File name: Pandora251s1_Nainital-ARIES_20250216_L2Fit_fout2c5d20240923p1-8.txt File generation date: 20250216T190002.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c5p1-8 Local principal investigator: Manish Naja Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 251 Spectrometer number: 1 Processing software version used: BlickP v1.8.70 Instrument operation file used: Pandora251_OF_v2d20221122.txt Instrument calibration file used: Pandora251s1_CF_v5d20240923.txt Level 1 file used: Pandora251s1_Nainital-ARIES_20250216_L1_smca1c5d20240923p1-8.txt Full location name: Aryabhatta Research Institute of Observational Sciences (ARIES) Short location name: Nainital-ARIES Country of location: India Location latitude [deg]: 29.3588 Location longitude [deg]: 79.4583 Location altitude [m]: 1978 Local noon date: 20250216 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 4, but HCHO with MLE. First and last pixel inside fitting window: 196 338 Nominal wavelengths inside fitting window [nm]: 305.0497 305.1909 305.3320 305.4732 305.6143 305.7554 305.8965 306.0376 306.1787 306.3197 306.4608 306.6018 306.7429 306.8839 307.0249 307.1659 307.3069 307.4479 307.5888 307.7298 307.8707 308.0117 308.1526 308.2935 308.4344 308.5753 308.7162 308.8570 308.9979 309.1387 309.2795 309.4204 309.5612 309.7020 309.8428 309.9835 310.1243 310.2651 310.4058 310.5465 310.6872 310.8280 310.9686 311.1093 311.2500 311.3907 311.5313 311.6720 311.8126 311.9532 312.0938 312.2344 312.3750 312.5156 312.6561 312.7967 312.9372 313.0777 313.2183 313.3588 313.4992 313.6397 313.7802 313.9207 314.0611 314.2015 314.3420 314.4824 314.6228 314.7632 314.9036 315.0439 315.1843 315.3246 315.4650 315.6053 315.7456 315.8859 316.0262 316.1664 316.3067 316.4470 316.5872 316.7274 316.8677 317.0079 317.1481 317.2883 317.4284 317.5686 317.7087 317.8489 317.9890 318.1291 318.2692 318.4093 318.5494 318.6895 318.8295 318.9696 319.1096 319.2496 319.3897 319.5297 319.6696 319.8096 319.9496 320.0895 320.2295 320.3694 320.5093 320.6493 320.7892 320.9290 321.0689 321.2088 321.3486 321.4885 321.6283 321.7681 321.9079 322.0477 322.1875 322.3273 322.4670 322.6068 322.7465 322.8862 323.0260 323.1657 323.3053 323.4450 323.5847 323.7243 323.8640 324.0036 324.1432 324.2829 324.4224 324.5620 324.7016 324.8412 324.9807 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20250216T014947.0Z 9178.076239 255 1 52.66 2 84.68 107.32 72.96 255.08 0.00 1 0.00 1 0 17 3.118e-01 2.727e-02 6.606e-02 4.515e-03 9.438180e-01 2.438766e-03 9.440829e-03 -6.000000e+00 1.760132e-01 224.18 -2.00 3.21 -2.00 321.94 0.00e+00 1.492773e-03 1.163139e-03 3.105689e-03 -6.000000e+00 7.627964e-03 273.93 -2.00 20.00 -2.00 321.50 0.00e+00 9.433 0.009 302.00 328.00 3 5.1175e-01 8.3234e-03 8.7914e-02 -6.0000e+00 4.3488e-01 1.2510e+00 1.0325e-02 4.8088e-02 -6.0000e+00 4.7468e-01 -1.7790e+00 8.1014e-03 