File name: Pandora197s1_Nagoya_20240724_L2Fit_fout2c43d20230601p1-8.txt File generation date: 20240724T150715.0Z Data description: Level 2 spectral fitting results file Data file version: fout2c43p1-8 Local principal investigator: Urumu Tsunogai Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 197 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora197_OF_v3d20210224.txt Instrument calibration file used: Pandora197s1_CF_v43d20230601.txt Level 1 file used: Pandora197s1_Nagoya_20240724_L1_smca1c43d20230601p1-8.txt Full location name: Nagoya University Short location name: Nagoya Country of location: Japan Location latitude [deg]: 35.1517 Location longitude [deg]: 136.9721 Location altitude [m]: 117 Local noon date: 20240724 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: VP4_July 2023 First and last pixel inside fitting window: 200 342 Nominal wavelengths inside fitting window [nm]: 305.0252 305.1664 305.3077 305.4489 305.5901 305.7314 305.8726 306.0137 306.1549 306.2961 306.4372 306.5784 306.7195 306.8606 307.0017 307.1428 307.2839 307.4250 307.5661 307.7071 307.8482 307.9892 308.1302 308.2712 308.4122 308.5532 308.6942 308.8351 308.9761 309.1170 309.2579 309.3989 309.5398 309.6807 309.8215 309.9624 310.1033 310.2441 310.3850 310.5258 310.6666 310.8074 310.9482 311.0890 311.2297 311.3705 311.5112 311.6520 311.7927 311.9334 312.0741 312.2148 312.3555 312.4961 312.6368 312.7774 312.9180 313.0587 313.1993 313.3399 313.4804 313.6210 313.7616 313.9021 314.0427 314.1832 314.3237 314.4642 314.6047 314.7452 314.8857 315.0261 315.1666 315.3070 315.4474 315.5878 315.7282 315.8686 316.0090 316.1493 316.2897 316.4300 316.5704 316.7107 316.8510 316.9913 317.1316 317.2719 317.4121 317.5524 317.6926 317.8328 317.9730 318.1132 318.2534 318.3936 318.5338 318.6739 318.8141 318.9542 319.0943 319.2344 319.3745 319.5146 319.6547 319.7948 319.9348 320.0749 320.2149 320.3549 320.4949 320.6349 320.7749 320.9149 321.0548 321.1948 321.3347 321.4746 321.6145 321.7544 321.8943 322.0342 322.1741 322.3139 322.4538 322.5936 322.7334 322.8732 323.0130 323.1528 323.2926 323.4323 323.5721 323.7118 323.8516 323.9913 324.1310 324.2707 324.4103 324.5500 324.6897 324.8293 324.9689 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240723T213133.0Z 8970.896910 223 1 49.24 2 72.23 77.89 77.98 244.48 0.00 1 0.00 1 0 57 8.284e-02 4.660e-02 2.291e-02 2.731e-03 2.639479e-01 1.359698e-03 7.312809e-03 -6.000000e+00 4.737317e-02 232.02 -2.00 3.39 -2.00 319.84 0.00e+00 3.404931e-03 4.036715e-04 8.388760e-03 -6.000000e+00 2.148420e-03 292.15 -2.00 20.00 -2.00 318.93 0.00e+00 3.231 0.000 302.00 328.00 3 3.1802e+00 4.0142e-03 5.0988e-02 -6.0000e+00 1.1856e-01 -2.6076e-01 4.7588e-03 5.3936e-02 -6.0000e+00 1.2838e-01 -5.2756e-02 3.3397e-03 1.5333e-02 -6.0000e+00 7.6657e-02 