File name: Pandora69s1_NewBrunswickNJ_20200809_L2Fit_fout2c1d20200727p1-8.txt File generation date: 20250604T165919.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c1p1-8 Local principal investigator: Nader Abuhassan Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 69 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora69_OF_v3d20190730.txt Instrument calibration file used: Pandora69s1_CF_v1d20200727.txt Level 1 file used: Pandora69s1_NewBrunswickNJ_20200809_L1_smca1c1d20200727p1-8.txt Full location name: Rutgers NJDEP (USEPA AQS ID 34-023-0011) Short location name: NewBrunswickNJ Country of location: USA Location latitude [deg]: 40.4622 Location longitude [deg]: -74.4294 Location altitude [m]: 19 Local noon date: 20200809 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: None First and last pixel inside fitting window: 259 400 Nominal wavelengths inside fitting window [nm]: 305.1058 305.2474 305.3889 305.5305 305.6719 305.8134 305.9548 306.0962 306.2376 306.3789 306.5202 306.6615 306.8027 306.9440 307.0852 307.2263 307.3675 307.5086 307.6497 307.7907 307.9318 308.0728 308.2138 308.3548 308.4957 308.6366 308.7775 308.9184 309.0593 309.2001 309.3409 309.4817 309.6224 309.7632 309.9039 310.0446 310.1853 310.3260 310.4666 310.6072 310.7478 310.8884 311.0290 311.1695 311.3100 311.4505 311.5910 311.7315 311.8719 312.0124 312.1528 312.2932 312.4336 312.5739 312.7143 312.8546 312.9949 313.1352 313.2755 313.4158 313.5560 313.6962 313.8364 313.9766 314.1168 314.2570 314.3971 314.5373 314.6774 314.8175 314.9576 315.0977 315.2377 315.3778 315.5178 315.6578 315.7978 315.9378 316.0778 316.2178 316.3577 316.4976 316.6375 316.7774 316.9173 317.0572 317.1971 317.3369 317.4768 317.6166 317.7564 317.8962 318.0360 318.1757 318.3155 318.4552 318.5950 318.7347 318.8744 319.0141 319.1537 319.2934 319.4331 319.5727 319.7123 319.8519 319.9915 320.1311 320.2707 320.4103 320.5498 320.6893 320.8289 320.9684 321.1079 321.2474 321.3868 321.5263 321.6657 321.8052 321.9446 322.0840 322.2234 322.3628 322.5022 322.6416 322.7809 322.9203 323.0596 323.1989 323.3382 323.4775 323.6168 323.7560 323.8953 324.0345 324.1738 324.3130 324.4522 324.5914 324.7306 324.8698 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SU 20200809T112029.8Z 7526.472567 584 1 49.57 2 76.70 80.66 46.02 226.25 0.00 1 0.00 1 0 25 3.391e-01 2.284e-02 3.649e-01 1.857e-02 5.529351e-01 1.046513e-02 6.273581e-03 -6.000000e+00 2.026344e-01 231.96 -2.00 3.50 -2.00 320.92 0.00e+00 4.918081e-04 3.556863e-03 4.306447e-04 -6.000000e+00 9.916077e-03 290.39 -2.00 20.00 -2.00 320.60 0.00e+00 4.236 0.001 302.00 328.00 3 4.9753e+00 3.1024e-02 5.1826e-02 -6.0000e+00 5.1437e-01 8.4634e-02 3.8749e-02 2.9879e-02 -6.0000e+00 5.5831e-01 -1.4966e-01 4.0616e-02 1.5759e-02 -6.0000e+00 3.2461e-01 6.5204e-02 2.0867e-02 4.9825e-03 -6.0000e+00 1.3722e-01 2.8635e-05 -1.2515e-03 6.0898e-04 6.4693e-05 -6.0000e+00 9.7998e-03 3.2191e-04 -1.1163e-04 12 8 8 10 0 0 99.86 22.77 0.93 0.00032 -0.00908 13 3 1 5 0 3812.610 25.90 19.98 22.77 30.47 12.1 1007.00 -141343 900000 -14676 -134921 900000 -100902 -100512 -23179 900000 900000 900000 900000 -42867 900000 -2331 -36892 8150 68643 61018 900000 -78803 46825 -35747 112012 82165 -20766 131743 