File name: Pandora197s1_Nagoya_20240308_L2Fit_fout2c43d20230601p1-8.txt File generation date: 20240308T151121.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c43p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 197 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora197_OF_v3d20210224.txt Instrument calibration file used: Pandora197s1_CF_v43d20230601.txt Level 1 file used: Pandora197s1_Nagoya_20240308_L1_smca1c43d20230601p1-8.txt Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20240308 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: VP4_July 2023 First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0252 305.1664 305.3077 305.4489 305.5901 305.7314 305.8726 306.0137 306.1549 306.2961 306.4372 306.5784 306.7195 306.8606 307.0017 307.1428 307.2839 307.4250 307.5661 307.7071 307.8482 307.9892 308.1302 308.2712 308.4122 308.5532 308.6942 308.8351 308.9761 309.1170 309.2579 309.3989 309.5398 309.6807 309.8215 309.9624 310.1033 310.2441 310.3850 310.5258 310.6666 310.8074 310.9482 311.0890 311.2297 311.3705 311.5112 311.6520 311.7927 311.9334 312.0741 312.2148 312.3555 312.4961 312.6368 312.7774 312.9180 313.0587 313.1993 313.3399 313.4804 313.6210 313.7616 313.9021 314.0427 314.1832 314.3237 314.4642 314.6047 314.7452 314.8857 315.0261 315.1666 315.3070 315.4474 315.5878 315.7282 315.8686 316.0090 316.1493 316.2897 316.4300 316.5704 316.7107 316.8510 316.9913 317.1316 317.2719 317.4121 317.5524 317.6926 317.8328 317.9730 318.1132 318.2534 318.3936 318.5338 318.6739 318.8141 318.9542 319.0943 319.2344 319.3745 319.5146 319.6547 319.7948 319.9348 320.0749 320.2149 320.3549 320.4949 320.6349 320.7749 320.9149 321.0548 321.1948 321.3347 321.4746 321.6145 321.7544 321.8943 322.0342 322.1741 322.3139 322.4538 322.5936 322.7334 322.8732 323.0130 323.1528 323.2926 323.4323 323.5721 323.7118 323.8516 323.9913 324.1310 324.2707 324.4103 324.5500 324.6897 324.8293 324.9689 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240307T220327.9Z 8832.919073 82 1 49.09 2 80.53 102.79 70.61 137.29 0.00 1 0.00 1 0 41 1.616e-01 4.048e-02 9.354e-02 8.599e-03 4.656534e-01 4.427267e-03 1.154336e-02 -6.000000e+00 9.063951e-02 226.41 -2.00 3.39 -2.00 321.70 0.00e+00 9.186459e-03 2.054098e-03 2.065278e-02 -6.000000e+00 3.991895e-03 280.57 -2.00 20.00 -2.00 321.11 0.00e+00 5.791 0.003 302.00 328.00 3 2.2012e+00 1.5488e-02 1.1936e-01 -6.0000e+00 2.2470e-01 1.4268e-01 1.8830e-02 1.2922e-01 -6.0000e+00 2.4471e-01 -8.7741e-01 1.3671e-02 4.7784e-02 -6.0000e+00 1.4577e-01 4.0786e-01 6.7473e-03 5.0163e-03 -6.0000e+00 6.1693e-02 1.7230e-04 3.8867e-03 2.7299e-04 3.5756e-04 -6.0000e+00 4.2225e-03 3.3649e-03 0.0000e+00 12 8 8 10 0 0 62.27 16.15 1.16 0.00336 