File name: Pandora34s1_MountainViewCA_20241225_L2Fit_fwvt1c3d20230605p1-8.txt File generation date: 20241226T082008.8Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 34 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora34_OF_v3d20191105.txt Instrument calibration file used: Pandora34s1_CF_v3d20230605.txt Level 1 file used: Pandora34s1_MountainViewCA_20241225_L1_smca1c3d20230605p1-8.txt Full location name: Ames Research Center Short location name: MountainViewCA Country of location: United States Location latitude [deg]: 37.4200 Location longitude [deg]: -122.0568 Location altitude [m]: 50 Local noon date: 20241225 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: based on session 2 for P from 20230605 First and last pixel inside fitting window: 1682 1832 Nominal wavelengths inside fitting window [nm]: 492.1126 492.2328 492.3531 492.4734 492.5936 492.7139 492.8341 492.9543 493.0744 493.1946 493.3147 493.4349 493.5550 493.6751 493.7952 493.9152 494.0353 494.1553 494.2753 494.3953 494.5153 494.6353 494.7552 494.8751 494.9951 495.1150 495.2348 495.3547 495.4746 495.5944 495.7142 495.8340 495.9538 496.0736 496.1933 496.3131 496.4328 496.5525 496.6722 496.7918 496.9115 497.0311 497.1508 497.2704 497.3900 497.5095 497.6291 497.7486 497.8681 497.9876 498.1071 498.2266 498.3461 498.4655 498.5849 498.7043 498.8237 498.9431 499.0625 499.1818 499.3011 499.4204 499.5397 499.6590 499.7783 499.8975 500.0167 500.1359 500.2551 500.3743 500.4935 500.6126 500.7318 500.8509 500.9700 501.0890 501.2081 501.3271 501.4462 501.5652 501.6842 501.8032 501.9221 502.0411 502.1600 502.2789 502.3978 502.5167 502.6356 502.7544 502.8732 502.9921 503.1109 503.2296 503.3484 503.4672 503.5859 503.7046 503.8233 503.9420 504.0607 504.1793 504.2979 504.4166 504.5352 504.6537 504.7723 504.8909 505.0094 505.1279 505.2464 505.3649 505.4834 505.6018 505.7203 505.8387 505.9571 506.0755 506.1938 506.3122 506.4305 506.5488 506.6672 506.7854 506.9037 507.0220 507.1402 507.2584 507.3766 507.4948 507.6130 507.7311 507.8493 507.9674 508.0855 508.2036 508.3217 508.4397 508.5578 508.6758 508.7938 508.9118 509.0298 509.1477 509.2656 509.3836 509.5015 509.6194 509.7372 509.8551 509.9729 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-251: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 252-402: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20241225T152906.1Z 9125.645210 176 1 17.25 2 89.44 120.46 53.62 173.17 0.00 1 0.00 1 0 22 6.371e-03 6.293e-03 1.227e-03 1.223e-03 2.171113e+04 8.985540e+01 1.422900e+03 -6.000000e+00 3.481923e+02 279.26 -2.00 20.00 -2.00 505.43 0.00e+00 5.955605e-03 3.374590e-05 3.442934e-04 -6.000000e+00 1.767681e-04 279.26 -2.00 20.00 -2.00 500.98 0.00e+00 1.077780e+00 2.369963e-02 1.478662e-01 -6.000000e+00 1.255583e-01 223.66 -2.00 3.44 -2.00 502.48 0.00e+00 19.701 0.129 489.00 513.00 1 4.4880e+00 1.8120e-03 3.6747e-02 -6.0000e+00 9.6180e-03 -2.8833e-02 4.5138e-04 4.0014e-03 -6.0000e+00 2.4967e-03 1.1050e-03 1.9245e-03 1.0688e-04 2.0620e-04 -6.0000e+00 6.4866e-04 5.1280e-02 -5.2136e-04 12 9 9 12 1 1 84.20 21.40 3.26 0.05128 0.06463 8 5 1 4 0 1914.990 24.96 19.99 21.40 999.00 -9.0 -9.00 -811 -64 -227 537 1253 1550 1529 1145 1225 804 229 2 9 -496 -502 -276 -2 85 312 391 421 228 307 389 362 