File name: Pandora64s1_NewHavenCT_20250509_L2Fit_fwvt1c4d20190911p1-8.txt File generation date: 20250513T150225.4Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Lukas Valin Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 64 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora64_OF_v3d20190516.txt Instrument calibration file used: Pandora64s1_CF_v4d20190911.txt Level 1 file used: Pandora64s1_NewHavenCT_20250509_L1_smca1c4d20190911p1-8.txt Full location name: New Haven - Criscuolo Park CTDEEP (USEPA AQS ID 34-017-0006) Short location name: NewHavenCT Country of location: USA Location latitude [deg]: 41.3014 Location longitude [deg]: -72.9029 Location altitude [m]: 4 Local noon date: 20250509 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Mod WL cal slit func 9 First and last pixel inside fitting window: 1670 1819 Nominal wavelengths inside fitting window [nm]: 492.0778 492.1987 492.3196 492.4405 492.5613 492.6822 492.8030 492.9238 493.0446 493.1654 493.2861 493.4069 493.5276 493.6483 493.7690 493.8897 494.0104 494.1310 494.2516 494.3722 494.4928 494.6134 494.7340 494.8545 494.9751 495.0956 495.2161 495.3365 495.4570 495.5774 495.6979 495.8183 495.9387 496.0591 496.1794 496.2998 496.4201 496.5404 496.6607 496.7810 496.9012 497.0215 497.1417 497.2619 497.3821 497.5023 497.6225 497.7426 497.8627 497.9829 498.1029 498.2230 498.3431 498.4631 498.5832 498.7032 498.8232 498.9431 499.0631 499.1830 499.3030 499.4229 499.5428 499.6627 499.7825 499.9024 500.0222 500.1420 500.2618 500.3816 500.5013 500.6211 500.7408 500.8605 500.9802 501.0999 501.2195 501.3392 501.4588 501.5784 501.6980 501.8176 501.9371 502.0567 502.1762 502.2957 502.4152 502.5347 502.6541 502.7736 502.8930 503.0124 503.1318 503.2512 503.3705 503.4899 503.6092 503.7285 503.8478 503.9670 504.0863 504.2055 504.3247 504.4439 504.5631 504.6823 504.8015 504.9206 505.0397 505.1588 505.2779 505.3970 505.5160 505.6350 505.7541 505.8731 505.9920 506.1110 506.2299 506.3489 506.4678 506.5867 506.7056 506.8244 506.9433 507.0621 507.1809 507.2997 507.4185 507.5372 507.6560 507.7747 507.8934 508.0121 508.1308 508.2494 508.3681 508.4867 508.6053 508.7239 508.8425 508.9610 509.0796 509.1981 509.3166 509.4351 509.5535 509.6720 509.7904 509.9088 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-250: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 251-400: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250509T115117.2Z 9260.493949 216 1 18.19 2 66.82 86.60 131.39 302.71 0.00 1 0.00 1 0 22 3.226e-03 3.211e-03 1.405e-03 1.403e-03 4.059006e+03 8.942579e+01 2.863905e+02 -6.000000e+00 1.834952e+02 282.73 -2.00 20.00 -2.00 505.27 0.00e+00 7.420506e-04 3.900221e-05 4.470926e-05 -6.000000e+00 9.142475e-05 282.73 -2.00 20.00 -2.00 500.47 0.00e+00 1.886365e-01 2.817095e-02 2.958215e-02 -6.000000e+00 6.508401e-02 230.58 -2.00 3.52 -2.00 502.06 0.00e+00 2.521 0.000 489.00 513.00 1 7.3581e+00 2.1583e-03 4.5252e-03 -6.0000e+00 4.9906e-03 -7.5451e-03 5.5442e-04 7.2597e-04 -6.0000e+00 1.2934e-03 8.4513e-04 1.1218e-03 1.4201e-04 3.3234e-05 -6.0000e+00 3.3850e-04 9.9731e-03 -1.6537e-04 12 1 1 12 1 1 99.99 20.95 1.16 0.00997 0.01775 6 5 1 4 0 2597.450 25.47 20.00 20.95 20.98 40.1 1017.58 -357 -288 -66 417 44 -215 367 447 39 131 -275 241 -34 -164 14 -77 -211 -102 489 266 54 234 50 295 663 499 262 492 206 -859 -547 -296 -489 -250 444 97 -330 6 31 -229 134 64 211 200 192 272 119 -170 -3 -241 -533 -605 -797 -741 68 189 112 7 26 -25 14 410 195 431 -17 -168 -103 -35 339 -423 -109 -212 -54 -375 230 336 -139 -488 -331 -245 -316 174 -109 -479 -343 137 -168 -169 62 30 21 -76 257 509 28 -68 120 -169 151 -520 -429 -525 -862 84 112 -97 -496 -170 -694 -194 -117 161 158 305 584 214 495 815 233 318 350 385 -293 362 474 39 172 215 -341 308 194 40 -276 266 -272 -298 242 55 -7 136 180 195 8 104 -176 317 -121 -215 -462 -394 -346 -283 -65 421 44 -222 382 469 41 136 -283 244 -34 -167 14 -79 -212 -105 512 274 56 242 52 306 689 519 271 503 212 -865 -543 -295 -495 -254 460 102 -344 6 32 -232 136 66 217 207 200 285 124 -176 -3 -245 -529 -588 -770 -720 67 192 113 7 27 -26 14 419 200 442 -18 -170 -102 -36 337 -417 -107 -208 -53 -376 225 335 -138 -476 -320 -235 -305 169 -107 -473 -334 134 -165 -166 61 30 21 -77 260 516 28 -67 116 -164 142 -486 -401 -498 -822 82 110 -95 -487 -169 -687 -192 -114 159 158 308 591 218 507 834 238 320 347 376 -286 353 464 38 169 211 -334 300 188 39 -268 255 -262 -289 234 54 -7 137 178 194 8 104 -177 315 -119 -211 -448 -381 SQ 20250509T121600.0Z 9260.511111 230 1 5.53 2 62.18 90.62 135.09 309.03 0.00 1 0.00 1 0 15 3.201e-03 3.187e-03 1.013e-03 1.012e-03 3.262144e+03 6.297333e+01 2.316677e+02 -6.000000e+00 1.821810e+02 282.73 -2.00 20.00 -2.00 505.27 0.00e+00 7.159196e-04 2.811776e-05 4.408230e-05 -6.000000e+00 9.072305e-05 282.73 -2.00 20.00 -2.00 500.51 0.00e+00 1.078997e-01 2.026401e-02 2.465622e-02 -6.000000e+00 6.456048e-02 230.58 -2.00 3.52 -2.00 502.09 0.00e+00 2.132 0.000 489.00 513.00 1 5.6495e+00 1.5529e-03 3.8438e-03 -6.0000e+00 4.9511e-03 -1.1542e-02 3.9941e-04 5.9860e-04 -6.0000e+00 1.2817e-03 4.9728e-03 -1.6063e-04 1.0279e-04 2.9390e-05 -6.0000e+00 3.3510e-04 5.4431e-03 -7.1879e-05 12 1 1 12 1 1 75.25 20.95 1.20 0.00544 0.00433 7 17 1 4 0 690.520 25.47 20.00 20.95 21.66 40.2 1020.97 -389 -286 -183 517 58 -41 378 357 389 -46 -65 394 12 -78 -116 -58 -342 -49 541 235 84 402 212 132 380 144 242 545 216 -965 -497 -110 -599 95 655 108 -338 4 -7 -235 -17 155 55 161 365 131 88 -108 -93 -24 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54 -234 202 -92 25 44 32 -490 -377 -378 SQ 20250509T122007.7Z 9260.513978 233 1 48.61 2 61.41 91.31 135.67 310.16 0.00 1 0.00 1 0 15 2.845e-03 2.833e-03 6.603e-04 6.595e-04 3.428048e+03 4.132943e+01 2.398742e+02 -6.000000e+00 1.619099e+02 282.73 -2.00 20.00 -2.00 505.27 0.00e+00 6.786059e-04 1.832750e-05 4.138288e-05 -6.000000e+00 8.063961e-05 282.73 -2.00 20.00 -2.00 500.49 0.00e+00 1.498665e-01 1.321454e-02 2.622234e-02 -6.000000e+00 5.739985e-02 230.58 -2.00 3.52 -2.00 502.08 0.00e+00 2.079 0.000 489.00 513.00 1 7.0695e+00 1.0121e-03 3.8385e-03 -6.0000e+00 4.4016e-03 -9.8086e-03 2.6080e-04 6.2862e-04 -6.0000e+00 1.1400e-03 1.2075e-03 3.5859e-04 6.7052e-05 2.9219e-05 -6.0000e+00 2.9831e-04 7.5538e-03 -1.1196e-04 10 0 0 10 0 0 99.74 20.95 1.23 0.00755 0.01004 27 6 1 4 0 1800.010 25.47 20.00 20.95 21.66 40.4 1021.12 -271 -208 -277 402 62 -86 332 337 314 -96 -62 249 178 -209 -56 -14 -219 189 534 319 -10 161 89 79 375 298 219 516 219 -885 -347 40 -532 -139 519 29 -391 -147 24 -184 1 158 93 55 216 130 -2 -139 9 56 -388 -491 -607 -675 -267 144 234 -80 -96 -71 -70 260 211 366 104 27 -137 74 292 -102 -229 -63 -232 -177 226 49 -297 -475 -179 -423 -294 -41 -155 -543 -120 89 -104 -57 -159 -139 -206 -132 481 390 -30 -167 78 -81 -80 -428 -337 -373 -667 -184 103 -142 -110 -262 -590 -220 177 277 194 399 294 198 432 478 329 202 274 189 -199 449 579 188 165 266 -254 354 379 -96 -83 264 -320 -210 310 269 51 195 58 -48 -24 -40 -3 57 17 -315 -448 -341 -259 -201 -276 401 63 -88 343 351 326 -98 -63 256 180 -210 -56 -14 -223 192 552 334 -11 170 94 82 387 307 230 536 222 -880 -350 40 -532 -143 533 30 -404 -150 25 -190 1 163 94 57 224 135 -2 -141 9 56 -380 -484 -593 -665 -262 145 239 -81 -98 -72 -71 264 215 371 105 27 -138 74 286 -99 -221 -62 -227 -175 224 48 -290 -458 -175 -413 -281 -40 -150 -532 -119 89 -104 -57 -159 -136 -203 -132 483 392 -30 -164 77 -78 -75 -409 -321 -352 -648 -180 103 -143 -110 -259 -579 -217 176 280 193 400 296 201 440 487 334 202 270 189 -197 446 577 188 161 266 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