4.2444e-02 1.7144e-03 3.8993e-03 -6.0000e+00 3.2367e-02 8.3509e-04 4.3208e-03 8.1890e-05 5.6669e-05 -6.0000e+00 2.1688e-03 1.5870e-02 0.0000e+00 12 8 8 10 0 0 99.92 15.37 1.30 0.01587 0.04834 90 19 1 5 0 546.640 20.67 15.00 15.37 37.54 18.8 1029.10 11866 1196 -17246 -8131 -19255 -17147 -21698 -14033 -8163 -16926 -23676 -22936 -15367 -9836 1274 2063 9360 8178 7283 15674 5577 7998 -1153 10503 -1762 4424 23 -7177 -8990 -12845 -5723 -9124 -1465 -11897 -14136 -19050 -11432 -4733 4212 10779 7653 12309 9742 10537 10423 7527 6840 2354 451 -2833 1665 2233 4255 3634 2625 3804 1534 1107 -3165 -518 1074 5922 8277 9090 3821 -2280 -6570 -8271 -2900 714 3667 2721 1517 80 -4889 -10985 -17896 -18497 -15839 -9706 -6625 -3729 -2767 -896 2943 4761 7425 7139 7190 4661 562 -5291 -10230 -10309 -8000 -3364 285 3299 2579 -51 -3520 -6593 -6012 -3073 405 1713 3979 5098 6968 9003 8986 7447 3810 -346 -4367 -5738 -4874 -1685 1173 2388 3022 2810 2443 -745 -2928 -6703 -8071 -6704 -4378 -2976 -3040 -2899 -2686 -684 1511 2315 3321 3761 2957 1280 78 -1320 -1073 376 46 -823 -329 -769 -644 -904 -605 -366 -857 -1256 -1261 -904 -643 86 153 678 628 591 1218 488 674 -109 928 -184 495 3 -845 -1023 -1540 -695 -1259 -205 -1873 -2112 -2984 -1848 -847 831 2306 1830 2944 2481 2706 2707 2031 1835 650 126 -833 502 723 1435 1302 978 1435 603 435 -1283 -207 446 2570 3851 4467 1941 -1131 -3199 -4095 -1506 409 2216 1722 966 50 -2951 -6340 -10167 -10386 -9471 -6264 -4683 -2827 -2208 -743 2550 4365 7015 6973 7013 4457 517 -4722 -8916 -9070 -7522 -3388 311 3881 3188 -63 -4173 -7453 -6626 -3537 491 2164 5188 6933 9932 13520 14184 11917 6033 -529 -6443 -8296 -7189 -2570 1718 3660 4661 4703 4002 -1207 -4644 -10520 -12448 -10671 -7409 -5330 -5188 -5055 -4823 -1275 2948 4681 6842 7900 6250 2674 160 -2654 -2161 SS 20240723T213706.4Z 8970.900769 227 1 49.26 2 71.12 78.61 78.96 245.38 0.00 1 0.00 1 0 49 8.413e-02 4.619e-02 8.586e-03 1.217e-03 2.541689e-01 6.116855e-04 6.283345e-03 -6.000000e+00 4.810823e-02 232.02 -2.00 3.39 -2.00 319.52 0.00e+00 4.045635e-03 1.627266e-04 6.664524e-03 -6.000000e+00 2.181891e-03 292.15 -2.00 20.00 -2.00 318.56 0.00e+00 3.053 0.000 302.00 328.00 3 2.1181e+00 1.7720e-03 4.3079e-02 -6.0000e+00 1.2039e-01 -2.4648e-01 2.0712e-03 4.0695e-02 -6.0000e+00 1.3038e-01 -3.0873e-02 1.3785e-03 1.2755e-02 -6.0000e+00 7.7848e-02 2.7485e-02 7.0604e-04 2.2523e-03 -6.0000e+00 3.2868e-02 2.8429e-03 4.3767e-03 3.6698e-05 4.7746e-05 -6.0000e+00 2.2027e-03 1.6314e-02 0.0000e+00 12 8 8 10 0 0 99.57 15.38 1.37 0.01631 0.04920 238 52 1 5 0 206.960 20.67 15.00 15.38 38.07 18.8 1031.65 -4860 2558 -2172 -7416 -28917 -26224 -25105 -21080 -11370 -17769 -19584 -23810 -10955 -3167 3019 7197 7244 10394 7247 11761 5716 3874 2923 2880 2480 413 -690 -9136 -11345 -14251 -10061 -8692 -5592 -9184 -17657 -16206 -12874 -3164 3226 8149 8914 9861 10025 9100 9287 7867 6171 2815 -154 -1528 688 2726 3660 3974 2895 3175 891 2 -1817 -787 2387 5693 8468 8283 4396 -2317 -6687 -7852 -3449 1137 3057 3627 1806 16 -4958 -10517 -16204 -18660 -14646 -10046 -5683 -3544 -2375 -493 2822 5218 6953 7745 7189 4648 46 -5044 -9994 -10258 -7234 -3481 654 3488 3061 37 -3197 -6428 -6172 -2465 165 2079 3778 5284 6911 8915 9066 7308 3955 -567 -4116 -5550 -4211 -1882 1205 2427 3043 3070 2089 -730 -3299 -6607 -7981 -6634 -4530 -3242 -2831 -2970 -2628 -822 1372 2180 3361 3654 2860 1509 30 -1271 -1159 -207 111 -101 -339 -1451 -1228 -1230 -1105 -595 -1024 -1237 -1639 -767 -241 251 634 668 973 734 1187 623 424 330 341 308 54 -91 -1234 -1489 -1956 -1440 -1346 -918 -1583 -3072 -2774 -2373 -626 720 2000 2350 2697 2842 2648 2728 2367 1864 865 -48 -494 233 976 1378 1572 1189 1330 389 1 -801 -348 1081 2734 4338 4519 2440 -1262 -3569 -4233 -1966 707 2025 2476 1247 11 -3255 -6565 -9825 -11376 -9370 -7034 -4296 -2890 -2031 -438 2631 5114 7083 8064 7516 4761 45 -4796 -9265 -9602 -7175 -3727 755 3943 3619 44 -3625 -7656 -7195 -2978 192 2509 4728 6862 9415 12778 13608 11123 5929 -823 -5728 -7571 -5831 -2718 1835 3865 4878 4843 3244 -1116 -4953 -9762 -11582 -9929 -7212 -5459 -4967 -5334 -4850 -1576 2754 4531 7108 7233 5696 3231 64 -2626 -2403 SS 20240723T214248.4Z 8970.904726 230 1 20.52 2 69.98 79.35 79.97 246.28 0.00 1 0.00 1 0 33 7.962e-02 4.733e-02 1.190e-02 2.154e-03 2.471420e-01 1.075148e-03 5.705244e-03 -6.000000e+00 4.552685e-02 232.02 -2.00 3.39 -2.00 319.01 0.00e+00 3.903695e-03 2.481664e-04 5.085065e-03 -6.000000e+00 2.064751e-03 292.15 -2.00 20.00 -2.00 318.06 0.00e+00 2.889 0.000 302.00 328.00 3 2.8681e+00 3.0055e-03 3.6217e-02 -6.0000e+00 1.1393e-01 -2.2483e-01 3.4720e-03 2.9035e-02 -6.0000e+00 1.2338e-01 -2.2186e-02 2.2523e-03 9.6597e-03 -6.0000e+00 7.3670e-02 1.9785e-02 1.1545e-03 1.7352e-03 -6.0000e+00 3.1105e-02 1.5553e-03 3.8000e-03 6.3163e-05 2.4383e-05 -6.0000e+00 2.0844e-03 1.6076e-02 0.0000e+00 12 9 9 12 1 1 99.96 15.38 1.25 0.01608 0.04463 42 22 1 5 0 476.990 20.67 15.00 15.38 38.58 18.6 1033.20 -7519 2042 1503 -8621 -13015 -30447 -21187 -18314 -17399 -15307 -21079 -17812 -13040 -1746 2905 9055 8946 6801 6519 7957 8744 5635 5577 1866 107 1615 -2346 -6870 -13148 -11490 -10788 -5473 -5313 -9498 -15592 -18706 -12232 -5279 3440 7040 8534 8583 9868 7883 9189 8605 4574 2880 -859 241 698 2755 3101 3902 2395 2551 1385 -356 -636 -991 1928 4642 7602 8446 3840 -1098 -6656 -7180 -4008 1005 3325 3277 2547 659 -3913 -9778 -15307 -18428 -14756 -9666 -6026 -3357 -2579 -360 2124 5515 7272 7788 7289 4673 255 -4987 -9402 -10893 -7353 -3594 535 3591 2891 418 -2797 -5838 -6209 -2477 103 1810 3523 4804 6785 8424 9075 7219 4381 111 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