File name: Pandora64s1_NewHavenCT_20240428_L2Fit_fout2c4d20190911p1-8.txt File generation date: 20240429T095556.5Z Data description: Level 2 spectral fitting results file Data file version: fout2c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora64_OF_v3d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20240428_L1_smca1c4d20190911p1-8.txt Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20240428 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 249 390 Nominal wavelengths inside fitting window [nm]: 305.1279 305.2688 305.4097 305.5506 305.6915 305.8324 305.9732 306.1141 306.2549 306.3958 306.5366 306.6774 306.8182 306.9590 307.0997 307.2405 307.3812 307.5220 307.6627 307.8034 307.9441 308.0848 308.2255 308.3662 308.5068 308.6475 308.7881 308.9287 309.0693 309.2099 309.3505 309.4911 309.6316 309.7722 309.9127 310.0533 310.1938 310.3343 310.4748 310.6153 310.7557 310.8962 311.0366 311.1771 311.3175 311.4579 311.5983 311.7387 311.8791 312.0195 312.1598 312.3002 312.4405 312.5808 312.7211 312.8614 313.0017 313.1420 313.2822 313.4225 313.5627 313.7030 313.8432 313.9834 314.1236 314.2638 314.4039 314.5441 314.6842 314.8244 314.9645 315.1046 315.2447 315.3848 315.5249 315.6649 315.8050 315.9450 316.0851 316.2251 316.3651 316.5051 316.6451 316.7850 316.9250 317.0649 317.2049 317.3448 317.4847 317.6246 317.7645 317.9044 318.0442 318.1841 318.3239 318.4638 318.6036 318.7434 318.8832 319.0230 319.1628 319.3025 319.4423 319.5820 319.7217 319.8614 320.0011 320.1408 320.2805 320.4202 320.5598 320.6995 320.8391 320.9787 321.1183 321.2579 321.3975 321.5371 321.6766 321.8162 321.9557 322.0953 322.2348 322.3743 322.5138 322.6532 322.7927 322.9322 323.0716 323.2110 323.3504 323.4899 323.6292 323.7686 323.9080 324.0474 324.1867 324.3260 324.4654 324.6047 324.7440 324.8833 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 77: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 80: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 83: Atmospheric variability [%], 999=no atmospheric variability was determined Column 84: Wavelength effective temperature [°C], 999=no effective temperature given Column 85: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 86: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 87: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 88: Number of bright count cycles Column 89: Number of dark count cycles Column 90: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 91: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 92: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 93: Integration time [ms] Column 94: Temperature at electronics board [°C], 999=no temperature signal Column 95: Spectrometer control temperature [°C], 999=no temperature signal Column 96: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 97: Temperature in head sensor [°C], 999=no temperature signal Column 98: Humidity in head sensor [%], -9=no humidity signal Column 99: Pressure in head sensor [hPa], -9=no pressure signal Columns 100-241: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 