File name: Pandora197s1_Nagoya_20240411_L2Fit_fout2c43d20230601p1-8.txt File generation date: 20240411T150151.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c43p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 197 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora197_OF_v3d20210224.txt Instrument calibration file used: Pandora197s1_CF_v43d20230601.txt Level 1 file used: Pandora197s1_Nagoya_20240411_L1_smca1c43d20230601p1-8.txt Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20240411 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: VP4_July 2023 First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0252 305.1664 305.3077 305.4489 305.5901 305.7314 305.8726 306.0137 306.1549 306.2961 306.4372 306.5784 306.7195 306.8606 307.0017 307.1428 307.2839 307.4250 307.5661 307.7071 307.8482 307.9892 308.1302 308.2712 308.4122 308.5532 308.6942 308.8351 308.9761 309.1170 309.2579 309.3989 309.5398 309.6807 309.8215 309.9624 310.1033 310.2441 310.3850 310.5258 310.6666 310.8074 310.9482 311.0890 311.2297 311.3705 311.5112 311.6520 311.7927 311.9334 312.0741 312.2148 312.3555 312.4961 312.6368 312.7774 312.9180 313.0587 313.1993 313.3399 313.4804 313.6210 313.7616 313.9021 314.0427 314.1832 314.3237 314.4642 314.6047 314.7452 314.8857 315.0261 315.1666 315.3070 315.4474 315.5878 315.7282 315.8686 316.0090 316.1493 316.2897 316.4300 316.5704 316.7107 316.8510 316.9913 317.1316 317.2719 317.4121 317.5524 317.6926 317.8328 317.9730 318.1132 318.2534 318.3936 318.5338 318.6739 318.8141 318.9542 319.0943 319.2344 319.3745 319.5146 319.6547 319.7948 319.9348 320.0749 320.2149 320.3549 320.4949 320.6349 320.7749 320.9149 321.0548 321.1948 321.3347 321.4746 321.6145 321.7544 321.8943 322.0342 322.1741 322.3139 322.4538 322.5936 322.7334 322.8732 323.0130 323.1528 323.2926 323.4323 323.5721 323.7118 323.8516 323.9913 324.1310 324.2707 324.4103 324.5500 324.6897 324.8293 324.9689 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240410T212516.2Z 8866.892549 60 1 49.09 2 78.66 87.68 93.91 61.80 0.00 1 0.00 1 0 49 1.688e-01 4.031e-02 8.090e-02 7.077e-03 3.964366e-01 3.629022e-03 1.099453e-02 -6.000000e+00 9.547472e-02 228.91 -2.00 3.39 -2.00 321.34 0.00e+00 1.076067e-02 1.564263e-03 1.791226e-02 -6.000000e+00 4.216386e-03 283.31 -2.00 20.00 -2.00 320.67 0.00e+00 4.912 0.002 302.00 328.00 3 2.8586e+00 1.2263e-02 1.0093e-01 -6.0000e+00 2.3785e-01 -5.2035e-02 1.4971e-02 1.1033e-01 -6.0000e+00 2.5851e-01 -5.4224e-01 1.1184e-02 4.0379e-02 -6.0000e+00 1.5393e-01 2.6529e-01 5.4969e-03 3.8227e-03 -6.0000e+00 6.4908e-02 2.1159e-04 3.7499e-03 2.2491e-04 3.0006e-04 -6.0000e+00 4.4136e-03 9.8626e-03 0.0000e+00 12 8 8 10 0 0 83.16 16.67 1.23 0.00986 