File name: Pandora251s1_Nainital-ARIES_20241015_L2Fit_fout2c5d20240923p1-8.txt File generation date: 20241220T135135.6Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Manish Naja Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 251 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora251_OF_v2d20221122.txt Instrument calibration file used: Pandora251s1_CF_v5d20240923.txt Level 1 file used: Pandora251s1_Nainital-ARIES_20241015_L1_smca1c5d20240923p1-8.txt Full location name: Aryabhatta Research Institute of Observational Sciences (ARIES) Short location name: Nainital-ARIES Country of location: India Location latitude [deg]: 29.3588 Location longitude [deg]: 79.4583 Location altitude [m]: 1978 Local noon date: 20241015 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 4, but HCHO with MLE. First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0497 305.1909 305.3320 305.4732 305.6143 305.7554 305.8965 306.0376 306.1787 306.3197 306.4608 306.6018 306.7429 306.8839 307.0249 307.1659 307.3069 307.4479 307.5888 307.7298 307.8707 308.0117 308.1526 308.2935 308.4344 308.5753 308.7162 308.8570 308.9979 309.1387 309.2795 309.4204 309.5612 309.7020 309.8428 309.9835 310.1243 310.2651 310.4058 310.5465 310.6872 310.8280 310.9686 311.1093 311.2500 311.3907 311.5313 311.6720 311.8126 311.9532 312.0938 312.2344 312.3750 312.5156 312.6561 312.7967 312.9372 313.0777 313.2183 313.3588 313.4992 313.6397 313.7802 313.9207 314.0611 314.2015 314.3420 314.4824 314.6228 314.7632 314.9036 315.0439 315.1843 315.3246 315.4650 315.6053 315.7456 315.8859 316.0262 316.1664 316.3067 316.4470 316.5872 316.7274 316.8677 317.0079 317.1481 317.2883 317.4284 317.5686 317.7087 317.8489 317.9890 318.1291 318.2692 318.4093 318.5494 318.6895 318.8295 318.9696 319.1096 319.2496 319.3897 319.5297 319.6696 319.8096 319.9496 320.0895 320.2295 320.3694 320.5093 320.6493 320.7892 320.9290 321.0689 321.2088 321.3486 321.4885 321.6283 321.7681 321.9079 322.0477 322.1875 322.3273 322.4670 322.6068 322.7465 322.8862 323.0260 323.1657 323.3053 323.4450 323.5847 323.7243 323.8640 324.0036 324.1432 324.2829 324.4224 324.5620 324.7016 324.8412 324.9807 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241015T012047.7Z 9054.056107 176 1 52.37 2 82.92 104.10 131.79 288.86 0.00 1 0.00 1 0 25 5.607e-01 1.629e-02 5.065e-02 2.107e-03 7.480181e-01 1.110130e-03 8.065534e-03 -6.000000e+00 3.181119e-01 225.80 -2.00 3.21 -2.00 321.18 0.00e+00 5.238276e-03 5.226869e-04 3.983708e-03 -6.000000e+00 1.408283e-02 280.32 -2.00 20.00 -2.00 320.64 0.00e+00 7.483 0.005 302.00 328.00 3 1.0232e+00 3.6484e-03 7.0563e-02 -6.0000e+00 7.8714e-01 2.9139e-01 4.9034e-03 4.0477e-02 -6.0000e+00 8.5765e-01 -4.6842e-01 4.7816e-03 2.2565e-02 -6.0000e+00 5.1112e-01 1.9781e-01 2.2900e-03 7.8403e-03 -6.0000e+00 2.1527e-01 2.4691e-04 -6.2715e-04 5.5348e-05 1.2969e-04 -6.0000e+00 1.5410e-02 3.3367e-03 0.0000e+00 12 8 8 10 0 0 7.36 25.70 0.15 0.00334 -0.00138 182 26 1 5 0 287.710 34.25 20.00 25.70 21.06 8.9 921.15 -158419 -159322 -160887 -193091 -147549 -204071 -204860 -201044 -117119 -182479 -143861 -160646 -114535 -101759 -85425 -71943 -14972 -50978 -41885 -44155 -42546 -64446 -69776 -57398 -28379 -24221 -53492 -43208 -54007 -43695 -40537 -20435 -12776 997 -15594 -19297 -26572 1515 5655 3920 9009 16256 4579 12087 12421 15213 18135 4636 8843 14382 13733 10128 13512 10383 16592 8012 5861 9074 11173 2080 4364 10530 7778 8955 8622 8950 5460 7471 5789 4047 4557 4764 4346 1983 2315 -116 -1439 -5227 -1440 -1470 -269 -1920 -1855 -1060 -626 -1606 -146 314 352 -373 1 -1176 -2123 -2378 -2045 -2091 -806 -110 -731 -1355 -1029 -1433 -1112 -1332 -2005 -2297 -1606 -993 407 303 133 199 300 -169 -291 94 46 247 9 390 882 1627 1236 1110 1019 821 949 1300 506 