File name: Pandora227s1_NakhonPathom_20250702_L2Fit_fwvt1c3d20240531p1-8.txt File generation date: 20250702T173045.0Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Darunee Promchot Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 227 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora227_OF_v2d20220531.txt Instrument calibration file used: Pandora227s1_CF_v3d20240531.txt Level 1 file used: Pandora227s1_NakhonPathom_20250702_L1_smca1c3d20240531p1-8.txt Full location name: Silpakorn University, Sanam Chandra palace campus (Nakhon Pathom) Short location name: NakhonPathom Country of location: Thailand Location latitude [deg]: 13.8200 Location longitude [deg]: 100.0400 Location altitude [m]: 72 Local noon date: 20250702 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on lab session 1 First and last pixel inside fitting window: 1617 1766 Nominal wavelengths inside fitting window [nm]: 492.0832 492.2045 492.3258 492.4471 492.5683 492.6895 492.8107 492.9319 493.0531 493.1742 493.2954 493.4165 493.5376 493.6587 493.7798 493.9008 494.0218 494.1429 494.2639 494.3848 494.5058 494.6268 494.7477 494.8686 494.9895 495.1104 495.2313 495.3521 495.4729 495.5937 495.7145 495.8353 495.9561 496.0768 496.1975 496.3183 496.4389 496.5596 496.6803 496.8009 496.9215 497.0422 497.1627 497.2833 497.4039 497.5244 497.6449 497.7654 497.8859 498.0064 498.1268 498.2473 498.3677 498.4881 498.6085 498.7288 498.8492 498.9695 499.0898 499.2101 499.3304 499.4507 499.5709 499.6911 499.8113 499.9315 500.0517 500.1719 500.2920 500.4121 500.5322 500.6523 500.7724 500.8925 501.0125 501.1325 501.2525 501.3725 501.4925 501.6124 501.7323 501.8523 501.9722 502.0920 502.2119 502.3317 502.4516 502.5714 502.6912 502.8110 502.9307 503.0505 503.1702 503.2899 503.4096 503.5292 503.6489 503.7685 503.8882 504.0078 504.1273 504.2469 504.3665 504.4860 504.6055 504.7250 504.8445 504.9639 505.0834 505.2028 505.3222 505.4416 505.5610 505.6803 505.7997 505.9190 506.0383 506.1576 506.2769 506.3961 506.5154 506.6346 506.7538 506.8730 506.9921 507.1113 507.2304 507.3495 507.4686 507.5877 507.7067 507.8258 507.9448 508.0638 508.1828 508.3018 508.4207 508.5397 508.6586 508.7775 508.8964 509.0152 509.1341 509.2529 509.3717 509.4905 509.6093 509.7281 509.8468 509.9655 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250702T015406.2Z 9314.079238 134 1 51.53 2 50.36 71.38 132.50 79.92 0.00 1 0.00 1 0 15 3.816e-03 3.806e-03 1.326e-03 1.320e-03 7.074386e+03 8.880262e+01 4.896440e+02 -6.000000e+00 2.181187e+02 294.79 -2.00 20.00 -2.00 505.23 0.00e+00 4.291152e-04 3.742953e-05 3.576098e-05 -6.000000e+00 1.096186e-04 294.79 -2.00 20.00 -2.00 500.28 0.00e+00 1.810215e-01 2.605384e-02 3.747386e-02 -6.000000e+00 7.424021e-02 227.84 -2.00 3.09 -2.00 501.89 0.00e+00 1.564 0.000 489.00 513.00 1 7.7153e+00 2.0128e-03 4.0173e-03 -6.0000e+00 5.7171e-03 1.0565e-02 5.1279e-04 9.5755e-04 -6.0000e+00 1.4786e-03 6.8009e-04 5.2101e-06 1.1834e-04 4.6233e-05 -6.0000e+00 3.6376e-04 1.7567e-02 4.2971e-06 11 9 0 11 16 0 90.87 24.73 0.96 0.01757 0.01760 13 2 1 4 0 3963.060 27.15 20.00 24.73 35.85 1.7 1047.35 -590 -520 -361 -140 262 467 845 421 305 553 161 -56 -307 -644 -837 -189 -156 254 -124 524 174 