0.03804 45 10 1 5 0 1090.660 21.48 15.00 16.67 18.11 10.2 1011.91 -12466 19461 -43534 -26734 -64365 -3462 -62041 -36212 -40877 -44915 -30407 -76040 -22692 -33941 10486 9511 14018 46254 3171 25858 9858 14977 -232 2301 -14465 -600 -16672 -17679 -22786 -23923 -1878 -19647 5059 1803 -6682 -9559 -13929 2627 9793 24440 7336 17952 12171 23238 14521 20606 19175 8778 12968 6537 16365 8686 16015 15504 13361 14294 4249 6876 -2343 1935 7458 10691 11697 14220 10442 2465 -2032 -7045 -4203 3934 6036 4924 3325 1227 -8059 -13169 -18531 -20471 -17533 -11167 -3839 -3604 -2366 -3334 2076 3054 5688 7445 7098 3129 -584 -5686 -13879 -12771 -9024 -4230 -1455 1805 1509 -638 -5489 -7616 -8450 -4637 -226 1518 4256 5569 7267 9235 8765 7029 2785 -1537 -4602 -5666 -4147 -2133 1297 2050 3608 3719 3920 54 -1431 -5340 -5556 -4433 -3310 -2054 -1948 -1718 -2453 -674 1266 1488 2607 2763 2213 627 -411 -2304 -1626 -430 537 -2294 -1090 -3271 -87 -2764 -1295 -1590 -1803 -1011 -4198 -883 -1810 428 442 660 1654 181 1201 532 733 -13 126 -935 -34 -1088 -1109 -1458 -1621 -115 -1627 362 136 -503 -720 -1189 219 897 2208 847 2143 1604 2806 1944 2645 2501 1272 1808 1001 2451 1523 2774 2846 2563 2752 912 1419 -521 417 1611 2479 3003 3876 2969 711 -585 -2149 -1378 1363 2228 1903 1290 463 -3075 -4771 -6599 -7473 -6957 -4871 -1786 -1870 -1301 -1963 1254 1968 3788 5040 4839 2136 -385 -3649 -9147 -8558 -6508 -3336 -1280 1739 1549 -655 -5523 -7175 -7744 -4359 -222 1560 4530 6261 8746 11988 12292 10231 4111 -2232 -6460 -7820 -5827 -3142 2004 3314 5784 5845 6014 83 -2156 -8037 -8191 -6864 -5642 -3788 -3825 -3497 -5239 -1505 2975 3650 6505 7044 5660 1575 -999 -5493 -3851 SS 20240410T213129.3Z 8866.896867 63 1 49.43 2 77.39 88.56 92.82 62.67 0.00 1 0.00 1 0 33 1.726e-01 4.250e-02 4.163e-02 3.693e-03 3.794419e-01 1.863601e-03 1.156604e-02 -6.000000e+00 9.764855e-02 228.91 -2.00 3.39 -2.00 320.99 0.00e+00 9.130088e-03 7.649952e-04 1.731023e-02 -6.000000e+00 4.311777e-03 283.32 -2.00 20.00 -2.00 320.33 0.00e+00 4.453 0.001 302.00 328.00 3 2.3834e+00 6.0676e-03 9.4644e-02 -6.0000e+00 2.4327e-01 -1.4663e-01 7.4270e-03 1.0638e-01 -6.0000e+00 2.6438e-01 -3.8089e-01 5.7630e-03 3.7866e-02 -6.0000e+00 1.5743e-01 1.9751e-01 2.8484e-03 2.9322e-03 -6.0000e+00 6.6398e-02 5.2881e-04 3.5562e-03 1.1353e-04 2.8513e-04 -6.0000e+00 4.5127e-03 8.2653e-03 0.0000e+00 12 8 8 10 0 0 38.24 16.67 1.02 0.00827 0.03499 88 19 1 5 0 561.640 21.48 15.00 16.67 18.77 10.3 1014.81 -33785 -44088 -26921 -27813 -60690 -26328 -72993 -43808 -65113 -59641 -47807 -52103 -30741 -14725 6401 -4257 9741 -7948 18135 7164 11755 6981 -2934 4820 -6884 -972 -25798 -14046 -28254 -11661 -1802 -9085 5270 -3053 -5074 -17601 -4610 -2331 12909 16249 17170 