 1.6558e-03 5.7041e-02 -6.0000e+00 4.2146e-01 2.0238e-02 2.0405e-03 2.9448e-02 -6.0000e+00 4.5673e-01 -6.5233e-02 1.7431e-03 1.4156e-02 -6.0000e+00 2.7297e-01 2.1627e-02 8.9401e-04 3.8035e-03 -6.0000e+00 1.1587e-01 8.5990e-04 -5.6355e-05 2.8859e-05 4.7868e-05 -6.0000e+00 7.9671e-03 1.5881e-02 4.6739e-05 11 8 0 10 0 0 45.21 26.44 0.51 0.01588 0.01546 255 26 1 5 0 213.150 34.75 19.99 26.44 29.51 6.2 949.68 -101016 -81514 -80120 -104156 -107993 -95671 -115347 -97173 -100434 -86517 -73826 -70562 -59481 -53475 -31275 -23132 -24424 -23825 -21768 -16542 -20217 -22791 -20379 -10580 -13135 -12152 -5381 -13709 -16186 -13116 -2926 -4413 -596 -63 -7788 -5729 -3446 -2085 1312 2300 2133 2263 3309 3128 1172 1176 2284 418 2210 -59 876 3111 3117 2429 2803 2576 3133 1754 -1438 1790 880 2436 3252 3541 1565 1071 8 -39 1497 1379 1256 986 315 520 -428 -1221 -1665 -2606 -2060 -1699 -1302 -1504 -1968 -1923 -1168 -512 54 313 672 1137 715 141 -557 -504 -731 -139 171 665 -56 -256 -594 -1131 -914 -305 -1023 -1077 -835 -311 375 555 509 549 355 44 -338 75 150 241 279 93 204 487 636 450 524 89 -56 660 282 99 -138 -265 -320 -106 -115 -53 356 371 90 -99 -234 -422 -536 -1282 -1001 -1050 -1701 -1686 -1304 -2100 -1709 -2101 -1728 -1367 -1417 -1331 -1430 -836 -681 -821 -880 -856 -656 -860 -1003 -925 -481 -671 -656 -278 -745 -879 -737 -174 -317 -48 -5 -694 -497 -324 -232 175 333 350 399 608 590 228 234 458 88 476 -14 227 884 892 763 933 900 1125 639 -527 627 322 966 1451 1627 767 512 4 -19 799 790 796 655 209 326 -248 -691 -883 -1409 -1148 -1115 -926 -1221 -1647 -1708 -1040 -484 53 319 681 1102 648 128 -487 -453 -692 -142 191 799 -73 -333 -727 -1323 -1042 -352 -1218 -1357 -1054 -418 521 818 790 891 575 68 -521 110 223 375 443 155 335 771 973 696 776 127 -81 955 440 166 -243 -492 -601 -202 -235 -110 753 797 193 -205 -475 -813 -1048 SS 20250419T115422.8Z 9240.496097 235 1 54.39 2 77.57 83.25 59.08 204.32 0.00 1 0.00 1 0 17 1.932e-01 8.103e-03 1.140e-02 7.463e-04 5.513262e-01 3.824401e-04 5.748616e-03 -6.000000e+00 1.109554e-01 229.68 -2.00 3.16 -2.00 319.56 0.00e+00 1.455352e-03 1.119398e-04 9.932684e-04 -6.000000e+00 5.030370e-03 290.49 -2.00 20.00 -2.00 318.73 0.00e+00 4.512 0.001 302.00 328.00 3 6.9450e-01 1.1060e-03 5.1815e-02 -6.0000e+00 2.7616e-01 1.2849e-02 1.3193e-03 2.6308e-02 -6.0000e+00 2.9927e-01 -4.9924e-02 1.0358e-03 1.2947e-02 -6.0000e+00 1.7886e-01 1.6202e-02 5.4111e-04 3.7076e-03 -6.0000e+00 7.5921e-02 1.6792e-03 -7.1535e-05 2.0321e-05 4.1960e-05 -6.0000e+00 5.2205e-03 1.5907e-02 4.2267e-05 11 8 0 10 0 0 55.80 26.44 0.43 0.01591 0.01537 380 39 1 5 0 143.120 34.75 20.00 26.44 29.84 6.2 951.40 -70700 -60766 -67053 -47384 -70710 -71180 -73309 -63055 -59789 -46532 -54163 -51802 -37335 -30662 -22621 -13623 -13695 -14283 -9405 -10907 -9790 -11724 -11328 -6130 -7220 -7925 -4558 -9044 -8808 -7448 -3074 -1164 464 -1346 -3662 -3313 -4111 -2160 667 1190 382 2388 1287 2019 2048 1550 1214 1094 1025 910 1653 2455 2258 2157 2256 1801 2301 1407 -293 1274 1459 2474 2733 2566 1293 918 181 -380 372 1251 1105 681 501 262 -365 -962 -2117 -2201 -1954 -1524 -1336 -1772 -2253 -1762 -1261 -448 23 331 560 796 565 85 -580 -517 -379 -8 400 641 100 -207 -565 -1155 -804 -425 -995 -1041 -805 -454 177 568 530 457 365 214 -274 27 33 250 288 188 179 548 636 488 499 118 307 753 374 150 -115 -265 -296 -50 -72 -146 335 343 -30 -96 -333 -500 -486 -1261 -1145 -1449 -821 -1415 -1404 -1606 -1432 -1501 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