0.03257 52 11 1 5 0 943.900 20.96 14.99 16.15 10.84 8.0 989.76 -18922 18976 16572 11605 9035 -40147 -44676 -65364 -52282 -59937 -13559 -42726 -11714 -20477 -17316 27657 -5076 19837 5529 19227 479 8815 -1124 -5149 20629 -21727 1554 -20797 -23066 -24370 6017 20911 -12811 21111 -26037 -135 -5854 2431 9676 19060 26204 18117 32224 17755 26094 11076 16644 8866 16545 9809 18066 20285 16696 25567 17185 15767 9295 15030 4603 -287 5500 10460 17580 12444 10082 6402 -5422 -2434 1911 6339 5816 7302 4953 -3235 -6625 -15508 -20370 -24326 -17138 -14776 -4446 -3574 -1123 -996 2188 3939 4438 9878 4776 3605 -1007 -7387 -13168 -13670 -9976 -5744 -169 1855 2712 -3177 -4767 -8713 -8984 -3728 -1411 1987 2568 5258 6745 9967 9507 7505 3832 -1022 -5109 -6920 -5197 -2408 403 2930 3630 4948 4315 965 -1585 -4523 -7182 -4616 -2267 -966 -669 -1797 -2250 -952 495 796 2310 3526 2227 527 -1247 -1896 -1610 -912 676 602 434 289 -1867 -2112 -3887 -2790 -3381 -455 -1987 -473 -1093 -1056 1202 -321 1013 333 1011 30 470 -64 -306 944 -1507 83 -1300 -1407 -1561 321 1084 -1025 1223 -2203 -8 -415 182 789 1613 2217 1726 2751 1773 2648 1319 1870 1078 1873 1226 2242 2671 2422 3581 2680 2525 1598 2395 791 -52 982 1965 3450 2818 2367 1471 -1346 -594 494 1797 1805 2309 1578 -1061 -2061 -4747 -6115 -7691 -5677 -5638 -1767 -1586 -525 -493 1134 2160 2568 5599 2860 2104 -574 -4181 -7542 -8162 -6467 -4128 -132 1626 2522 -3088 -4397 -7636 -7556 -3154 -1279 1853 2541 5454 7574 12053 12564 10441 5431 -1445 -7095 -9540 -7282 -3512 620 4617 5702 7511 6455 1447 -2359 -6687 -10691 -7161 -3865 -1798 -1336 -3799 -5005 -2229 1228 2063 6057 9344 5956 1382 -3173 -4648 -3928 SS 20240307T221244.3Z 8832.925513 87 1 49.37 2 78.69 104.20 69.37 139.07 0.00 1 0.00 1 0 41 1.787e-01 4.185e-02 4.395e-02 3.577e-03 4.324044e-01 1.803960e-03 1.255745e-02 -6.000000e+00 1.002178e-01 226.41 -2.00 3.39 -2.00 321.30 0.00e+00 1.066127e-02 8.094277e-04 2.035414e-02 -6.000000e+00 4.414480e-03 280.57 -2.00 20.00 -2.00 320.71 0.00e+00 4.926 0.002 302.00 328.00 3 1.8465e+00 6.0850e-03 1.1055e-01 -6.0000e+00 2.4845e-01 -5.7061e-02 7.5208e-03 1.2347e-01 -6.0000e+00 2.7059e-01 -5.6354e-01 6.0283e-03 4.7754e-02 -6.0000e+00 1.6119e-01 2.7972e-01 2.9557e-03 5.9614e-03 -6.0000e+00 6.8198e-02 5.6002e-04 3.5785e-03 1.0940e-04 3.9112e-04 -6.0000e+00 4.6698e-03 5.2377e-03 0.0000e+00 12 8 8 10 0 0 18.94 16.15 1.18 0.00524 0.03213 111 24 1 5 0 444.650 20.96 15.00 16.15 11.75 8.1 993.82 -25515 4995 -27780 -24962 -44296 -69750 -55589 -64107 -38067 -58068 -44449 -64889 -54814 -32850 -7600 4603 -7511 15715 8946 23271 10124 -3630 793 -17877 -5955 -11971 -1775 -21432 -14486 -28511 -16900 3291 -6770 4149 -14351 -4478 -9926 6480 12005 16049 20095 10500 21163 