File name: Pandora251s1_Nainital-ARIES_20241113_L2Fit_fout2c5d20240923p1-8.txt File generation date: 20241220T141752.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Manish Naja Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 251 Spectrometer number: 1 Processing software version used: BlickP v1.8.60 Instrument operation file used: Pandora251_OF_v2d20221122.txt Instrument calibration file used: Pandora251s1_CF_v5d20240923.txt Level 1 file used: Pandora251s1_Nainital-ARIES_20241113_L1_smca1c5d20240923p1-8.txt Full location name: Aryabhatta Research Institute of Observational Sciences (ARIES) Short location name: Nainital-ARIES Country of location: India Location latitude [deg]: 29.3588 Location longitude [deg]: 79.4583 Location altitude [m]: 1978 Local noon date: 20241113 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 4, but HCHO with MLE. First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0497 305.1909 305.3320 305.4732 305.6143 305.7554 305.8965 306.0376 306.1787 306.3197 306.4608 306.6018 306.7429 306.8839 307.0249 307.1659 307.3069 307.4479 307.5888 307.7298 307.8707 308.0117 308.1526 308.2935 308.4344 308.5753 308.7162 308.8570 308.9979 309.1387 309.2795 309.4204 309.5612 309.7020 309.8428 309.9835 310.1243 310.2651 310.4058 310.5465 310.6872 310.8280 310.9686 311.1093 311.2500 311.3907 311.5313 311.6720 311.8126 311.9532 312.0938 312.2344 312.3750 312.5156 312.6561 312.7967 312.9372 313.0777 313.2183 313.3588 313.4992 313.6397 313.7802 313.9207 314.0611 314.2015 314.3420 314.4824 314.6228 314.7632 314.9036 315.0439 315.1843 315.3246 315.4650 315.6053 315.7456 315.8859 316.0262 316.1664 316.3067 316.4470 316.5872 316.7274 316.8677 317.0079 317.1481 317.2883 317.4284 317.5686 317.7087 317.8489 317.9890 318.1291 318.2692 318.4093 318.5494 318.6895 318.8295 318.9696 319.1096 319.2496 319.3897 319.5297 319.6696 319.8096 319.9496 320.0895 320.2295 320.3694 320.5093 320.6493 320.7892 320.9290 321.0689 321.2088 321.3486 321.4885 321.6283 321.7681 321.9079 322.0477 322.1875 322.3273 322.4670 322.6068 322.7465 322.8862 323.0260 323.1657 323.3053 323.4450 323.5847 323.7243 323.8640 324.0036 324.1432 324.2829 324.4224 324.5620 324.7016 324.8412 324.9807 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20241113T013533.8Z 9083.066363 170 1 51.76 2 84.60 114.22 132.84 310.35 0.00 1 0.00 1 0 17 5.841e-01 3.876e-02 2.408e-01 8.592e-03 8.347322e-01 4.744209e-03 8.731699e-03 -6.000000e+00 3.403785e-01 224.12 -2.00 3.21 -2.00 321.76 0.00e+00 1.461792e-02 2.310577e-03 8.080123e-04 -6.000000e+00 1.727664e-02 277.62 -2.00 20.00 -2.00 321.26 0.00e+00 9.324 0.009 302.00 328.00 3 1.6570e+00 1.6550e-02 8.5543e-02 -6.0000e+00 8.4023e-01 1.2714e+00 2.0634e-02 5.0810e-02 -6.0000e+00 9.2032e-01 -1.5877e+00 1.7319e-02 2.1308e-02 -6.0000e+00 5.4640e-01 6.3033e-01 8.5383e-03 1.7137e-02 -6.0000e+00 2.3246e-01 2.3938e-05 -5.8657e-04 2.3277e-04 2.1411e-04 -6.0000e+00 1.6631e-02 2.1340e-03 0.0000e+00 12 9 8 11 32 0 -7.26 25.36 -0.26 0.00213 -0.00227 30 4 1 5 0 1725.010 34.25 19.99 25.36 19.25 8.9 907.23 900000 262701 900000 202312 900000 900000 169855 -103779 900000 -11848 900000 12014 57886 58001 900000 129413 900000 900000 -73613 201002 178491 143171 21493 10935 70618 900000 90008 75086 -22026 17235 114500 -32697 157537 53472 97258 4424 -54765 37767 104415 56496 61696 -11531 65388 -15662 54149 104629 900000 43882 43632 70253 62770 38517 29804 22709 82479 7206 15551 -33831 41704 -13765 17003 43101 4564 45573 47151 36250 15942 34013 12054 11278 35588 51292 36617 21705 7919 8557 5780 -20192 1300 -8459 444 -20185 -692 6048 719 -10355 4397 4250 10880 -1059 1039 1767 -4017 -1340 -6361 -8282 -3934 -3278 1751 -3766 -1402 -6133 1237 -1317 4103 -6154 -3799 -566 -643 1988 -1431 102 2021 -106 -4464 -37 -1631 -1109 -237 2100 4172 2397 -2122 345 2035 2241 -293 1655 2301 1748 -1020 860 -215 1225 1391 483 996 -701 -907 -1419 2160 -1312 -3270 900000 2196 900000 1692 900000 900000 1420 -8046 900000 -333 900000 274 1056 1367 900000 2164 900000 900000 -10799 1833 1899 1959 931 507 1718 900000 1642 1484 -1122 655 2202 -2958 2634 2593 2765 296 -6202 2053 3318 3259 3611 -1446 3882 -2095 3577 4199 900000 3376 3502 4582 4828 4122 3713 3209 6551 1211 2366 -8062 4394 -2440 2275 4901 874 6554 7017 5910 3186 5887 2852 3046 8123 10164 8052 5063 1880 1789 1179 -5622 340 -2956 167 -10717 -330 2837 377 -6390 2430 2395 5686 -595 531 847 -2019 -704 -4080 -5861 -3157 -3040 1680 -3790 -1282 -5231 976 -974 3078 -5398 -3477 -550 -704 2441 -2056 154 3045 -159 -6728 -53 -2393 -1707 -351 3377 6374 3549 -3173 485 2726 2914 -387 2343 3773 3030 -2023 1807 -487 2698 3274 1194 2485 -1796 -2285 -3379 4981 -2921 -7230 SS 20241113T014651.0Z 9083.074202 173 1 52.48 2 82.37 115.73 134.55 313.21 0.00 1 0.00 1 0 25 5.398e-01 1.557e-02 4.359e-02 1.982e-03 7.083295e-01 1.030366e-03 7.551273e-03 -6.000000e+00 3.043481e-01 224.12 -2.00 3.21 -2.00 320.91 0.00e+00 6.006901e-03 4.472953e-04 2.708607e-03 -6.000000e+00 1.340744e-02 277.62 -2.00 20.00 -2.00 320.39 0.00e+00 7.024 0.004 302.00 328.00 3 1.3695e+00 3.2570e-03 6.5099e-02 -6.0000e+00 7.5091e-01 2.1687e-01 4.2902e-03 3.4975e-02 -6.0000e+00 8.1948e-01 -3.4729e-01 4.1929e-03 2.0982e-02 -6.0000e+00 4.8822e-01 1.4873e-01 2.0443e-03 8.9423e-03 -6.0000e+00 2.0589e-01 2.5690e-04 -4.5752e-04 5.2385e-05 1.2067e-04 -6.0000e+00 1.4827e-02 1.9706e-03 0.0000e+00 12 9 8 11 8 0 14.70 25.36 0.12 0.00197 -0.00147 148 21 1 5 0 354.520 34.00 20.00 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-874 -737 -277 -373 -440 -657 -1717 -401 648 513 321 1217 240 1645 922 1300 1511 1118 1313 1517 1805 1737 2135 1716 2071 1462 1508 1450 1056 876 1496 1775 1634 2188 2180 1899 1024 1267 1883 984 1692 1343 1116 877 -87 -959 -660 -1250 -948 -1719 -659 -621 -1981 -1594 -733 -1294 -107 -417 645 88 235 -768 -1303 -1195 -1189 -1829 -655 283 -454 -1334 -720 -1598 -458 -946 -1737 -2051 -1493 -649 144 526 402 675 379 -543 -606 816 100 174 214 279 1094 1805 1681 1842 1362 746 1197 2164 661 597 401 266 -104 -20 -28 -631 1095 329 -352 -372 -905 -1772 -1992 SS 20241113T020506.6Z 9083.086881 178 1 52.52 2 78.83 118.27 137.13 318.22 0.00 1 0.00 1 0 17 1.584e-01 6.825e-03 9.825e-03 5.782e-04 5.402452e-01 2.901307e-04 5.707450e-03 -6.000000e+00 8.930258e-02 224.12 -2.00 3.21 -2.00 319.53 0.00e+00 1.545159e-03 8.223640e-05 4.484579e-04 -6.000000e+00 3.933867e-03 277.62 -2.00 20.00 -2.00 318.92 0.00e+00 4.991 0.001 302.00 328.00 3 8.4271e-01 8.1457e-04 4.6655e-02 -6.0000e+00 2.2034e-01 3.2867e-04 9.6634e-04 2.5150e-02 -6.0000e+00 2.4045e-01 -2.0941e-02 8.1451e-04 1.2780e-02 -6.0000e+00 1.4325e-01 5.4443e-03 4.2916e-04 4.1429e-03 -6.0000e+00 6.0414e-02 2.4287e-03 -1.2367e-04 1.5947e-05 4.4280e-05 -6.0000e+00 4.3504e-03 1.6775e-03 0.0000e+00 11 8 0 10 0 0 9.13 25.32 0.21 0.00168 0.00075 612 87 1 5 0 85.810 34.00 20.00 25.32 20.69 9.0 915.91 -47313 -46107 -52877 -59563 -55202 -58239 -58377 -58968 -42854 -39357 -45343 -43622 -31542 -20550 -14562 -12584 -8408 -7800 -5298 -6912 -8091 -8091 -5962 -6645 -5629 -4422 -7407 -7882 -10467 -6761 -3992 -3019 -812 -3072 -4158 -5377 -6086 -1775 -619 -286 -496 79 63 934 1323 1516 1167 989 532 1590 2183 1774 2385 2078 1878 1820 1113 366 575 655 1066 1746 2341 2323 926 673 268 477 1209 679 431 422 149 191 -335 -661 -802 -1605 -1261 -1564 -1105 -1480 -2119 -1462 -780 -575 4 226 699 505 556 181 31 194 -39 -323 521 659 -218 -391 -617 -801 -37 -254 -1393 -1097 -935 -556 251 400 445 310 383 102 91 305 70 273 -19 -263 -209 352 536 515 410 8 614 1130 316 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