File name: Pandora197s1_Nagoya_20240415_L2Fit_fout2c43d20230601p1-8.txt File generation date: 20240415T150008.1Z Data description: Level 2 spectral fitting results file Data file version: fout2c43p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 197 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora197_OF_v3d20210224.txt Instrument calibration file used: Pandora197s1_CF_v43d20230601.txt Level 1 file used: Pandora197s1_Nagoya_20240415_L1_smca1c43d20230601p1-8.txt Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20240415 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: VP4_July 2023 First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0252 305.1664 305.3077 305.4489 305.5901 305.7314 305.8726 306.0137 306.1549 306.2961 306.4372 306.5784 306.7195 306.8606 307.0017 307.1428 307.2839 307.4250 307.5661 307.7071 307.8482 307.9892 308.1302 308.2712 308.4122 308.5532 308.6942 308.8351 308.9761 309.1170 309.2579 309.3989 309.5398 309.6807 309.8215 309.9624 310.1033 310.2441 310.3850 310.5258 310.6666 310.8074 310.9482 311.0890 311.2297 311.3705 311.5112 311.6520 311.7927 311.9334 312.0741 312.2148 312.3555 312.4961 312.6368 312.7774 312.9180 313.0587 313.1993 313.3399 313.4804 313.6210 313.7616 313.9021 314.0427 314.1832 314.3237 314.4642 314.6047 314.7452 314.8857 315.0261 315.1666 315.3070 315.4474 315.5878 315.7282 315.8686 316.0090 316.1493 316.2897 316.4300 316.5704 316.7107 316.8510 316.9913 317.1316 317.2719 317.4121 317.5524 317.6926 317.8328 317.9730 318.1132 318.2534 318.3936 318.5338 318.6739 318.8141 318.9542 319.0943 319.2344 319.3745 319.5146 319.6547 319.7948 319.9348 320.0749 320.2149 320.3549 320.4949 320.6349 320.7749 320.9149 321.0548 321.1948 321.3347 321.4746 321.6145 321.7544 321.8943 322.0342 322.1741 322.3139 322.4538 322.5936 322.7334 322.8732 323.0130 323.1528 323.2926 323.4323 323.5721 323.7118 323.8516 323.9913 324.1310 324.2707 324.4103 324.5500 324.6897 324.8293 324.9689 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240414T212024.2Z 8870.889169 88 1 48.87 2 78.63 85.91 116.48 13.53 0.00 1 0.00 1 0 41 2.171e-01 4.286e-02 1.572e-01 1.236e-02 4.455806e-01 6.376317e-03 1.191716e-02 -6.000000e+00 1.229456e-01 229.21 -2.00 3.39 -2.00 321.50 0.00e+00 8.644243e-03 2.889610e-03 2.068045e-02 -6.000000e+00 5.431269e-03 283.67 -2.00 20.00 -2.00 320.85 0.00e+00 4.902 0.002 302.00 328.00 3 3.4894e+00 2.2017e-02 1.1626e-01 -6.0000e+00 3.0648e-01 5.2708e-02 2.7209e-02 1.3592e-01 -6.0000e+00 3.3299e-01 -7.3704e-01 1.9880e-02 5.0567e-02 -6.0000e+00 1.9828e-01 3.5088e-01 9.6222e-03 4.0406e-03 -6.0000e+00 8.3587e-02 1.0754e-04 4.3308e-03 3.8909e-04 3.2458e-04 -6.0000e+00 5.6768e-03 9.3294e-03 0.0000e+00 12 8 8 10 0 0 