File name: Pandora227s1_NakhonPathom_20250228_L2Fit_fout2c3d20240531p1-8.txt File generation date: 20250327T115404.7Z Data description: Level 2 spectral fitting results file Data file version: fout2c3p1-8 Local principal investigator: Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 227 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora227_OF_v1d20220531.txt Instrument calibration file used: Pandora227s1_CF_v3d20240531.txt Level 1 file used: Pandora227s1_NakhonPathom_20250228_L1_smca1c3d20240531p1-8.txt Full location name: Silpakorn University, Sanam Chandra palace campus (Nakhon Pathom) Short location name: NakhonPathom Country of location: Thailand Location latitude [deg]: 13.8200 Location longitude [deg]: 100.0400 Location altitude [m]: 72 Local noon date: 20250228 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on lab session 1 First and last pixel inside fitting window: 199 341 Nominal wavelengths inside fitting window [nm]: 305.0039 305.1450 305.2862 305.4272 305.5683 305.7094 305.8505 305.9915 306.1326 306.2736 306.4146 306.5556 306.6966 306.8376 306.9786 307.1195 307.2605 307.4014 307.5423 307.6833 307.8242 307.9651 308.1059 308.2468 308.3877 308.5285 308.6694 308.8102 308.9510 309.0918 309.2326 309.3734 309.5142 309.6549 309.7957 309.9364 310.0772 310.2179 310.3586 310.4993 310.6400 310.7806 310.9213 311.0620 311.2026 311.3432 311.4838 311.6244 311.7650 311.9056 312.0462 312.1868 312.3273 312.4678 312.6084 312.7489 312.8894 313.0299 313.1704 313.3108 313.4513 313.5918 313.7322 313.8726 314.0130 314.1534 314.2938 314.4342 314.5746 314.7149 314.8553 314.9956 315.1359 315.2763 315.4166 315.5569 315.6971 315.8374 315.9777 316.1179 316.2581 316.3984 316.5386 316.6788 316.8190 316.9591 317.0993 317.2395 317.3796 317.5197 317.6599 317.8000 317.9401 318.0802 318.2202 318.3603 318.5004 318.6404 318.7804 318.9204 319.0604 319.2004 319.3404 319.4804 319.6204 319.7603 319.9003 320.0402 320.1801 320.3200 320.4599 320.5998 320.7396 320.8795 321.0194 321.1592 321.2990 321.4388 321.5786 321.7184 321.8582 321.9980 322.1377 322.2775 322.4172 322.5569 322.6966 322.8363 322.9760 323.1157 323.2554 323.3950 323.5346 323.6743 323.8139 323.9535 324.0931 324.2327 324.3722 324.5118 324.6514 324.7909 324.9304 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-385: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20250228T082544.8Z 9190.351213 30 1 51.62 2 48.16 245.91 44.63 243.77 0.00 1 0.00 1 0 17 8.935e-03 6.962e-03 2.131e-04 1.474e-04 1.727122e-01 7.450469e-05 1.852406e-03 -6.000000e+00 5.042078e-03 226.33 -2.00 3.09 -2.00 314.93 0.00e+00 4.503133e-04 6.636064e-06 5.290228e-05 -6.000000e+00 2.344001e-04 293.40 -2.00 20.00 -2.00 314.19 0.00e+00 1.496 0.000 302.00 328.00 3 7.9597e-01 1.9007e-04 1.6606e-02 -6.0000e+00 1.2440e-02 -2.2786e-02 2.1172e-04 7.7644e-03 -6.0000e+00 1.3507e-02 4.3654e-03 1.2144e-04 3.7823e-03 -6.0000e+00 8.1107e-03 -5.4282e-03 5.4065e-05 1.0685e-03 -6.0000e+00 3.4846e-03 4.7183e-02 2.7221e-04 4.0939e-06 1.3474e-05 -6.0000e+00 2.3712e-04 2.7236e-02 0.0000e+00 11 8 0 10 0 0 12.27 25.77 0.27 0.02724 0.02928 2135 350 1 5 0 24.140 27.99 20.00 25.77 45.05 1.1 1100.00 -114 -78 -158 -1971 -2404 -2507 -1109 85 588 -443 -1618 -1416 -923 -330 624 306 326 688 1086 1495 959 823 1399 1155 