File name: Pandora227s1_NakhonPathom_20250827_L2Fit_fwvt1c3d20240531p1-8.txt File generation date: 20250827T173048.6Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c3p1-8 Local principal investigator: Darunee Promchot Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 227 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora227_OF_v2d20220531.txt Instrument calibration file used: Pandora227s1_CF_v3d20240531.txt Level 1 file used: Pandora227s1_NakhonPathom_20250827_L1_smca1c3d20240531p1-8.txt Full location name: Silpakorn University, Sanam Chandra palace campus (Nakhon Pathom) Short location name: NakhonPathom Country of location: Thailand Location latitude [deg]: 13.8200 Location longitude [deg]: 100.0400 Location altitude [m]: 72 Local noon date: 20250827 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on lab session 1 First and last pixel inside fitting window: 1617 1766 Nominal wavelengths inside fitting window [nm]: 492.0832 492.2045 492.3258 492.4471 492.5683 492.6895 492.8107 492.9319 493.0531 493.1742 493.2954 493.4165 493.5376 493.6587 493.7798 493.9008 494.0218 494.1429 494.2639 494.3848 494.5058 494.6268 494.7477 494.8686 494.9895 495.1104 495.2313 495.3521 495.4729 495.5937 495.7145 495.8353 495.9561 496.0768 496.1975 496.3183 496.4389 496.5596 496.6803 496.8009 496.9215 497.0422 497.1627 497.2833 497.4039 497.5244 497.6449 497.7654 497.8859 498.0064 498.1268 498.2473 498.3677 498.4881 498.6085 498.7288 498.8492 498.9695 499.0898 499.2101 499.3304 499.4507 499.5709 499.6911 499.8113 499.9315 500.0517 500.1719 500.2920 500.4121 500.5322 500.6523 500.7724 500.8925 501.0125 501.1325 501.2525 501.3725 501.4925 501.6124 501.7323 501.8523 501.9722 502.0920 502.2119 502.3317 502.4516 502.5714 502.6912 502.8110 502.9307 503.0505 503.1702 503.2899 503.4096 503.5292 503.6489 503.7685 503.8882 504.0078 504.1273 504.2469 504.3665 504.4860 504.6055 504.7250 504.8445 504.9639 505.0834 505.2028 505.3222 505.4416 505.5610 505.6803 505.7997 505.9190 506.0383 506.1576 506.2769 506.3961 506.5154 506.6346 506.7538 506.8730 506.9921 507.1113 507.2304 507.3495 507.4686 507.5877 507.7067 507.8258 507.9448 508.0638 508.1828 508.3018 508.4207 508.5397 508.6586 508.7775 508.8964 509.0152 509.1341 509.2529 509.3717 509.4905 509.6093 509.7281 509.8468 509.9655 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250827T000532.4Z 9370.003848 58 1 19.85 2 77.04 82.67 120.03 92.89 0.00 1 0.00 1 0 22 3.610e-03 3.566e-03 8.568e-04 8.546e-04 1.188283e+04 6.103653e+01 7.753409e+02 -6.000000e+00 2.061779e+02 294.59 -2.00 20.00 -2.00 505.31 0.00e+00 7.454273e-04 2.405295e-05 5.933102e-05 -6.000000e+00 1.036586e-04 294.59 -2.00 20.00 -2.00 500.49 0.00e+00 5.492693e-01 1.666177e-02 6.525620e-02 -6.000000e+00 7.023683e-02 227.24 -2.00 3.09 -2.00 502.07 0.00e+00 4.339 0.000 489.00 513.00 1 5.9676e+00 1.2803e-03 8.4011e-03 -6.0000e+00 5.4080e-03 7.7574e-03 3.2588e-04 1.6487e-03 -6.0000e+00 1.3998e-03 2.5383e-03 -1.8717e-05 7.5292e-05 6.8064e-05 -6.0000e+00 3.4427e-04 2.3233e-02 -7.9778e-05 12 1 1 12 17 1 31.04 24.01 0.91 0.02323 0.02310 12 6 1 4 0 1526.460 26.62 20.01 24.01 31.45 2.0 1014.38 -736 -704 -284 19 323 487 565 465 471 385 246 -166 -314 -436 -488 -289 -107 53 114 69 195 234 283 310 529 376 480 -11 -544 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-293 134 -9 9 239 512 488 681 353 307 67 69 -6 171 363 210 206 323 335 249 83 -242 -254 -346 -429 -409 18 53 179 108 271 218 360 245 387 221 -64 -107 -489 -416 -555 SQ 20250827T001020.8Z 9370.007185 61 1 50.82 2 75.88 82.92 118.91 93.15 0.00 1 0.00 1 0 22 3.613e-03 3.581e-03 9.902e-04 9.873e-04 1.186372e+04 7.008873e+01 7.762374e+02 -6.000000e+00 2.063826e+02 294.59 -2.00 20.00 -2.00 505.34 0.00e+00 7.581533e-04 2.793301e-05 5.771818e-05 -6.000000e+00 1.037626e-04 294.59 -2.00 20.00 -2.00 500.52 0.00e+00 4.658873e-01 1.921445e-02 6.699097e-02 -6.000000e+00 7.031017e-02 227.24 -2.00 3.09 -2.00 502.11 0.00e+00 4.006 0.000 489.00 513.00 1 6.9108e+00 1.4776e-03 8.1438e-03 -6.0000e+00 5.4136e-03 3.1767e-03 3.7413e-04 1.6853e-03 -6.0000e+00 1.4013e-03 1.0420e-03 1.4054e-04 8.7082e-05 6.8213e-05 -6.0000e+00 3.4463e-04 2.3214e-02 -8.2872e-05 11 1 0 11 16 0 97.92 24.02 0.96 0.02321 0.02419 23 4 1 4 0 2209.160 26.62 19.99 24.02 31.57 2.1 1015.56 -831 -699 -449 93 248 482 593 283 149 317 274 -61 -213 -461 -582 -405 -44 238 283 284 122 243 258 339 361 426 554 40 -423 -408 -133 -367 -15 145 276 -38 2 1 -269 -216 -141 47 17 337 442 636 371 279 -274 -384 -741 -985 -550 -464 -217 -139 159 -73 42 154 257 613 348 276 133 260 12 -80 -334 -401 -238 -223 105 38 -127 -333 -60 -307 -518 -156 -396 -92 -363 -248 -73 -197 -204 -9 261 33 391 583 611 411 533 490 59 -464 -792 -611 -695 -549 -178 -48 99 -318 -421 -634 -170 -146 -56 -112 238 340 478 488 659 451 432 115 -74 148 129 280 370 80 322 335 310 -74 51 -323 -245 -433 -531 124 99 109 -35 224 -131 37 263 189 430 237 -292 -707 -430 -391 -804 -690 -459 97 248 490 613 295 154 324 276 -61 -225 -482 -609 -427 -44 242 295 298 128 256 271 358 383 451 581 42 -427 -400 -128 -359 -15 150 294 -41 2 1 -277 -221 -144 48 18 355 470 673 390 290 -279 -381 -716 -935 -558 -444 -213 -141 164 -76 44 158 265 634 361 285 136 261 12 -79 -324 -385 -228 -215 101 38 -126 -325 -58 -289 -483 -145 -370 -87 -345 -238 -71 -192 -199 -9 252 32 381 574 604 401 505 449 57 -436 -732 -559 -644 -525 -165 -47 98 -317 -416 -620 -165 -144 -55 -113 240 342 483 497 678 467 443 116 -73 144 125 273 362 78 316 328 303 -72 49 -306 -230 -407 -504 119 97 109 -36 230 -136 39 275 197 445 242 -294 -701 -422 -385 SQ 20250827T002942.9Z 9370.020636 68 1 51.06 2 71.21 83.93 114.39 94.22 0.00 1 0.00 1 0 22 3.401e-03 3.367e-03 9.432e-04 9.402e-04 9.378480e+03 6.566319e+01 6.246389e+02 -6.000000e+00 1.942596e+02 294.59 -2.00 20.00 -2.00 505.34 0.00e+00 5.540695e-04 2.653890e-05 4.421797e-05 -6.000000e+00 9.766833e-05 294.59 -2.00 20.00 -2.00 500.51 0.00e+00 3.543750e-01 1.827939e-02 5.348359e-02 -6.000000e+00 6.618217e-02 227.24 -2.00 3.09 -2.00 502.11 0.00e+00 3.065 0.000 489.00 513.00 1 6.9819e+00 1.4059e-03 6.3682e-03 -6.0000e+00 5.0958e-03 7.1421e-03 3.5710e-04 1.3460e-03 -6.0000e+00 1.3191e-03 1.1252e-03 1.3029e-04 8.4451e-05 5.1410e-05 -6.0000e+00 3.2441e-04 2.0278e-02 -6.6709e-05 11 1 0 11 16 0 82.23 24.02 0.94 0.02028 0.02118 24 4 1 4 0 2127.330 26.62 20.00 24.02 32.51 2.0 1021.82 -706 -619 -419 -5 249 507 583 194 305 195 179 -45 -187 -458 -471 -269 -141 244 53 210 140 139 259 298 559 428 343 -43 -243 -333 -315 -430 -119 233 113 40 -2 -100 -275 -123 -155 277 -100 381 519 518 326 235 -154 -274 -752 -752 -685 -556 -277 -3 171 61 33 7 204 562 158 449 12 148 65 -96 -327 -481 -132 -260 12 29 172 -131 -180 -419 -464 -158 -404 -308 -173 -224 -52 -157 -116 -129 55 176 450 558 409 580 487 353 29 -459 -642 -725 -491 -395 -225 -154 -272 -208 -349 -473 -221 -7 28 -79 208 249 356 565 858 335 125 34 -4 187 349 398 191 102 227 371 241 37 -48 -238 -435 -538 -611 170 -70 38 67 272 -24 174 216 430 264 -3 -150 -464 -438 -501 -692 -618 -432 -5 252 521 610 205 320 202 183 -45 -185 -450 -462 -266 -141 251 55 223 149 148 275 317 596 456 364 -45 -246 -328 -307 -424 -120 243 121 42 -3 -105 -285 -127 -160 287 -106 403 553 551 344 245 -158 -273 -729 -714 -647 -534 -273 -3 176 64 34 7 211 582 164 465 12 150 65 -94 -317 -462 -126 -250 12 28 170 -128 -172 -395 -434 -147 -379 -291 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