769 262 -264 -81 -843 -1114 -715 -479 -188 -69 182 163 -62 11 -464 -144 -110 331 419 653 504 477 177 -367 -643 -1053 -1328 -1051 -914 -812 -227 -71 418 412 379 606 504 578 80 32 54 162 -493 -502 -482 -551 -809 -596 -575 -274 -479 -62 -543 -931 -711 -636 -910 -566 -529 -852 -786 -630 -382 -424 -112 -333 265 44 412 553 579 200 -505 -815 -1372 -1308 -1146 -1097 -874 -382 -218 -141 -287 88 -602 -297 48 619 638 1191 1459 1161 1088 971 573 404 434 150 567 451 991 680 787 1036 44 413 474 28 -510 -47 -166 -553 527 380 367 310 355 153 396 253 258 -89 -217 -586 -834 -917 -728 -57 -210 501 1195 1476 1480 1097 1191 776 219 2 8 -462 -466 -258 -1 81 303 383 415 221 299 382 359 763 260 -261 -78 -813 -1063 -685 -461 -184 -69 183 163 -62 11 -460 -143 -109 332 428 661 514 486 179 -375 -645 -1035 -1308 -1026 -902 -808 -227 -72 425 421 388 622 521 601 84 33 55 164 -496 -509 -484 -549 -810 -601 -576 -276 -482 -62 -539 -916 -693 -619 -891 -557 -525 -858 -784 -627 -377 -422 -111 -331 261 44 407 543 559 189 -466 -751 -1252 -1188 -1057 -1032 -834 -374 -220 -141 -286 87 -604 -302 48 629 651 1214 1495 1191 1139 1012 598 422 444 154 578 465 1007 699 812 1070 46 428 486 28 -517 -48 -171 -574 553 399 392 331 383 167 433 277 281 -97 -231 -619 -894 -974 SQ 20241225T153215.0Z 9125.647396 180 1 50.18 2 88.90 120.94 53.56 174.10 0.00 1 0.00 1 0 29 5.076e-03 5.019e-03 6.267e-04 6.251e-04 1.997105e+04 4.556640e+01 1.313867e+03 -6.000000e+00 2.774534e+02 279.26 -2.00 20.00 -2.00 505.41 0.00e+00 4.403854e-03 1.724911e-05 2.590820e-04 -6.000000e+00 1.408540e-04 279.26 -2.00 20.00 -2.00 500.90 0.00e+00 1.117007e+00 1.213386e-02 1.333937e-01 -6.000000e+00 1.000480e-01 223.66 -2.00 3.44 -2.00 502.42 0.00e+00 18.500 0.107 489.00 513.00 1 4.5334e+00 9.2817e-04 3.3059e-02 -6.0000e+00 7.6641e-03 -2.0912e-02 2.3160e-04 3.6565e-03 -6.0000e+00 1.9891e-03 1.2786e-03 2.5451e-03 5.5233e-05 1.7674e-04 -6.0000e+00 5.1699e-04 -1.2027e-02 -1.3378e-04 12 8 8 10 0 0 91.50 21.41 2.39 -0.01203 0.00563 30 6 1 4 0 1672.280 24.96 20.00 21.41 999.00 -9.0 -9.00 -767 -377 -44 556 1105 1115 1168 1116 805 843 109 53 -155 -178 -249 -217 14 -2 306 316 352 319 343 268 308 495 68 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-702 -809 -798 -429 -211 -184 -45 139 -309 -280 208 442 574 1072 1218 1044 810 759 518 303 498 473 358 430 832 366 621 710 111 48 208 23 -294 15 -223 -335 308 362 306 266 283 346 432 307 100 -112 -241 -596 -747 -634 SQ 20241225T160538.1Z 9125.670580 206 1 13.67 2 83.38 126.26 53.56 183.92 0.00 1 0.00 1 0 15 2.718e-03 2.712e-03 5.386e-04 5.380e-04 7.170309e+03 3.470579e+01 4.912701e+02 -6.000000e+00 1.485523e+02 279.26 -2.00 20.00 -2.00 505.30 0.00e+00 1.346283e-03 1.469731e-05 8.524366e-05 -6.000000e+00 7.540173e-05 279.26 -2.00 20.00 -2.00 500.57 0.00e+00 6.310561e-01 1.054560e-02 5.349642e-02 -6.000000e+00 5.351913e-02 223.66 -2.00 3.44 -2.00 502.15 0.00e+00 7.894 0.008 489.00 513.00 1 4.5289e+00 8.0743e-04 1.2345e-02 -6.0000e+00 4.1004e-03 2.5041e-03 2.0600e-04 1.4030e-03 -6.0000e+00 1.0630e-03 6.3874e-03 9.5389e-04 5.1804e-05 6.7490e-05 -6.0000e+00 2.7661e-04 -9.6073e-03 -8.1462e-05 12 1 1 12 1 1 -23.89 21.42 1.43 -0.00961 -0.00299 24 18 1 4 0 546.250 24.96 20.00 21.42 999.00 -9.0 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