91.06 16.91 1.35 0.00933 0.04187 28 6 1 5 0 1744.700 21.69 15.00 16.91 22.16 10.6 1024.96 -41453 4150 9607 -1118 37909 -33736 -79895 -33846 -13360 -77644 -55859 -57444 78210 -55468 12976 12352 60011 12846 15453 14352 29213 59792 34192 -5651 22833 5700 -31466 -27547 7199 -7318 25769 920 49501 2372 -9621 -8355 -10355 12410 5421 42002 34108 48730 15764 29535 3087 10269 25519 11817 18935 6034 20715 20220 7047 2720 7565 22456 12914 16504 -56 8314 7947 7648 21658 9416 21490 -2636 8614 -6522 -165 5172 8974 4495 -3342 849 -6487 -3497 -26047 -16168 -14071 -16630 -6195 -5984 -2582 -2736 9375 521 5837 8222 4552 1568 -4279 -7364 -13248 -9683 -8407 -5185 -1746 1969 1458 -2286 -6769 -9702 -4954 -4615 1077 324 4099 5431 6980 9688 8402 8018 3495 -252 -5304 -5322 -6114 -3214 2190 1927 3715 5342 5339 -201 -1512 -6405 -7804 -3550 -2063 41 -2865 -1756 -2452 -200 422 1214 2596 2703 2840 334 -29 -2163 -2377 -2249 154 338 -39 762 -1254 -4655 -1409 -468 -5105 -2816 -3085 1286 -4194 583 623 1973 704 847 802 1377 1966 1424 -353 1076 319 -2483 -1962 347 -425 1214 63 2278 177 -738 -613 -840 925 511 3130 2953 3791 1762 2913 399 1249 2657 1412 2328 873 2797 2974 1257 534 1450 3763 2397 2905 -11 1553 1571 1678 4621 2474 5025 -737 2066 -1848 -49 1658 3007 1626 -1285 297 -2236 -1054 -9200 -5243 -5038 -7177 -2771 -2994 -1341 -1510 4961 324 3645 5174 2974 1013 -2729 -4500 -8193 -5999 -5787 -3981 -1491 1835 1450 -2312 -6667 -8994 -4222 -4178 1008 324 4210 5911 8196 12250 11627 11405 5076 -360 -7487 -7333 -8793 -4804 3359 3108 5898 8165 7981 -306 -2258 -9659 -11713 -5464 -3504 74 -5775 -3648 -5361 -455 1026 3058 6621 7036 7335 852 -71 -5174 -5702 SS 20240414T212614.6Z 8870.893224 91 1 49.78 2 77.44 86.73 116.20 14.87 0.00 1 0.00 1 0 41 1.875e-01 4.127e-02 7.827e-02 5.853e-03 4.120816e-01 2.996141e-03 1.267161e-02 -6.000000e+00 1.061942e-01 229.22 -2.00 3.39 -2.00 321.36 0.00e+00 9.975009e-03 1.369110e-03 2.150987e-02 -6.000000e+00 4.690918e-03 283.67 -2.00 20.00 -2.00 320.71 0.00e+00 4.470 0.001 302.00 328.00 3 3.0578e+00 1.0307e-02 1.1686e-01 -6.0000e+00 2.6472e-01 -1.4278e-01 1.2826e-02 1.3794e-01 -6.0000e+00 2.8761e-01 -4.5787e-01 1.0181e-02 4.9188e-02 -6.0000e+00 1.7126e-01 2.3496e-01 4.9569e-03 3.3305e-03 -6.0000e+00 7.2205e-02 2.5997e-04 3.3511e-03 1.8349e-04 3.2497e-04 -6.0000e+00 4.9026e-03 8.5128e-03 0.0000e+00 12 8 8 10 0 0 97.94 16.91 1.20 0.00851 0.03369 49 11 1 5 0 1015.700 21.69 15.00 16.91 22.50 10.6 1026.57 -24100 -22818 -20034 -39619 -44137 -37560 -68040 -59870 -57952 -38942 -88819 -58392 -30229 -37641 -4618 -14534 30511 -10964 26504 -7950 5797 5396 10320 -6794 -19423 4269 -18316 -23762 -23932 -28193 -20419 -15563 -9245 -8555 -14240 -19164 453 -853 26234 16495 24604 19968 