180 258 293 405 351 487 -204 -475 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106 120 263 112 459 255 527 187 486 172 -233 -54 474 -2 587 -118 345 283 61 247 -212 -53 -356 -368 -595 45 137 263 -204 281 -5 201 288 485 409 87 -323 -381 -427 -402 SQ 20250702T020638.3Z 9314.087943 141 1 51.13 2 47.47 71.28 129.62 81.12 0.00 1 0.00 1 0 22 3.308e-03 3.294e-03 9.292e-04 9.263e-04 5.733358e+03 6.145040e+01 3.960257e+02 -6.000000e+00 1.891316e+02 294.79 -2.00 20.00 -2.00 505.31 0.00e+00 3.998767e-04 2.612953e-05 2.919250e-05 -6.000000e+00 9.504810e-05 294.79 -2.00 20.00 -2.00 500.45 0.00e+00 1.613126e-01 1.804927e-02 3.296886e-02 -6.000000e+00 6.438701e-02 227.84 -2.00 3.09 -2.00 502.06 0.00e+00 1.477 0.000 489.00 513.00 1 7.1719e+00 1.3876e-03 3.5731e-03 -6.0000e+00 4.9581e-03 1.0115e-02 3.5490e-04 8.2726e-04 -6.0000e+00 1.2827e-03 1.1906e-03 2.1486e-04 8.4987e-05 3.4654e-05 -6.0000e+00 3.1544e-04 1.9656e-02 -2.4373e-05 11 1 0 11 16 0 99.52 24.72 0.96 0.01966 0.02115 25 4 1 4 0 2045.150 27.15 19.99 24.72 36.46 1.8 1053.12 -863 -686 -427 44 173 406 531 290 363 324 177 57 -329 -312 -426 -334 -128 86 157 19 283 231 300 366 265 334 324 -27 -249 -212 -352 -368 -48 235 230 74 50 -160 -354 -15 -194 332 279 345 263 331 392 299 74 -446 -633 -716 -631 -522 -355 -102 -32 205 -91 -45 265 526 480 264 404 127 128 -159 -386 -313 -250 -90 -207 61 -96 -174 -241 -511 -306 -294 -282 -348 -91 -4 70 -83 -282 25 -88 86 322 496 576 498 298 366 280 -404 -635 -700 -523 -543 -88 -119 -96 -199 -483 -436 -247 102 -3 129 92 242 488 470 574 383 236 71 -72 160 203 155 142 319 424 324 53 -39 -210 -231 -413 -293 -191 148 -15 61 58 100 62 311 233 425 307 -104 -415 -649 -503 -387 -852 -692 -445 47 176 421 559 307 382 336 181 57 -328 -331 -452 -331 -129 89 166 20 301 245 319 390 284 357 344 -28 -252 -208 -344 -363 -49 245 246 79 53 -167 -367 -15 -200 343 291 364 280 351 412 309 75 -441 -608 -727 -638 -499 -349 -103 -33 211 -93 -46 272 540 494 272 409 127 126 -155 -371 -297 -237 -86 -201 60 -95 -168 -229 -479 -284 -272 -263 -328 -86 -4 68 -81 -276 25 -86 84 317 493 577 495 291 348 259 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1.7 1054.60 -790 -843 -350 164 -162 159 579 279 197 335 -29 -63 -582 -797 -538 -348 34 261 181 133 96 84 184 453 599 488 328 14 -323 -114 -168 -513 -95 303 205 349 -41 -171 -277 -103 343 363 -19 487 361 254 266 299 -116 -263 -688 -928 -395 -773 -324 -18 52 105 -95 -170 216 848 269 232 375 124 91 174 -443 -106 -304 -86 -112 122 -150 -82 -279 -57 -425 85 -272 -37 -172 -416 -74 51 -628 -139 40 189 447 560 459 339 392 526 69 -472 -695 -772 -512 -572 48 -84 -25 -411 -395 -257 90 10 -18 17 27 221 515 706 602 36 353 -159 210 269 441 214 -110 316 204 429 177 191 -52 -59 -121 -363 -643 -203 206 -36 -29 233 9 398 58 368 40 64 -494 -423 -784 -448 -743 -810 -347 167 -170 170 624 304 213 357 -30 -66 -596 -809 -543 -355 35 276 196 145 105 92 200 494 655 534 356 15 -336 -115 -169 -520 -98 324 225 381 -45 -183 -294 -108 361 385 -20 527 393 277 287 318 -121 -267 -680 -900 -380 -759 -327 -19 54 111 -100 -179 228 891 285 245 390 127 92 174 -438 -103 -296 -85 -111 122 -150 -81 -272 -55 -405 81 -260 -36 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