2.4494e-02 -6.0000e+00 2.8219e-01 7.2874e-01 4.0733e-03 7.4089e-03 -6.0000e+00 1.1875e-01 7.2214e-05 -1.0798e-03 1.1282e-04 1.2901e-04 -6.0000e+00 8.5598e-03 -6.3424e-03 0.0000e+00 12 8 8 10 0 0 -20.69 24.38 0.17 -0.00634 -0.01446 115 16 1 5 0 457.880 33.50 20.00 24.38 13.41 8.8 870.46 18571 8785 -8093 -41411 -27388 -26772 -76768 -128627 -58776 -69042 -66108 -78390 -63131 262 22022 -4739 79196 41028 42450 4612 947 -8333 -14764 -41853 18571 73719 -10982 -12396 -65044 -11924 -3446 -7623 18032 14813 8562 17159 -44881 9438 78275 57846 49673 60420 35936 87763 43134 46667 74404 23930 38207 35388 40815 45930 48378 22331 54097 30667 21584 30066 29336 8961 22238 28562 1463 21886 26682 22820 18684 28302 20334 19061 20126 24241 19782 17984 6034 772 4512 -12578 -4554 -3571 1556 861 -781 1458 2834 -1245 736 2874 5374 520 -1979 -1754 -3908 -3772 -5786 -6627 -4603 245 -1525 -3727 -3370 -5263 -3504 -3669 -4593 -4692 -2857 -2681 -940 -815 -430 -748 374 -854 -1274 941 -1103 -495 251 1293 1768 2904 1963 3300 2190 2408 2122 2822 604 1385 305 693 -367 286 157 238 846 -161 -415 -409 57 -1368 -2618 550 306 -324 -2022 -943 -793 -3595 -10195 -2353 -3040 -2752 -3922 -3260 9 714 -230 1775 1396 1427 218 43 -380 -697 -2664 654 1475 -488 -506 -4166 -520 -164 -446 921 809 456 778 -3913 536 2619 2751 2800 3166 2421 3439 2545 2610 3145 1718 2490 2540 3073 3640 4047 2606 4812 3524 2728 3363 3074 1081 2340 3056 235 3267 4053 3587 3101 4499 3877 4205 4785 5668 4660 3943 1318 157 835 -2902 -1129 -1068 527 341 -349 676 1377 -604 363 1413 2806 272 -991 -835 -1905 -1992 -3317 -4587 -3714 220 -1539 -3861 -3256 -4614 -2706 -2818 -3810 -4120 -2634 -2715 -1062 -984 -594 -1133 577 -1323 -1918 1354 -1654 -777 411 2139 2814 4325 2839 4563 2970 3179 2783 4012 1035 2528 634 1569 -836 697 412 650 2330 -422 -1147 -1059 134 -3036 -6115 SS 20250216T020045.7Z 9178.083863 258 1 52.48 2 82.40 108.75 75.25 256.52 0.00 1 0.00 1 0 17 6.624e-01 1.416e-02 3.508e-02 1.274e-03 7.865371e-01 6.669095e-04 8.116042e-03 -6.000000e+00 3.739552e-01 224.18 -2.00 3.21 -2.00 321.10 0.00e+00 5.421538e-03 2.988920e-04 2.320910e-03 -6.000000e+00 1.620532e-02 273.93 -2.00 20.00 -2.00 320.64 0.00e+00 7.049 0.004 302.00 328.00 3 4.4043e-01 2.1231e-03 6.7061e-02 -6.0000e+00 9.2395e-01 2.1809e-01 2.9211e-03 3.8495e-02 -6.0000e+00 1.0085e+00 -3.5484e-01 3.1032e-03 2.3136e-02 -6.0000e+00 5.9953e-01 1.4981e-01 1.4989e-03 9.8548e-03 -6.0000e+00 2.5232e-01 5.9667e-04 -4.4991e-04 3.2577e-05 1.2643e-04 -6.0000e+00 1.8185e-02 -6.7796e-03 0.0000e+00 12 8 8 10 0 0 27.27 24.38 0.16 -0.00678 -0.01016 390 56 1 5 0 134.550 33.50 20.00 24.38 14.13 8.7 874.69 -218276 -194920 -199180 -198726 -196828 -226469 -218145 -240617 -202102 -188004 -183066 -178811 -148163 -118069 -80601 -79326 -32893 -65440 -52434 -48480 -55727 -72234 -68051 -58733 -43178 -33861 -55429 -52216 -57446 -42892 -33038 -27379 -9091 -13844 -14319 -14622 -24040 -1157 504 4162 6167 10153 5648 11479 9830 10951 16282 5411 9089 10562 8704 11190 9709 9484 11599 7667 5326 6206 5154 2579 3902 6628 6341 7836 6055 5749 4194 3872 4212 4308 3650 3021 2578 2481 1322 -967 -1020 -2910 -1328 -1672 -705 -1037 -1672 -1318 -919 -1465 -79 300 834 362 -196 -306 -1696 -1652 -1817 -1779 -156 246 -551 -620 -904 -1402 -484 -1047 -2079 -1946 -1420 -900 -83 99 203 92 341 -69 -212 283 50 215 240 272 473 1078 1124 949 869 501 909 1375 447 522 188 241 -175 123 -194 -381 295 89 -121 -233 -297 -683 -712 -2662 -2267 -2654 -2603 -2311 -3452 -3227 -4917 -3126 -2738 -2956 -3198 -2558 -2024 -1241 -1498 -453 -1406 -1081 -1012 -1274 -1929 -1809 -1539 -1035 -778 -1618 -1446 -1677 -1209 -1046 -1010 -331 -576 -580 -585 -1156 -52 27 261 430 736 454 898 796 904 1323 517 895 1119 1062 1507 1468 1577 2015 1444 1054 1208 979 492 761 1398 1551 1971 1660 1576 1181 1151 1389 1639 1542 1335 1122 1010 492 -330 -330 -1001 -518 -792 -392 -612 -1096 -915 -679 -1158 -60 230 635 288 -146 -216 -1193 -1233 -1439 -1662 -156 284 -652 -731 -1071 -1493 -499 -1089 -2174 -2143 -1654 -1134 -107 137 316 145 538 -112 -332 426 77 345 383 445 752 1727 1735 1414 1248 746 1324 2010 759 951 359 497 -364 271 -436 -899 703 216 -290 -526 -658 -1424 -1446 SS 20250216T021829.0Z 9178.096169 263 1 52.53 2 78.77 111.14 78.97 258.77 0.00 1 0.00 1 0 17 2.252e-01 7.110e-03 9.174e-03 4.327e-04 5.965708e-01 2.187244e-04 6.241239e-03 -6.000000e+00 1.271550e-01 224.18 -2.00 3.21 -2.00 319.78 0.00e+00 2.228494e-03 6.639889e-05 4.567305e-04 -6.000000e+00 5.510028e-03 273.93 -2.00 20.00 -2.00 319.26 0.00e+00 4.967 0.001 302.00 328.00 3 2.2740e-01 6.1762e-04 4.7908e-02 -6.0000e+00 3.1417e-01 9.4523e-03 7.4328e-04 2.7781e-02 -6.0000e+00 3.4290e-01 -3.1197e-02 6.7346e-04 1.4435e-02 -6.0000e+00 2.0385e-01 9.2187e-03 3.5315e-04 5.1457e-03 -6.0000e+00 8.5798e-02 4.2797e-03 -1.6767e-04 1.1593e-05 5.2828e-05 -6.0000e+00 6.1829e-03 -7.0785e-03 0.0000e+00 11 8 0 10 0 0 6.91 24.31 0.19 -0.00708 -0.00834 1156 165 1 5 0 45.430 33.25 20.00 24.31 15.48 8.8 881.24 -83681 -69152 -66612 -72936 -79579 -79863 -76965 -77939 -71355 -62622 -61648 -55822 -48021 -35405 -23738 -20021 -14632 -14284 -12759 -11053 -12687 -13452 -11416 -11195 -10008 -8600 -11288 -11545 -13175 -10146 -5157 -4194 -520 -3906 -5986 -5185 -6069 -2519 -1231 -336 -426 336 14 866 1420 1280 1293 855 877 1598 2168 2171 2471 2295 1972 1871 1392 946 629 722 1735 2437 2671 2599 990 1127 523 182 1222 828 557 451 169 377 -253 -823 -1393 -1718 -1121 -1413 -1047 -1386 -2110 -1545 -856 -651 -94 227 715 660 493 165 -111 69 -153 -319 449 709 -120 -379 -485 -688 17 -218 -1410 -1167 -834 -551 115 345 392 234 350 102 77 385 67 282 22 -273 -243 425 557 512 419 -80 618 1087 239 191 2 -23 -123 39 -158 -347 281 202 -143 -84 -285 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