810 752 391 -44 -589 322 591 973 1277 -902 -2481 -2596 -2615 -1517 -430 -403 -558 -405 -330 -277 209 -45 -368 -536 -755 -174 476 557 1013 807 730 1006 565 338 233 317 756 1366 1843 1659 518 -115 -601 -777 385 677 497 746 426 506 115 -291 -1164 -1475 -1221 -1331 -1300 -1557 -2022 -1600 -912 -430 -73 249 794 568 358 -139 -484 -204 -265 89 336 747 319 -108 -327 -956 -795 -438 -802 -810 -715 -514 162 597 822 679 515 142 -142 -129 -30 150 290 347 155 410 642 417 684 195 221 466 251 286 -69 -145 -302 18 -100 126 259 242 55 -137 -444 -652 -768 -38 -28 -58 -701 -752 -788 -355 28 211 -170 -615 -530 -345 -138 270 145 159 340 552 778 481 435 739 599 441 424 222 -23 -310 161 302 524 686 -511 -1331 -1421 -1444 -899 -285 -295 -425 -321 -269 -227 170 -36 -292 -410 -588 -132 374 442 839 668 621 866 496 297 201 272 663 1273 1761 1608 504 -107 -538 -667 342 647 500 785 432 520 116 -278 -1005 -1250 -1057 -1225 -1276 -1610 -2141 -1761 -1025 -498 -89 302 964 692 420 -155 -511 -205 -277 97 388 913 399 -134 -393 -1113 -914 -501 -968 -1033 -917 -686 216 810 1162 965 699 185 -182 -155 -37 187 375 466 215 562 858 554 890 243 270 569 313 379 -92 -197 -417 25 -140 187 380 364 83 -205 -666 -949 -1099 SU 20250228T082836.2Z 9190.353197 33 1 51.60 2 48.79 246.33 45.23 244.26 0.00 1 0.00 1 0 17 9.043e-03 6.972e-03 2.229e-04 1.523e-04 1.748963e-01 7.682483e-05 1.873056e-03 -6.000000e+00 5.102897e-03 226.33 -2.00 3.09 -2.00 314.99 0.00e+00 4.417613e-04 6.940165e-06 5.424023e-05 -6.000000e+00 2.372268e-04 293.40 -2.00 20.00 -2.00 314.25 0.00e+00 1.515 0.000 302.00 328.00 3 8.3893e-01 1.9609e-04 1.6811e-02 -6.0000e+00 1.2590e-02 -2.3654e-02 2.1871e-04 7.8550e-03 -6.0000e+00 1.3670e-02 4.3115e-03 1.2530e-04 3.8288e-03 -6.0000e+00 8.2085e-03 -5.5727e-03 5.5867e-05 1.0825e-03 -6.0000e+00 3.5266e-03 4.4223e-02 2.7776e-04 4.2225e-06 1.3595e-05 -6.0000e+00 2.3998e-04 2.7201e-02 0.0000e+00 11 8 0 10 0 0 6.39 25.77 0.28 0.02720 0.02929 2037 334 1 5 0 25.300 27.99 19.99 25.77 45.15 1.1 1100.00 -126 -127 -244 -1966 -2562 -2478 -1186 117 612 -427 -1711 -1353 -988 -362 620 298 442 672 1155 1476 1017 834 1369 1219 756 787 429 6 -649 318 628 987 1349 -945 -2462 -2678 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690 178 -177 -174 5 162 365 450 194 530 826 552 867 286 266 584 296 397 -68 -245 -386 -9 -124 173 392 350 66 -169 -663 -951 -1071 SU 20250228T083128.8Z 9190.355195 36 1 51.64 2 49.43 246.74 45.84 244.73 0.00 1 0.00 1 0 17 9.136e-03 7.036e-03 2.287e-04 1.545e-04 1.771729e-01 7.787440e-05 1.897100e-03 -6.000000e+00 5.155160e-03 226.33 -2.00 3.09 -2.00 315.04 0.00e+00 4.509090e-04 7.117887e-06 5.761072e-05 -6.000000e+00 2.396568e-04 293.40 -2.00 20.00 -2.00 314.29 0.00e+00 1.535 0.000 302.00 328.00 3 8.4124e-01 1.9886e-04 1.7029e-02 -6.0000e+00 1.2719e-02 -2.3828e-02 2.2178e-04 7.9587e-03 -6.0000e+00 1.3810e-02 4.0761e-03 1.2705e-04 3.8777e-03 -6.0000e+00 8.2926e-03 -5.3676e-03 5.6800e-05 1.0960e-03 -6.0000e+00 3.5627e-03 4.3109e-02 2.6341e-04 4.2836e-06 1.3833e-05 -6.0000e+00 2.4244e-04 2.7228e-02 0.0000e+00 11 8 0 10 0 0 5.21 25.78 0.27 0.02723 0.02921 2020 332 1 5 0 25.510 27.99 20.00 25.78 45.18 1.1 1100.00 -181 -92 -188 -2071 -2463 -2620 -1201 -22 527 -533 -1734 -1411 -948 -309 555 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