242-383: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240428T122844.5Z 8884.519960 278 1 47.89 2 61.92 95.36 89.80 229.19 0.00 1 0.00 1 0 25 2.012e-02 9.678e-03 8.565e-03 2.225e-03 3.162165e-01 1.193320e-03 3.772372e-03 -6.000000e+00 1.224749e-02 229.73 -2.00 3.52 -2.00 317.60 0.00e+00 3.731230e-04 1.863059e-04 2.503864e-04 -6.000000e+00 5.339990e-04 281.63 -2.00 20.00 -2.00 316.90 0.00e+00 2.114 0.000 302.00 328.00 3 5.1522e+00 3.1706e-03 2.6931e-02 -6.0000e+00 3.0574e-02 5.4231e-02 3.5560e-03 1.6432e-02 -6.0000e+00 3.3019e-02 -7.9464e-03 2.1900e-03 8.0471e-03 -6.0000e+00 1.9624e-02 -4.0688e-03 1.0878e-03 2.2455e-03 -6.0000e+00 8.2961e-03 2.4116e-04 -2.8303e-04 6.9246e-05 2.6845e-05 -6.0000e+00 5.9863e-04 -9.7381e-04 -1.5295e-05 12 8 8 10 0 0 99.99 21.45 -0.07 -0.00097 -0.00310 21 5 1 5 0 2280.360 25.90 20.00 21.45 17.42 38.2 1000.95 -5984 -3123 -5036 -1320 -5186 757 -3425 -4745 -2807 2088 -9529 -2263 -5634 109 -856 910 -2360 2153 -1249 3371 1970 4341 3905 1672 644 1680 -1477 -1516 -794 -5503 1449 1440 3649 -313 -4690 -2653 -1192 -2248 1216 277 -497 -701 -262 -2074 -60 162 -227 -527 -808 -2494 1924 1306 1540 137 770 285 1645 44 976 153 674 1190 2151 2797 1659 -1830 -1155 -1110 606 1659 815 953 323 408 -428 -1134 -516 -2591 -1450 -346 -1424 -1913 -2254 -1631 -666 -278 346 772 1496 871 17 609 -1457 -498 474 576 62 1292 732 -368 -976 -1790 -2487 243 238 -1291 -676 8 -286 477 1464 458 358 181 -671 -578 486 -375 548 825 -150 47 873 112 930 214 -1524 882 894 304 113 -469 -940 -253 678 -46 -130 646 490 -554 -170 -1035 -527 -283 -469 -108 -409 57 -294 -461 -293 215 -1105 -268 -752 16 -143 162 -453 418 -260 698 416 896 852 395 160 426 -377 -364 -183 -1375 368 392 1058 -93 -1383 -808 -382 -857 532 132 -254 -374 -143 -1154 -33 88 -122 -281 -431 -1402 1114 772 959 91 520 198 1143 31 665 106 489 887 1706 2309 1337 -1422 -867 -841 499 1440 756 902 300 360 -365 -881 -392 -2000 -1160 -295 -1362 -1934 -2407 -1758 -766 -323 417 937 1778 1022 19 638 -1469 -508 521 671 77 1667 969 -474 -1230 -2195 -3006 293 307 -1688 -928 11 -420 713 2258 706 546 257 -933 -777 661 -538 803 1249 -230 70 1255 159 1262 291 -2041 1208 1269 444 174 -741 -1487 -417 1137 -80 -232 1124 873 -961 -284 -1747 SS 20240428T152933.4Z 8884.645526 399 1 11.87 2 31.92 141.49 118.41 255.02 0.00 1 0.00 1 0 17 1.249e-02 8.758e-03 2.635e-03 1.854e-03 1.783607e-01 1.013627e-03 2.168521e-03 -6.000000e+00 7.611652e-03 229.74 -2.00 3.52 -2.00 314.80 0.00e+00 4.479860e-04 8.287052e-05 1.881245e-05 -6.000000e+00 3.317568e-04 281.65 -2.00 20.00 -2.00 314.25 0.00e+00 1.177 0.000 302.00 328.00 3 4.6928e+00 2.6012e-03 1.5058e-02 -6.0000e+00 1.9002e-02 4.0809e-02 2.8707e-03 9.2212e-03 -6.0000e+00 2.0516e-02 -5.5046e-03 1.6416e-03 4.5019e-03 -6.0000e+00 1.2192e-02 -1.5778e-03 7.1511e-04 1.2779e-03 -6.0000e+00 5.1594e-03 1.2292e-03 7.9899e-05 5.6740e-05 1.8170e-05 -6.0000e+00 3.7169e-04 -4.9518e-03 5.1286e-05 12 9 1 12 1 1 78.87 21.60 0.16 -0.00495 -0.00435 8 9 1 5 0 1318.390 26.00 20.00 21.60 21.06 38.5 1018.44 1663 -963 1234 -3078 -7488 -1367 273 910 2408 -192 -2840 -1393 456 551 1603 -464 83 970 1059 1583 1599 -505 