19748 13657 22163 15070 20813 11514 15929 9002 6526 13325 10612 15708 10350 8160 4907 3933 4362 -396 974 1371 8114 9707 14959 7984 2284 -3211 -7344 -75 2353 6103 4258 4138 -880 -5307 -11687 -20338 -21441 -16542 -10300 -7329 -4477 -4492 -1441 1657 4619 6694 6652 7087 3020 -531 -6722 -10742 -12555 -8922 -4732 -564 2883 1564 -809 -4851 -7067 -7254 -4108 -849 987 3875 4778 7141 8666 9362 6900 3611 -673 -4272 -5430 -4869 -1937 701 2667 3156 4027 3627 635 -1752 -5763 -6535 -5472 -2966 -2040 -1668 -2205 -2408 -609 634 2098 2588 3079 2349 1076 -374 -1934 -1755 -1139 -1833 -969 -938 -2464 -698 -3107 -1477 -2878 -2519 -1737 -2081 -1188 -593 249 -209 443 -455 837 380 596 359 -165 256 -417 -56 -1900 -878 -1970 -718 -113 -693 425 -275 -431 -1654 -415 -238 1348 1890 2146 2525 1938 2961 2198 2923 1779 2358 1433 1097 2260 2010 3015 2218 1837 1161 952 1041 -98 239 355 2174 2859 4552 2619 743 -1050 -2518 -26 928 2530 1866 1799 -385 -2238 -4739 -8350 -8895 -7268 -4967 -3933 -2610 -2811 -927 1119 3266 4917 5059 5388 2301 -390 -4851 -7605 -9251 -7046 -4097 -535 2985 1742 -904 -5268 -7194 -7129 -4161 -912 1104 4471 5832 9232 12096 13921 10710 5620 -1027 -6323 -7883 -7242 -2988 1143 4089 5341 6632 5862 1019 -2773 -9114 -10141 -8879 -5204 -3876 -3360 -4208 -4787 -1263 1392 4752 6000 7272 5579 2504 -848 -4282 -3875 SS 20240410T213651.9Z 8866.900601 66 1 49.46 2 76.29 89.33 91.87 63.41 0.00 1 0.00 1 0 41 1.650e-01 4.186e-02 3.446e-02 2.966e-03 3.569623e-01 1.484017e-03 1.044812e-02 -6.000000e+00 9.334927e-02 228.91 -2.00 3.39 -2.00 320.80 0.00e+00 8.570188e-03 5.904283e-04 1.471433e-02 -6.000000e+00 4.122071e-03 283.32 -2.00 20.00 -2.00 320.13 0.00e+00 4.120 0.001 302.00 328.00 3 2.4233e+00 4.7424e-03 8.0702e-02 -6.0000e+00 2.3256e-01 -2.1875e-01 5.8025e-03 8.8512e-02 -6.0000e+00 2.5274e-01 -2.6062e-01 4.6089e-03 3.3406e-02 -6.0000e+00 1.5050e-01 1.4622e-01 2.2962e-03 3.5240e-03 -6.0000e+00 6.3472e-02 7.1028e-04 3.2376e-03 9.0592e-05 2.4081e-04 -6.0000e+00 4.3143e-03 8.6124e-03 0.0000e+00 12 8 8 10 0 0 99.16 16.67 1.29 0.00861 0.03294 102 22 1 5 0 484.780 21.48 14.99 16.67 19.60 10.3 1018.19 -27515 -33428 -25778 -28918 -49784 -66290 -50714 -64014 -50101 -48164 -59793 -50569 -40701 -12552 -6961 7696 -4357 5550 10547 11962 13994 4016 2360 -1833 -916 -2776 -9367 -12005 -16926 -6784 -9322 1539 -4372 -1563 -12022 -15741 -15116 -3269 9513 12543 17654 13156 15931 13510 14070 17292 11463 10645 7318 6924 6148 9478 7860 8311 7112 6229 4586 325 425 -962 3142 7411 10736 10351 8462 2964 -5222 -5653 -4293 2288 2544 3134 2429 -422 -5196 -12241 -16608 -20465 -15930 -10673 -6230 -3441 -3251 -1421 1035 4442 5312 6767 6213 3717 108 -5596 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