14208 20216 15657 19669 11061 12027 6418 6540 10922 10982 16149 10405 10128 14261 7458 4163 2099 5034 5490 15597 12847 13147 10638 4726 -4812 -5254 -2535 3439 9613 3766 3593 -2155 -1497 -12083 -18707 -20914 -17705 -8402 -6568 -2026 -3459 -1631 207 3228 5190 6721 6901 3156 185 -6328 -12090 -12440 -8969 -5985 -512 3051 2165 -575 -6148 -7797 -8327 -5024 -1205 562 3676 5377 7540 8930 9142 7070 3416 -1214 -5020 -6445 -4378 -1273 964 2646 3493 4570 3915 423 -740 -5484 -6870 -5304 -3330 -1987 -1362 -1564 -2673 -663 677 1688 2867 2994 2393 894 -343 -2076 -1691 -625 -651 -572 -1275 -1283 -936 -2295 -1957 -1955 -1091 -3964 -2030 -957 -1582 -168 -664 950 -546 949 -413 262 235 423 -335 -1099 193 -1026 -1344 -1316 -1697 -1293 -1066 -662 -626 -1020 -1402 33 -72 2007 1601 2387 2131 1679 2308 1904 2346 1446 1565 890 937 1621 1774 2645 1912 1919 2637 1494 853 431 1014 1166 3321 3153 3519 2951 1308 -1401 -1550 -805 1182 3391 1462 1382 -838 -533 -4318 -6652 -7640 -7003 -3554 -3138 -1038 -1933 -949 128 2087 3492 4611 4746 2170 122 -4129 -7908 -8386 -6522 -4851 -451 2938 2240 -600 -6338 -7477 -7709 -4777 -1208 588 3964 6102 9120 11734 12921 10436 5095 -1789 -7204 -9109 -6249 -1881 1511 4297 5660 7181 6054 653 -1115 -8329 -10321 -8319 -5706 -3686 -2682 -3210 -5779 -1495 1615 4172 7201 6986 5604 2258 -839 -4964 -4020 SS 20240414T213139.6Z 8870.896986 94 1 49.31 2 76.33 87.50 115.92 16.11 0.00 1 0.00 1 0 33 1.740e-01 4.172e-02 4.406e-02 3.688e-03 3.880986e-01 1.861906e-03 1.173005e-02 -6.000000e+00 9.856024e-02 229.22 -2.00 3.39 -2.00 321.00 0.00e+00 9.044437e-03 7.790148e-04 1.764881e-02 -6.000000e+00 4.353960e-03 283.68 -2.00 20.00 -2.00 320.35 0.00e+00 4.132 0.001 302.00 328.00 3 2.7213e+00 6.0969e-03 9.4954e-02 -6.0000e+00 2.4569e-01 -1.8118e-01 7.5136e-03 1.0957e-01 -6.0000e+00 2.6694e-01 -3.7365e-01 5.9247e-03 3.9763e-02 -6.0000e+00 1.5895e-01 1.9829e-01 2.9186e-03 3.1752e-03 -6.0000e+00 6.7009e-02 5.0787e-04 3.4255e-03 1.1270e-04 2.8453e-04 -6.0000e+00 4.5507e-03 9.1702e-03 0.0000e+00 12 9 8 11 8 0 44.85 16.91 1.21 0.00917 0.03491 77 17 1 5 0 640.200 21.69 14.99 16.91 23.11 10.6 1029.02 -7566 -46442 -29178 -26401 -40604 -37450 -61797 -39711 -72152 -49656 -64739 -60992 -50456 -25546 -10577 -11235 7198 2162 12943 2666 11325 2012 5250 3288 -11941 -3671 -17850 -19875 -22575 -19330 -7649 -10049 2312 -1408 -4809 -19198 -10079 -1025 11751 20196 16248 19728 22671 22101 17379 16082 11038 11298 6700 7418 9835 7033 15056 11754 11173 7619 4313 3864 1443 2329 2575 9416 10248 14612 6835 2938 -3543 -5991 -1180 3655 4736 3934 3134 -2005 -6487 -11999 -19697 -18924 -17225 -9428 -7016 -4053 -4555 -1822 1019 3947 5990 6527 6850 3773 914 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