459 278 89 69 76 -106 -254 538 150 -323 -260 -323 -777 -1139 -1924 -2292 -2525 -4040 -1764 -4117 -4363 -4507 -1247 -3989 -2231 -3361 -2142 -2196 -2001 -1789 -240 -1299 -1050 -1180 -1128 -2092 -2466 -1923 -752 -642 -1924 -1359 -1876 -1517 -1666 -831 -562 41 -724 -916 -1485 75 327 275 674 1213 404 1013 1052 1285 1532 469 909 1516 1637 1405 1991 1722 2741 1497 1144 1695 1972 395 840 2118 1851 2394 2445 2500 1590 2235 1783 1461 1798 1944 1742 760 800 -40 -483 -1901 -528 -649 -138 -1153 -1222 -675 -425 -1171 -110 241 269 -274 1 -838 -1502 -1640 -1612 -1938 -798 -124 -902 -1667 -1178 -1477 -1133 -1274 -2076 -2518 -1861 -1243 520 441 202 320 484 -266 -435 146 69 384 15 657 1443 2528 1864 1731 1532 1198 1361 2003 842 812 543 175 145 170 -240 -600 1284 363 -777 -592 -728 -1655 -2383 SS 20241015T013118.8Z 9054.063412 179 1 52.48 2 80.71 105.47 133.82 290.84 0.00 1 0.00 1 0 25 3.494e-01 8.589e-03 2.125e-02 8.994e-04 6.240438e-01 4.611737e-04 6.532091e-03 -6.000000e+00 1.982200e-01 225.80 -2.00 3.21 -2.00 320.28 0.00e+00 2.494984e-03 1.688172e-04 1.256126e-03 -6.000000e+00 8.774975e-03 280.32 -2.00 20.00 -2.00 319.68 0.00e+00 5.899 0.002 302.00 328.00 3 8.5757e-01 1.3768e-03 5.5159e-02 -6.0000e+00 4.9048e-01 3.4523e-02 1.7276e-03 2.9850e-02 -6.0000e+00 5.3441e-01 -8.4905e-02 1.6114e-03 1.5795e-02 -6.0000e+00 3.1848e-01 3.2615e-02 8.1546e-04 5.4124e-03 -6.0000e+00 1.3414e-01 1.1051e-03 -2.5253e-04 2.4354e-05 6.3751e-05 -6.0000e+00 9.6020e-03 3.1342e-03 0.0000e+00 11 8 0 10 0 0 8.79 25.68 0.20 0.00313 0.00124 428 61 1 5 0 122.590 34.25 20.00 25.68 22.61 8.9 930.06 -113133 -116885 -104599 -118734 -117696 -131111 -125282 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1013 1306 1412 1011 891 495 426 946 830 767 647 370 115 -28 -589 -744 -1173 -674 -940 -840 -939 -1849 -1196 -790 -739 -146 201 588 427 415 126 -201 -279 -647 -711 244 536 -165 -562 -769 -1092 -329 -452 -1727 -1387 -976 -657 540 839 587 477 575 -34 -80 304 168 324 162 -240 -4 984 1037 922 636 195 786 1328 218 279 -63 -225 -234 243 -285 -560 839 480 -172 -279 -752 -910 -693 SS 20241015T014042.3Z 9054.069934 184 1 52.51 2 78.74 106.73 135.61 292.71 0.00 1 0.00 1 0 25 1.560e-01 6.743e-03 8.802e-03 5.250e-04 5.384928e-01 2.654096e-04 5.676158e-03 -6.000000e+00 8.849243e-02 225.80 -2.00 3.21 -2.00 319.53 0.00e+00 1.570572e-03 7.573036e-05 5.157336e-04 -6.000000e+00 3.917327e-03 280.32 -2.00 20.00 -2.00 318.88 0.00e+00 4.954 0.001 302.00 328.00 3 6.6171e-01 7.4885e-04 4.6545e-02 -6.0000e+00 2.1897e-01 2.3609e-05 8.8875e-04 2.5264e-02 -6.0000e+00 2.3858e-01 -2.3333e-02 7.3725e-04 1.2758e-02 -6.0000e+00 1.4218e-01 5.5828e-03 3.8697e-04 4.0728e-03 -6.0000e+00 5.9888e-02 2.9855e-03 -1.6167e-04 1.4493e-05 4.3644e-05 -6.0000e+00 4.2865e-03 2.8659e-03 0.0000e+00 11 9 0 11 8 0 11.19 25.66 0.19 0.00287 0.00165 755 108 1 5 0 69.540 34.25 20.00 25.66 24.15 9.0 937.94 -56435 -51080 -47999 -54218 -54827 -61664 -53919 -57556 -38543 -43745 -39988 -37434 -29421 -20467 -16892 -14692 -5562 -8581 -7776 -5997 -5586 -6785 -6030 -6067 -5125 -5705 -7996 -8299 -8631 -6141 -3276 -2448 -870 -2624 -4261 -4491 -4892 -1687 -948 -439 -669 88 387 812 943 989 1417 520 236 1487 2484 1598 2045 2196 1724 1547 1037 809 652 513 1383 1935 2372 2284 832 755 96 343 1246 714 563 457 268 20 -355 -662 -1191 -1617 -1037 -1389 -1102 -1511 -2190 -1571 -665 -527 -56 353 700 582 559 186 -23 208 -144 -321 538 625 -165 -402 -657 -781 -105 -266 -1385 -1053 -864 -511 219 360 479 242 295 110 34 316 71 353 78 -272 -218 489 506 502 465 -32 629 1025 232 123 -66 -116 -171 40 -79 -262 338 212 -81 -111 -324 -444 -302 -881 -881 -865 -1016 -949 -1124 -986 -1241 -781 -1019 -938 -949 -845 -673 -661 -665 -257 -447 -434 -347 -332 -410 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