1366 365 837 1424 348 -941 -757 -35 1903 442 2214 568 -4183 -2137 -1429 -1546 -147 -52 -1059 -1401 -335 -1202 -639 -196 -868 174 -926 -300 893 848 752 1330 53 807 1085 932 111 888 53 973 1135 2299 315 -1470 -479 -1344 778 1693 393 600 190 980 -24 -780 -732 -1998 -485 -401 -1160 -741 -1904 -1902 -295 -526 -30 152 1044 765 304 592 -891 -216 712 -183 143 1239 818 -336 -668 -1297 -1705 53 438 -1310 -255 -715 -27 24 744 357 96 -293 -107 -286 631 -232 641 587 -120 -3 599 284 1194 677 -886 606 1037 288 428 -499 -598 -340 319 -2 -528 341 333 -303 -107 -1052 586 -338 446 -1042 -2411 -413 87 316 888 -74 -1090 -522 186 248 744 -232 42 501 558 810 863 -261 716 201 473 813 194 -519 -394 -18 1005 246 1221 311 -2368 -1170 -865 -1035 -109 -41 -852 -1167 -282 -1015 -534 -161 -724 139 -729 -237 736 701 649 1187 47 713 964 819 97 781 50 917 1128 2324 308 -1391 -427 -1245 739 1694 405 632 197 1006 -24 -734 -635 -1703 -437 -383 -1175 -780 -2124 -2155 -342 -646 -37 190 1277 916 349 643 -943 -227 760 -206 169 1515 1021 -407 -793 -1504 -1958 61 544 -1657 -336 -947 -36 33 1056 497 131 -382 -133 -344 767 -288 847 786 -164 -4 776 362 1490 808 -1070 743 1288 364 560 -666 -790 -468 447 -2 -765 500 484 -432 -154 -1477 SS 20240428T153414.3Z 8884.648776 402 1 12.12 2 31.38 143.40 119.22 255.65 0.00 1 0.00 1 0 17 1.192e-02 8.728e-03 2.113e-03 1.474e-03 1.767049e-01 8.034384e-04 2.164381e-03 -6.000000e+00 7.260857e-03 229.74 -2.00 3.52 -2.00 314.84 0.00e+00 2.741994e-04 6.670416e-05 3.107112e-05 -6.000000e+00 3.164764e-04 281.65 -2.00 20.00 -2.00 314.29 0.00e+00 1.171 0.000 302.00 328.00 3 4.3205e+00 2.0638e-03 1.4969e-02 -6.0000e+00 1.8126e-02 3.3779e-02 2.2779e-03 9.1594e-03 -6.0000e+00 1.9570e-02 -5.1134e-03 1.3025e-03 4.4785e-03 -6.0000e+00 1.1631e-02 -1.7954e-03 5.6913e-04 1.2488e-03 -6.0000e+00 4.9213e-03 1.8081e-03 3.4962e-05 4.5190e-05 1.8309e-05 -6.0000e+00 3.5458e-04 -4.1105e-03 6.9318e-05 12 9 1 12 1 1 99.95 21.61 0.15 -0.00411 -0.00385 16 16 1 5 0 712.890 26.00 20.00 21.61 21.39 38.4 1020.03 1061 -647 573 -2788 -6398 -1559 -2 910 1762 783 -3078 -1553 314 -75 1595 402 -292 578 833 1581 1670 -279 1012 932 987 838 711 -996 -667 373 1461 239 2367 -7 -4248 -2477 -1632 -1102 124 -39 -1190 -1267 -440 -1290 -258 202 -831 -134 -601 -788 1272 1274 813 1196 424 1119 1095 685 -192 577 358 1313 1197 2128 810 -1487 -589 -1698 1040 1573 303 249 -305 586 140 -722 -1101 -1861 -526 -327 -1074 -955 -1821 -1778 -809 -543 56 -11 1146 425 414 448 -905 -247 695 254 -13 1210 546 -359 -370 -1266 -1686 38 445 -1273 -208 -584 -306 396 1044 308 389 262 -347 -331 305 -435 638 670 43 -259 793 -82 1131 790 -890 581 1061 322 501 -428 -535 -475 602 -233 -656 305 278 -409 -101 -893 353 -225 195 -956 -2069 -479 -1 322 615 281 -1113 -582 128 -34 725 195 -144 293 429 834 880 -149 550 528 537 464 409 -538 -339 187 757 130 1342 -4 -2348 -1402 -952 -744 91 -30 -986 -1023 -360 -1058 -221 170 -680 -106 -463 -614 1025 1076 679 1036 374 998 984 611 -171 515 335 1231 1186 2151 787 -1423 -531 -1529 996 1572 308 260 -314 603 133 -658 -984 -1626 -459 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