70642 17972 -34108 82070 65928 -780 16453 20085 -44943 -4423 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2781 -1548 1229 1220 -2428 3245 14470 -3750 -436 -1090 -218 -895 1059 796 -1821 -851 525 -1425 -3601 -1401 -2042 113 1232 -235 718 2677 -3530 -109 -1471 -1317 -1112 -987 3376 -160 2858 3570 3568 487 -656 103 2186 -31 -765 270 -672 633 -1014 2276 564 -1777 -451 -2261 SU 20200809T114050.0Z 7526.486690 670 1 49.98 2 72.87 83.82 48.84 231.83 0.00 1 0.00 1 0 17 1.083e-01 6.779e-03 1.031e-01 5.723e-03 4.462061e-01 3.057520e-03 5.131076e-03 -6.000000e+00 6.438351e-02 231.96 -2.00 3.50 -2.00 320.14 0.00e+00 1.462129e-03 8.523458e-04 2.536692e-04 -6.000000e+00 2.530826e-03 290.39 -2.00 20.00 -2.00 319.83 0.00e+00 3.343 0.001 302.00 328.00 3 4.1481e+00 8.6524e-03 4.1073e-02 -6.0000e+00 1.6280e-01 1.2793e-02 1.0182e-02 2.3730e-02 -6.0000e+00 1.7629e-01 -1.9812e-03 9.3608e-03 1.2216e-02 -6.0000e+00 1.0324e-01 -5.5963e-03 4.9663e-03 3.7375e-03 -6.0000e+00 4.3141e-02 1.7284e-04 -7.0304e-04 1.8169e-04 4.4041e-05 -6.0000e+00 3.0783e-03 -6.6303e-04 -4.4374e-05 11 8 0 10 0 0 99.98 22.76 0.27 -0.00066 -0.00595 54 11 1 5 0 925.430 25.90 20.01 22.76 30.34 12.1 1006.42 -50756 1405 -52903 -27825 13471 -38125 -50258 30502 -18271 -8984 21201 25029 -16562 -32563 1681 2447 -3460 6499 -13855 2579 -2737 18687 2420 22361 443 -7343 -13029 228 -7122 5686 3967 -3688 10116 1428 -3987 -5381 -442 -3287 -2876 1288 -2930 1022 -392 -875 -3566 1587 -400 -2027 2754 -1997 1957 -1019 2470 302 1531 377 60 -344 683 1529 2330 2131 2758 2234 2914 407 -1228 596 493 1208 362 -510 -1541 -323 688 1265 952 174 -375 432 -1262 -1309 -2116 -1174 -534 -928 202 249 499 708 1182 39 351 -93 186 299 1460 -224 -145 44 -1053 -272 -1002 79 -896 -634 -867 -925 162 -156 113 -54 473 -901 968 370 312 457 495 -289 -63 76 -291 230 163 771 1239 674 402 -473 41 -380 222 62 -67 -545 382 128 -96 2 -200 -314 -1105 21 -1335 -532 167 -760 -1213 404 -409 -195 364 463 -524 -1412 63 102 -163 301 -815 136 -154 876 139 1147 29 -542 -1010 15 -492 376 300 -334 886 137 -385 -549 -49 -438 -458 227 -583 206 -83 -189 -798 342 -88 -459 609 -488 504 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1.1633e-01 3.7867e-05 -3.9891e-03 5.5140e-04 4.4102e-05 -6.0000e+00 8.2897e-03 5.1927e-04 -5.4008e-04 12 8 8 10 0 0 99.96 22.77 0.69 0.00052 -0.02946 16 3 1 5 0 3200.290 25.90 20.01 22.77 30.39 12.1 1006.81 -96636 900000 -39092 36987 -44988 -27923 -63089 -130010 113120 -61870 72002 4706 900000 39963 64361 114629 -18157 -5781 74694 2105 24212 52796 -24469 72884 5226 21285 52614 -39834 70859 -328 58338 28679 35844 3790 33605 -6715 20165 8938 -9974 9067 14549 24227 -4447 17964 2377 -627 3410 2570 23398 -6652 8272 -1553 14806 7470 6678 -1345 -6824 13584 -771 5092 -688 3566 2784 -471 -1723 1153 -8594 720 5620 -3311 7778 -1261 4246 -3794 2427 -4043 -7645 -1251 -6184 -486 -1129 867 -6198 -2978 -4521 -2934 359 -4066 2537 2749 2949 -3674 2021 -4851 2191 -1243 12084 -50 -2265 -178 -1118 1623 -2086 2610 -4435 498 -1622 -281 780 -87 1230 685 2552 -117 273 -580 245 1005 -335 2065 -2657 -86 367 2037 -115 880 1564 1142 737 -1816 227 -1672 2067 -509 425 -227 -965 -739 -1247 -146 38 1903 -5659 900000 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