File name: Pandora256s1_MiamiFL-FIU_20250521_L2Fit_fout2c2d20230424p1-8.txt File generation date: 20250522T052120.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v2d20230424.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20250521_L1_smca1c2d20230424p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20250521 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0391 305.1801 305.3211 305.4621 305.6031 305.7441 305.8850 306.0260 306.1669 306.3078 306.4487 306.5896 306.7305 306.8714 307.0122 307.1531 307.2939 307.4347 307.5756 307.7164 307.8572 307.9979 308.1387 308.2795 308.4202 308.5610 308.7017 308.8424 308.9831 309.1238 309.2645 309.4051 309.5458 309.6864 309.8271 309.9677 310.1083 310.2489 310.3895 310.5301 310.6706 310.8112 310.9517 311.0923 311.2328 311.3733 311.5138 311.6543 311.7948 311.9352 312.0757 312.2161 312.3565 312.4969 312.6374 312.7777 312.9181 313.0585 313.1989 313.3392 313.4795 313.6199 313.7602 313.9005 314.0408 314.1810 314.3213 314.4616 314.6018 314.7420 314.8823 315.0225 315.1627 315.3029 315.4430 315.5832 315.7233 315.8635 316.0036 316.1437 316.2838 316.4239 316.5640 316.7041 316.8441 316.9842 317.1242 317.2642 317.4042 317.5442 317.6842 317.8242 317.9642 318.1041 318.2441 318.3840 318.5239 318.6638 318.8037 318.9436 319.0835 319.2233 319.3632 319.5030 319.6429 319.7827 319.9225 320.0623 320.2020 320.3418 320.4816 320.6213 320.7610 320.9008 321.0405 321.1802 321.3199 321.4595 321.5992 321.7388 321.8785 322.0181 322.1577 322.2973 322.4369 322.5765 322.7161 322.8556 322.9952 323.1347 323.2742 323.4137 323.5532 323.6927 323.8322 323.9716 324.1111 324.2505 324.3900 324.5294 324.6688 324.8082 324.9476 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250521T110249.5Z 9272.460295 174 1 55.80 2 84.60 70.06 39.29 147.36 0.00 1 0.00 1 0 33 6.978e-01 7.282e-02 3.012e-01 2.352e-02 1.058324e+00 1.410779e-02 1.936564e-02 -6.000000e+00 4.261828e-01 230.52 -2.00 3.16 -2.00 321.95 0.00e+00 -1.225835e-01 6.459579e-03 2.108744e-03 -6.000000e+00 2.091288e-02 292.29 -2.00 20.00 -2.00 321.24 0.00e+00 9.243 0.007 302.00 328.00 3 1.1388e+00 5.4586e-02 1.5434e-01 -6.0000e+00 1.0734e+00 1.4503e+00 6.9043e-02 2.1713e-01 -6.0000e+00 1.1825e+00 -1.8036e+00 4.1967e-02 3.8291e-02 -6.0000e+00 6.8390e-01 6.6202e-01 2.0403e-02 1.0266e-01 -6.0000e+00 2.8490e-01 7.8289e-06 -8.7484e-04 6.1679e-04 1.6404e-03 -6.0000e+00 2.1121e-02 1.5188e-02 7.3198e-05 12 8 8 10 0 0 -30.58 26.70 2.18 0.01519 0.00861 15 2 1 5 0 3719.590 35.00 19.99 26.70 31.93 6.2 963.60 -11607 7407 -37368 900000 -108455 900000 -57887 14576 44874 117547 269160 185340 900000 7672 6509 113799 900000 -39514 -11146 29581 -35414 23191 11149 900000 173394 127342 900000 72621 334261 10176 900000 900000 900000 900000 900000 900000 900000 900000 900000 164209 72410 900000 900000 900000 25352 13836 60651 138251 900000 -28650 2062 900000 900000 33494 19720 40521 900000 900000 -75280 343414 32995 -16885 1832 -14651 -6973 48822 19522 -17880 23101 18971 150434 21640 32149 22513 11223 45112 15593 -4910 -26829 4938 90696 5499 33388 3805 -6978 9073 8599 2123 -4269 25936 6411 7416 9423 910 -5633 -6825 8074 -499 9420 -9858 14221 -16988 -8429 18581 -7031 4378 4258 10237 9716 -2802 2605 11921 -4015 6395 -9486 4890 416 6633 -2657 -664 -4432 7138 4494 -4843 1222 10188 -8399 -3551 -1407 -9270 -4574 231 -786 -5071 2251 2347 3272 5348 -1860 -243 -224 1999 -2442 -578 246 -1550 900000 -5850 900000 -3843 937 3817 7316 6142 6536 900000 780 513 2597 900000 -3197 -624 1043 -2351 914 694 900000 6835 10567 900000 6930 7628 718 900000 900000 900000 900000 900000 900000 900000 900000 900000 6813 9314 900000 900000 900000 3008 1452 3322 3155 900000 -3727 226 900000 900000 4127 3375 6935 900000 900000 -39356 7837 4066 -3160 293 -2942 -1321 5125 2807 -4162 4217 4286 10299 5728 7630 5497 2715 6691 2811 -1064 -7653 1161 10555 1769 9295 1563 -3471 4100 4042 1066 -2202 9233 2575 2860 3656 420 -3149 -4361 4974 -375 6900 -8751 9346 -13840 -5809 9922 -5246 3067 3119 7546 8004 -3024 3074 14200 -5909 8566 -14504 6238 550 8447 -3862 -963 -6453 8763 5455 -6322 1470 10951 -10696 -4628 -2090 -17304 -8369 443 -1657 -12213 5502 6071 8558 13792 -5046 -607 -511 4109 -5061 SS 20250521T111353.1Z 9272.467975 177 1 54.15 2 82.25 71.17 38.00 151.14 0.00 1 0.00 1 0 17 5.798e-01 1.553e-02 1.999e-01 3.601e-03 7.674816e-01 1.947427e-03 7.779617e-03 -6.000000e+00 3.339466e-01 230.52 -2.00 3.16 -2.00 321.40 0.00e+00 -5.821080e-03 1.046831e-03 4.350544e-03 -6.000000e+00 1.521130e-02 292.29 -2.00 20.00 -2.00 320.75 0.00e+00 6.893 0.003 302.00 328.00 3 1.0007e+00 7.2733e-03 8.2207e-02 -6.0000e+00 8.3233e-01 2.6384e-01 1.0275e-02 5.3582e-02 -6.0000e+00 9.0115e-01 -4.0514e-01 9.6369e-03 1.9282e-02 -6.0000e+00 5.3880e-01 1.5901e-01 4.4577e-03 9.3285e-03 -6.0000e+00 2.2872e-01 1.0805e-04 -7.0040e-05 9.4626e-05 6.3094e-05 -6.0000e+00 1.5669e-02 1.5645e-02 1.4179e-05 12 8 8 10 0 0 97.40 26.70 0.68 0.01565 0.01512 77 8 1 5 0 703.190 35.00 20.00 26.70 32.38 6.2 966.81 -183924 -92692 -182629 -41813 -186732 86902 -195911 -186563 -205566 -181911 -143168 -106269 -84652 -158113 -135254 -7904 -74920 -65069 -75711 -30260 -97331 -105532 -66725 163477 -70213 -52710 33447 -71819 -36489 -64211 45551 3076 59750 18693 2130 26068 26682 15091 26397 5263 10922 33406 42119 48537 9754 15820 17040 9732 34169 8484 6301 21371 20999 12417 11844 11348 20544 13122 -17753 15409 974 5414 3469 4534 792 10148 1969 -1514 7269 4260 9213 2703 2007 657 862 -2977 -1422 -4704 -4609 -1809 682 -2648 -352 -912 -1397 669 310 1310 44 1856 1499 -419 -198 -837 -2568 -1444 -216 -464 -1095 -1546 -258 -2751 -2064 120 -1768 -1592 -687 -385 -31 597 196 777 -115 572 -1273 102 -12 639 345 427 414 1452 1144 916 295 681 -367 97 659 -265 -72 -211 -544 -573 538 -182 794 785 -96 -159 -331 -608 -859 -1644 -385 -1983 -147 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20.00 -2.00 319.07 0.00e+00 4.943 0.001 302.00 328.00 3 6.9943e-01 1.4634e-03 5.6424e-02 -6.0000e+00 3.7329e-01 2.8319e-02 1.7857e-03 2.8554e-02 -6.0000e+00 4.0411e-01 -7.1781e-02 1.4731e-03 1.3677e-02 -6.0000e+00 2.4163e-01 2.4575e-02 7.6083e-04 3.6566e-03 -6.0000e+00 1.0260e-01 1.0869e-03 2.5284e-05 2.5821e-05 4.2462e-05 -6.0000e+00 7.0243e-03 1.4355e-02 4.9896e-05 11 8 0 10 0 0 5.57 26.68 0.49 0.01435 0.01454 309 32 1 5 0 175.960 35.00 20.00 26.68 33.29 6.2 972.76 -79665 -79134 -71436 -101019 -97177 -86910 -97014 -81113 -75939 -83020 -68450 -60738 -52126 -45188 -36707 -22331 -19495 -16213 -13677 -16718 -18208 -21815 -17942 -6814 -13759 -10473 -8354 -12611 -8742 -9902 -5499 -1365 399 -814 -8261 -5340 -5201 -3621 2154 1206 2832 2762 2422 3669 2147 2330 2074 444 1904 301 1836 3176 2705 2873 2485 2358 2931 1272 -1369 1514 886 1652 3006 3183 1629 1260 181 181 860 1145 1245 798 268 531 -334 -782 -1776 -2395 -2118 -1814 -1502 -1416 -2218 -1882 -1096 -406 8 488 777 656 493 196 -543 -540 -491 -321 180 470 56 -331 -564 -1220 -695 -313 -1031 -1097 -771 -489 270 671 671 597 238 132 -281 59 70 368 302 82 97 479 730 499 426 66 103 634 296 48 -110 -263 -328 -138 -15 -106 356 449 10 -74 -346 -459 -470 -1030 -1192 -1076 -2001 -1699 -1350 -1823 -1501 -1533 -1969 -1471 -1344 -1309 -1336 -1239 -777 -740 -656 -585 -782 -894 -1118 -931 -349 -824 -647 -516 -786 -510 -620 -385 -108 36 -79 -836 -521 -562 -460 320 198 516 542 501 768 462 511 463 103 454 78 517 905 848 978 903 897 1145 506 -545 578 352 717 1343 1585 860 646 92 95 457 700 784 528 177 356 -207 -437 -1007 -1276 -1251 -1175 -1129 -1134 -1957 -1654 -1025 -381 8 493 782 637 472 175 -469 -479 -484 -343 209 587 72 -427 -717 -1411 -780 -357 -1216 -1371 -966 -653 372 980 1030 961 381 204 -425 85 102 564 472 135 158 751 1155 763 626 98 148 945 473 79 -197 -481 -604 -269 -30 -216 741 950 21 -152 -694 -906 -906 SS 20250521T113539.2Z 9272.483093 185 1 54.42 2 77.58 73.26 35.89 159.22 0.00 1 0.00 1 0 22 1.732e-01 7.966e-03 1.040e-02 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