File name: Pandora256s1_MiamiFL-FIU_20250528_L2Fit_fout2c2d20230424p1-8.txt File generation date: 20250529T052325.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Paulo Olivas Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 256 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora256_OF_v3d20221212.txt Instrument calibration file used: Pandora256s1_CF_v2d20230424.txt Level 1 file used: Pandora256s1_MiamiFL-FIU_20250528_L1_smca1c2d20230424p1-8.txt Full location name: Florida International University (FIU), Miami, FL Short location name: MiamiFL-FIU Country of location: United States Location latitude [deg]: 25.7569 Location longitude [deg]: -80.3738 Location altitude [m]: 43 Local noon date: 20250528 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OoB session based on session 1 First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0391 305.1801 305.3211 305.4621 305.6031 305.7441 305.8850 306.0260 306.1669 306.3078 306.4487 306.5896 306.7305 306.8714 307.0122 307.1531 307.2939 307.4347 307.5756 307.7164 307.8572 307.9979 308.1387 308.2795 308.4202 308.5610 308.7017 308.8424 308.9831 309.1238 309.2645 309.4051 309.5458 309.6864 309.8271 309.9677 310.1083 310.2489 310.3895 310.5301 310.6706 310.8112 310.9517 311.0923 311.2328 311.3733 311.5138 311.6543 311.7948 311.9352 312.0757 312.2161 312.3565 312.4969 312.6374 312.7777 312.9181 313.0585 313.1989 313.3392 313.4795 313.6199 313.7602 313.9005 314.0408 314.1810 314.3213 314.4616 314.6018 314.7420 314.8823 315.0225 315.1627 315.3029 315.4430 315.5832 315.7233 315.8635 316.0036 316.1437 316.2838 316.4239 316.5640 316.7041 316.8441 316.9842 317.1242 317.2642 317.4042 317.5442 317.6842 317.8242 317.9642 318.1041 318.2441 318.3840 318.5239 318.6638 318.8037 318.9436 319.0835 319.2233 319.3632 319.5030 319.6429 319.7827 319.9225 320.0623 320.2020 320.3418 320.4816 320.6213 320.7610 320.9008 321.0405 321.1802 321.3199 321.4595 321.5992 321.7388 321.8785 322.0181 322.1577 322.2973 322.4369 322.5765 322.7161 322.8556 322.9952 323.1347 323.2742 323.4137 323.5532 323.6927 323.8322 323.9716 324.1111 324.2505 324.3900 324.5294 324.6688 324.8082 324.9476 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250528T113416.6Z 9279.482137 66 1 54.87 2 77.53 71.89 91.96 57.55 0.00 1 0.00 1 0 25 5.118e-01 5.628e-02 3.048e-01 1.841e-02 5.934561e-01 1.016924e-02 6.630269e-03 -6.000000e+00 3.044939e-01 230.24 -2.00 3.16 -2.00 320.46 0.00e+00 -4.334288e-02 3.760220e-03 1.056837e-03 -6.000000e+00 1.641406e-02 292.74 -2.00 20.00 -2.00 319.63 0.00e+00 4.499 0.001 302.00 328.00 3 5.5241e+00 3.2292e-02 6.3763e-02 -6.0000e+00 7.6071e-01 2.5561e-01 4.1253e-02 6.5103e-02 -6.0000e+00 8.3023e-01 -2.8295e-01 3.4655e-02 3.9895e-02 -6.0000e+00 4.9332e-01 1.1465e-01 1.7160e-02 4.8930e-02 -6.0000e+00 2.1341e-01 1.3079e-05 -1.0942e-03 5.6676e-04 4.3976e-04 -6.0000e+00 1.5079e-02 1.4682e-02 1.1427e-04 12 9 8 11 8 0 99.99 26.64 3.49 0.01468 0.00646 39 4 1 5 0 1406.870 35.00 20.00 26.64 34.22 6.2 977.98 900000 900000 900000 900000 170851 900000 900000 42788 130358 -8458 140394 54798 900000 -69109 28154 900000 900000 -83701 900000 111511 -29736 -55907 9049 900000 27450 13032 900000 30500 900000 18504 156170 900000 900000 20968 124562 110123 900000 900000 109328 72485 31887 96560 183233 265843 26938 19917 33434 11532 75837 -4416 -5677 38151 46942 2971 576 20107 63819 37247 -50997 42714 -7493 -4565 4555 -8095 -20297 2758 -5117 2925 4213 -1079 24965 -2915 1409 -1853 660 5961 13914 -4043 -6012 -6383 5066 -10181 8307 2946 -3723 642 27994 -650 -5166 2489 2118 46 5355 1911 -2096 3982 232 2329 -4208 -1674 3345 -4057 -6124 9658 -7352 -1651 -2993 4361 4296 -2021 601 5059 -1515 3764 -5490 -849 1083 1548 -1065 82 2801 3338 1343 273 -2185 3852 -5801 -629 395 -4035 -3007 -377 -602 -4906 1250 122 4103 2931 591 74 2685 -325 -3220 900000 900000 900000 900000 3057 900000 900000 766 2333 -275 2512 1070 900000 -4609 733 900000 900000 -7216 900000 1995 -1645 -4183 412 900000 1786 1259 900000 2183 900000 1060 2794 900000 900000 1426 2897 2956 900000 900000 5673 7004 5420 9157 7213 4757 4338 3207 4427 1836 6378 -869 -1249 6076 7560 824 181 5756 12790 9930 -31208 9401 -2588 -1568 1540 -3360 -9733 1002 -1950 1062 1681 -527 10498 -1716 797 -1034 330 2507 4905 -1649 -2646 -3209 2611 -6959 5202 2082 -3031 537 18684 -591 -4862 2071 1641 34 3593 1347 -1677 3356 227 2497 -5158 -1986 3543 -4218 -6049 8312 -8117 -1817 -3487 4978 5273 -2911 922 7804 -2492 5645 -8478 -1186 1472 2169 -1618 128 4255 4886 1939 384 -3023 4818 -7681 -813 559 -6613 -5283 -681 -1138 -10263 2632 248 8216 6022 1233 148 5438 -640 -6338 SS 20250528T120005.2Z 9279.500060 79 1 43.01 2 71.97 74.23 87.20 60.15 0.00 1 0.00 1 0 17 3.247e-02 6.399e-03 2.849e-03 5.598e-04 3.994889e-01 2.849448e-04 4.220924e-03 -6.000000e+00 1.868284e-02 230.24 -2.00 3.16 -2.00 318.06 0.00e+00 7.969992e-04 5.190602e-05 2.640221e-04 -6.000000e+00 8.534782e-04 292.75 -2.00 20.00 -2.00 317.13 0.00e+00 3.187 0.000 302.00 328.00 3 1.3453e+00 7.7081e-04 3.6759e-02 -6.0000e+00 4.6526e-02 -8.4734e-03 8.7673e-04 1.8734e-02 -6.0000e+00 5.0379e-02 -1.2339e-02 5.5122e-04 9.0317e-03 -6.0000e+00 3.0138e-02 9.0919e-04 2.8256e-04 2.4988e-03 -6.0000e+00 1.2808e-02 3.6708e-03 -1.9501e-04 1.5734e-05 2.7196e-05 -6.0000e+00 8.7741e-04 1.5557e-02 2.1200e-05 12 1 1 12 1 1 99.96 26.65 0.43 0.01556 0.01409 355 46 1 5 0 120.790 35.00 20.00 26.65 32.41 6.0 962.60 -8003 -7331 -9207 -9421 -13302 -13887 -13353 -10135 -9185 -9405 -8948 -9901 -6379 -3689 -1443 -757 -294 -359 768 638 565 -747 670 413 384 -8 -73 -1377 -1277 -1145 776 1057 1396 -642 -2195 -2527 -2255 -734 180 465 -81 269 406 461 449 647 161 -48 -226 281 647 980 1270 1178 964 1162 972 464 -112 483 662 1504 2088 2017 626 134 -339 -749 356 747 712 571 188 218 -182 -680 -1223 -1598 -1415 -1293 -1320 -1739 -2131 -1663 -1160 -618 -154 215 604 724 566 311 -125 -86 -16 159 588 613 83 -229 -470 -944 -566 -184 -839 -881 -706 -454 197 516 533 411 274 33 -111 132 175 323 311 86 -24 356 509 438 501 142 282 726 348 236 -116 -196 -294 15 -32 -40 298 253 15 -203 -357 -442 -596 -438 -452 -609 -599 -793 -804 -825 -690 -701 -772 -742 -879 -641 -394 -179 -107 -44 -58 131 114 104 -139 127 77 77 -2 -16 -285 -251 -229 168 257 378 -172 -567 -698 -629 -238 65 186 -36 127 187 216 211 307 76 -23 -108 138 342 531 737 691 593 735 632 303 -72 306 433 1003 1532 1530 489 99 -240 -530 270 614 615 516 170 188 -153 -542 -898 -1148 -1092 -1091 -1215 -1648 -2186 -1719 -1230 -699 -176 253 707 814 614 324 -127 -87 -17 180 696 785 111 -301 -601 -1146 -666 -223 -1067 -1145 -930 -610 281 748 804 636 414 49 -157 182 242 468 466 132 -37 540 750 639 719 195 385 1011 497 357 -182 -311 -482 26 -55 -71 539 467 27 -365 -632 -771 -1019 SS 20250528T131518.5Z 9279.552298 127 1 54.42 2 55.45 80.62 72.66 66.58 0.00 1 0.00 1 0 17 8.949e-03 6.263e-03 1.020e-03 5.604e-04 2.280278e-01 2.875141e-04 2.459918e-03 -6.000000e+00 5.151850e-03 230.24 -2.00 3.16 -2.00 315.85 0.00e+00 4.231755e-04 3.030322e-05 4.869697e-05 -6.000000e+00 2.352215e-04 292.75 -2.00 20.00 -2.00 315.03 0.00e+00 1.758 0.000 302.00 328.00 3 3.1531e+00 7.4678e-04 2.0458e-02 -6.0000e+00 1.2830e-02 1.3010e-02 8.3371e-04 1.0642e-02 -6.0000e+00 1.3891e-02 1.8513e-03 4.7711e-04 5.1452e-03 -6.0000e+00 8.3098e-03 -6.2432e-03 2.1734e-04 1.4272e-03 -6.0000e+00 3.5327e-03 3.0284e-03 2.5393e-04 1.5890e-05 1.7188e-05 -6.0000e+00 2.4181e-04 1.4405e-02 8.1572e-05 10 0 0 10 0 0 99.99 26.64 0.46 0.01440 0.01631 482 49 1 5 0 112.890 35.00 20.00 26.64 34.32 6.2 980.57 174 95 -739 -2018 -3469 -2589 -1645 -457 168 -905 -2076 -1671 -935 -615 439 154 41 489 922 977 760 339 1026 926 727 932 501 -320 -69 748 839 1627 1442 -661 -2371 -2263 -2357 -1184 -343 -398 -885 -408 -407 -134 -11 -221 -311 -313 -451 55 522 736 981 850 733 943 794 420 -104 517 754 1437 1680 1459 291 -149 -730 -784 350 656 555 380 446 411 27 -469 -971 -1319 -986 -1010 -1214 -1519 -2059 -1567 -1032 -644 -180 154 538 544 464 268 -66 58 189 297 583 735 168 -120 -329 -877 -522 -125 -766 -822 -621 -504 119 579 543 469 277 75 -162 74 55 216 248 132 -84 239 328 318 509 270 231 745 380 234 -13 -193 -283 -3 94 -2 266 307 -59 -131 -392 -612 -571 40 22 -177 -459 -771 -539 -357 -110 41 -235 -536 -434 -267 -200 148 57 16 193 376 411 304 145 411 391 323 429 231 -139 -30 314 369 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