File name: Pandora197s1_Nagoya_20240312_L2Fit_fout2c43d20230601p1-8.txt File generation date: 20240312T150645.3Z Data description: Level 2 spectral fitting results file Data file version: fout2c43p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 197 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora197_OF_v3d20210224.txt Instrument calibration file used: Pandora197s1_CF_v43d20230601.txt Level 1 file used: Pandora197s1_Nagoya_20240312_L1_smca1c43d20230601p1-8.txt Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20240312 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: VP4_July 2023 First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0252 305.1664 305.3077 305.4489 305.5901 305.7314 305.8726 306.0137 306.1549 306.2961 306.4372 306.5784 306.7195 306.8606 307.0017 307.1428 307.2839 307.4250 307.5661 307.7071 307.8482 307.9892 308.1302 308.2712 308.4122 308.5532 308.6942 308.8351 308.9761 309.1170 309.2579 309.3989 309.5398 309.6807 309.8215 309.9624 310.1033 310.2441 310.3850 310.5258 310.6666 310.8074 310.9482 311.0890 311.2297 311.3705 311.5112 311.6520 311.7927 311.9334 312.0741 312.2148 312.3555 312.4961 312.6368 312.7774 312.9180 313.0587 313.1993 313.3399 313.4804 313.6210 313.7616 313.9021 314.0427 314.1832 314.3237 314.4642 314.6047 314.7452 314.8857 315.0261 315.1666 315.3070 315.4474 315.5878 315.7282 315.8686 316.0090 316.1493 316.2897 316.4300 316.5704 316.7107 316.8510 316.9913 317.1316 317.2719 317.4121 317.5524 317.6926 317.8328 317.9730 318.1132 318.2534 318.3936 318.5338 318.6739 318.8141 318.9542 319.0943 319.2344 319.3745 319.5146 319.6547 319.7948 319.9348 320.0749 320.2149 320.3549 320.4949 320.6349 320.7749 320.9149 321.0548 321.1948 321.3347 321.4746 321.6145 321.7544 321.8943 322.0342 322.1741 322.3139 322.4538 322.5936 322.7334 322.8732 323.0130 323.1528 323.2926 323.4323 323.5721 323.7118 323.8516 323.9913 324.1310 324.2707 324.4103 324.5500 324.6897 324.8293 324.9689 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240312T073549.4Z 8837.316544 353 1 49.40 2 74.45 254.68 48.83 246.16 0.00 1 0.00 1 0 33 2.249e-01 4.170e-02 1.438e-01 8.331e-03 3.728520e-01 4.217020e-03 1.094241e-02 -6.000000e+00 1.262979e-01 226.65 -2.00 3.39 -2.00 320.89 0.00e+00 1.027304e-02 1.688576e-03 1.530587e-02 -6.000000e+00 5.561109e-03 280.78 -2.00 20.00 -2.00 320.25 0.00e+00 3.663 0.001 302.00 328.00 3 4.1477e+00 1.3447e-02 7.9405e-02 -6.0000e+00 3.1326e-01 -2.0850e-01 1.6520e-02 8.7786e-02 -6.0000e+00 3.4104e-01 -2.2802e-01 1.3638e-02 3.6601e-02 -6.0000e+00 2.0314e-01 1.3663e-01 6.7802e-03 6.3303e-03 -6.0000e+00 8.5979e-02 1.8334e-04 3.1013e-03 2.5900e-04 2.7420e-04 -6.0000e+00 5.8764e-03 8.1434e-04 0.0000e+00 12 8 8 10 0 0 