18373 25184 17898 15651 14089 11472 11981 10301 14220 12777 15780 11618 12306 7288 3038 804 189 5251 7812 15545 15057 10911 3883 -199 -5900 -3367 5469 5803 6842 3932 186 -5729 -14236 -20512 -23157 -16830 -12209 -5150 -3144 -3252 -2231 1053 3953 4819 7287 6537 4607 -643 -5416 -12613 -13182 -8814 -5961 -863 2334 2745 -994 -5026 -7799 -8526 -3638 -1612 2172 2869 4880 7657 9036 9194 7352 3757 -1256 -4886 -6423 -4257 -2127 1193 2557 3229 3929 3648 883 -2081 -4904 -6790 -4691 -2796 -1489 -1403 -2216 -2149 -785 717 1532 2526 3185 2409 1040 -883 -1860 -1913 -801 128 -1013 -815 -1503 -2765 -1886 -2460 -1171 -2173 -1396 -2634 -2434 -1448 -313 191 -376 658 417 959 472 -185 38 -1038 -308 -661 -87 -1223 -749 -1781 -1072 194 -492 305 -1172 -320 -810 518 1072 1579 2054 1238 2340 2141 2785 2173 1955 1799 1517 1630 1542 2227 2166 2747 2164 2310 1452 623 165 39 1099 1769 3660 3908 2992 1077 -55 -1745 -1073 1832 2113 2556 1494 70 -2101 -5125 -7335 -8571 -6558 -5345 -2422 -1628 -1815 -1306 645 2535 3250 4962 4504 3118 -427 -3503 -8320 -9009 -6460 -4891 -774 2304 2881 -1065 -5232 -7623 -8037 -3460 -1645 2267 3166 5660 9437 12143 13342 11153 5772 -1918 -7266 -9424 -6305 -3295 1935 3916 5430 6425 5849 1407 -3295 -7687 -10592 -7619 -4984 -2884 -2643 -4387 -4435 -1700 1640 3640 6106 7824 5947 2510 -2076 -4233 -4345 SS 20240307T221903.4Z 8832.929900 90 1 49.20 2 77.44 105.18 68.54 140.32 0.00 1 0.00 1 0 57 1.839e-01 4.128e-02 2.900e-02 2.396e-03 4.108923e-01 1.210693e-03 1.190863e-02 -6.000000e+00 1.031009e-01 226.41 -2.00 3.39 -2.00 321.09 0.00e+00 1.040083e-02 5.110889e-04 1.700912e-02 -6.000000e+00 4.541666e-03 280.57 -2.00 20.00 -2.00 320.47 0.00e+00 4.471 0.001 302.00 328.00 3 1.7032e+00 3.9161e-03 9.0784e-02 -6.0000e+00 2.5559e-01 -1.3400e-01 4.8309e-03 9.9087e-02 -6.0000e+00 2.7838e-01 -4.2898e-01 3.9373e-03 4.0627e-02 -6.0000e+00 1.6583e-01 2.2507e-01 1.9512e-03 6.4824e-03 -6.0000e+00 7.0156e-02 9.9760e-04 2.9909e-03 7.3944e-05 2.7546e-04 -6.0000e+00 4.8044e-03 5.7101e-03 0.0000e+00 12 8 8 10 0 0 38.23 16.15 1.12 0.00571 0.02819 159 34 1 5 0 309.390 20.96 15.00 16.15 12.44 8.1 996.43 -32798 -24862 -28229 -29143 -48401 -59555 -63948 -61658 -56624 -57171 -65705 -68187 -50231 -34808 -7125 -310 10916 4843 8544 10406 4717 -25 -3179 -4118 -2716 -5996 -12440 -19942 -20237 -22992 -11843 -7225 5033 -1381 -2852 -12533 -10336 2591 9632 19183 17560 17742 18817 20100 18094 17367 14669 13124 8947 6366 11067 11783 14864 12421 11087 9656 5172 2510 -441 204 2186 9534 11910 13513 9780 2811 -3290 -5830 -1428 2422 4369 4320 3015 -539 -6404 -12063 -18843 -19985 -16088 -11132 -6415 -4225 -3553 -1994 897 3568 5954 6622 6908 3904 -129 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