99.92 16.13 1.35 0.00081 0.02412 46 10 1 5 0 1073.740 20.87 15.00 16.13 13.61 8.2 1000.41 81052 -59532 1682 -51891 -77080 -85268 -95580 13708 -60416 -10141 -91761 -57879 -20716 11555 -21747 18481 47465 -3010 67352 18896 21858 -14398 -10157 -7129 -23 1892 -14566 8732 -33911 -2431 -3951 6609 13304 1246 3025 -21909 11331 -4447 15338 6765 14272 15935 12778 12746 2369 23540 10574 19271 6244 5376 4593 7468 16062 9790 14864 88 4899 -3187 1084 260 3366 8505 10202 19676 3779 5001 -4996 -8477 -1669 1258 8092 3304 6816 175 -3770 -11900 -16387 -19333 -17748 -7896 -5671 -2619 -2873 -3035 -1795 3278 6204 6606 9494 2069 39 -7398 -9363 -11663 -8788 -4358 -2178 3005 1095 1034 -3338 -7319 -7728 -4298 -1026 89 3646 5522 7504 7304 8663 6658 3853 -196 -4544 -4773 -5328 -1299 -144 2643 3859 3442 2927 44 -849 -5366 -6176 -5875 -3346 -1722 -1649 -2221 -2951 -598 257 2161 2459 3319 1818 1088 -45 -1902 -1926 658 -2242 36 -1801 -3017 -3338 -4165 213 -2097 -217 -4337 -2052 -612 307 -980 642 1332 -149 1741 823 936 -861 -578 -400 -1 101 -914 419 -2429 -133 -248 425 894 98 219 -1974 795 -424 1427 794 1697 1965 1708 1760 371 3366 1735 2912 1081 965 896 1541 3249 2235 3321 23 1246 -872 280 68 908 2411 3183 6106 1394 1710 -1790 -3140 -632 532 3497 1559 3084 81 -1682 -5192 -6909 -8324 -8291 -3900 -3142 -1575 -1860 -2078 -1311 2453 4783 5254 7374 1669 30 -5620 -6792 -8755 -7075 -3827 -2136 3159 1251 1162 -3658 -7629 -7716 -4372 -1104 100 4203 6648 9566 10200 12802 10240 5913 -293 -6629 -6720 -7717 -1921 -228 4299 6257 5494 4583 68 -1276 -8087 -9076 -9015 -5532 -3060 -3114 -4368 -6051 -1266 579 4988 5812 7955 4419 2577 -103 -4269 -4294 SS 20240312T074246.5Z 8837.321371 356 1 47.58 2 75.82 255.78 50.08 247.63 0.00 1 0.00 1 0 33 3.772e-01 4.677e-02 3.203e-01 1.867e-02 3.984868e-01 9.571754e-03 1.238640e-02 -6.000000e+00 2.118102e-01 226.65 -2.00 3.39 -2.00 321.04 0.00e+00 1.258259e-02 4.027631e-03 1.861703e-02 -6.000000e+00 9.902803e-03 280.78 -2.00 20.00 -2.00 320.42 0.00e+00 3.994 0.001 302.00 328.00 3 4.8488e+00 3.1294e-02 9.5941e-02 -6.0000e+00 5.2560e-01 -7.9222e-02 3.8050e-02 1.0463e-01 -6.0000e+00 5.7236e-01 -3.5442e-01 3.0753e-02 3.6998e-02 -6.0000e+00 3.4091e-01 1.8774e-01 1.5352e-02 4.0718e-03 -6.0000e+00 1.4522e-01 6.1808e-05 1.5963e-03 5.7857e-04 3.6548e-04 -6.0000e+00 9.9455e-03 1.0903e-03 0.0000e+00 12 8 8 10 0 0 99.54 16.13 1.24 0.00109 0.01309 13 3 1 5 0 3659.340 20.87 15.00 16.13 13.72 8.2 1000.92 163159 19761 900000 -79999 -16632 -67481 -142274 37223 -36483 30765 900000 -9263 -43494 -4220 203263 -5196 79675 -4373 133395 24778 6324 73449 118 -4517 31687 22086 -31566 147763 100192 28763 -7856 34034 396 -48131 20122 -14848 26576 -7689 39662 26738 43970 9867 4456 30370 2478 17824 28317 33992 8679 10053 17109 19569 23431 11521 20532 2644 22492 316 -4866 4121 -6927 14809 15284 12470 12436 20292 -917 -10992 855 -1908 6760 539 5951 1705 -4948 -11369 -20097 -26535 -22137 -11029 -5389 -3326 -6412 -3746 659 4394 5109 3550 7319 -1229 3923 -3247 -11602 -10517 -11719 -4090 -920 698 3945 3821 -3340 -4163 -9164 -3669 -1537 -425 2679 5272 6977 6630 10391 8169 1669 -3189 -4121 -5789 -5329 -42 2469 2819 3721 4863 2427 2170 -847 -4373 -6039 -6204 -3740 -3511 -3043 -2313 -3052 -846 954 2125 2967 3554 2255 865 -1541 -1043 -1828 2970 392 900000 -4303 -413 -2513 -10949 678 -1057 560 900000 -207 -1656 -136 3701 -252 1796 -243 2429 1117 345 1974 6 -258 1264 977 -2381 2690 1911 1172 -524 1711 31 -6468 1273 -1274 1693 -753 2997 2653 4002 1329 665 3622 399 2531 3660 4177 1383 1620 2757 3349 4116 2412 4037 628 4422 77 -1223 953 -1885 3586 4132 3814 3894 5541 -293 -3862 290 -763 2720 240 2497 714 -2049 -4522 -8049 -11207 -9834 -5130 -2728 -1850 -3963 -2377 431 3137 3843 2813 5624 -995 2808 -2302 -8371 -7558 -9399 -3476 -867 735 4317 4141 -3638 -4168 -9114 -3607 -1617 -470 3036 6208 8731 9136 14875 12281 2612 -4938 -6001 -8232 -7690 -62 3778 4552 6011 7610 3795 3281 -1267 -6502 -8813 -9464 -6164 -6338 -5844 -4581 -6303 -1804 2140 4939 7017 8545 5496 2068 -3608 -2325 -4056 SS 20240312T081638.6Z 8837.344891 364 1 49.04 2 82.60 260.93 56.36 254.19 0.00 1 0.00 1 0 49 1.955e-01 4.256e-02 1.139e-01 1.142e-02 5.685199e-01 5.978385e-03 9.712398e-03 -6.000000e+00 1.097789e-01 226.65 -2.00 3.39 -2.00 322.02 0.00e+00 1.768672e-03 2.651897e-03 1.945390e-02 -6.000000e+00 4.833613e-03 280.79 -2.00 20.00 -2.00 321.43 0.00e+00 7.184 0.006 302.00 328.00 3 1.0032e+00 2.1186e-02 1.2932e-01 -6.0000e+00 2.7229e-01 5.8113e-01 2.5377e-02 1.3586e-01 -6.0000e+00 2.9643e-01 -1.3524e+00 1.6937e-02 4.6562e-02 -6.0000e+00 1.7657e-01 5.5304e-01 8.6473e-03 4.4107e-03 -6.0000e+00 7.4738e-02 1.3655e-04 6.2842e-03 3.5445e-04 2.8030e-04 -6.0000e+00 5.1074e-03 3.2953e-04 0.0000e+00 12 8 8 10 0 0 15.76 16.13 1.21 0.00033 0.04755 78 17 1 5 0 628.680 20.87 15.00 16.13 15.16 8.2 1006.83 30872 88894 20151 40380 3670 6047 -10683 -3273 24758 -39711 8777 -44432 20413 -14069 1149 46462 -11500 87961 437 73578 -19370 9870 9798 2790 24898 -18845 21327 -38840 -4733 -42805 2966 -11427 -20010 2287 -33120 5367 -29183 12629 5884 23265 17042 20404 14695 3081 43582 13008 12163 -3159 -7860 -2225 14145 20112 5692 25945 1409 19429 15850 8272 -4266 1956 6810 -3003 21434 7977 10667 -4860 1328 -668 2845 15052 -75 18217 9042 7718 -15803 -17401 -27916 -31401 -18372 -17580 493 -4062 6265 -1713 3848 5908 9906 11995 8151 8642 -6068 -8213 -14636 -13962 -10486 -6339 2067 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