File name: Pandora236s1_NewLondonCT_20250607_L2Fit_fwvt1c4d20220606p1-8.txt File generation date: 20250608T045408.1Z Data description: Level 2 spectral fitting results file Data file version: fwvt1c4p1-8 Local principal investigator: Brooke S.Stutzman Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 236 Spectrometer number: 1 Processing software version used: BlickP v1.8.75 Instrument operation file used: Pandora236_OF_v3d20220107.txt Instrument calibration file used: Pandora236s1_CF_v4d20220606.txt Level 1 file used: Pandora236s1_NewLondonCT_20250607_L1_smca1c4d20220606p1-8.txt Full location name: United States Coast Guard Academy Short location name: NewLondonCT Country of location: United States Location latitude [deg]: 41.3758 Location longitude [deg]: -72.1004 Location altitude [m]: 30 Local noon date: 20250607 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are dark map for dark correction (replaced by immediate dark method), latency correction, matrix method stray light correction (replaced by simple method) Data caveats: Modification of session 3 "1.8 field calibration all gases" change in SO2 First and last pixel inside fitting window: 1613 1761 Nominal wavelengths inside fitting window [nm]: 492.1147 492.2362 492.3576 492.4791 492.6005 492.7219 492.8433 492.9647 493.0860 493.2073 493.3287 493.4500 493.5712 493.6925 493.8138 493.9350 494.0562 494.1774 494.2986 494.4198 494.5409 494.6620 494.7832 494.9043 495.0253 495.1464 495.2675 495.3885 495.5095 495.6305 495.7515 495.8724 495.9934 496.1143 496.2352 496.3561 496.4770 496.5979 496.7187 496.8395 496.9603 497.0811 497.2019 497.3227 497.4434 497.5641 497.6849 497.8055 497.9262 498.0469 498.1675 498.2881 498.4088 498.5293 498.6499 498.7705 498.8910 499.0115 499.1320 499.2525 499.3730 499.4935 499.6139 499.7343 499.8547 499.9751 500.0955 500.2158 500.3362 500.4565 500.5768 500.6971 500.8173 500.9376 501.0578 501.1780 501.2982 501.4184 501.5386 501.6587 501.7788 501.8990 502.0190 502.1391 502.2592 502.3792 502.4993 502.6193 502.7393 502.8592 502.9792 503.0991 503.2191 503.3390 503.4589 503.5787 503.6986 503.8184 503.9382 504.0581 504.1778 504.2976 504.4174 504.5371 504.6568 504.7765 504.8962 505.0159 505.1355 505.2551 505.3748 505.4944 505.6139 505.7335 505.8530 505.9726 506.0921 506.2116 506.3311 506.4505 506.5700 506.6894 506.8088 506.9282 507.0476 507.1669 507.2863 507.4056 507.5249 507.6442 507.7634 507.8827 508.0019 508.1211 508.2403 508.3595 508.4787 508.5978 508.7170 508.8361 508.9552 509.0743 509.1933 509.3124 509.4314 509.5504 509.6694 509.7884 509.9073 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Water vapor slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of water vapor slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of water vapor slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Water vapor effective temperature [K] Column 28: Independent uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of water vapor effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective water vapor fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for water vapor [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Nitrogen dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of nitrogen dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of nitrogen dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Nitrogen dioxide effective temperature [K] Column 39: Independent uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of nitrogen dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective nitrogen dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for nitrogen dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 45: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 46: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 47: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 48: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 49: Ozone effective temperature [K] Column 50: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 51: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 52: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 53: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 54: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 55: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 56: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 57: Lower limit used for wavelength scaling [nm] Column 58: Upper limit used for wavelength scaling [nm] Column 59: Order of smoothing polynomial Column 60: Smoothing polynomial coefficient, order 0 Column 61: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 62: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 63: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 64: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 65: Smoothing polynomial coefficient, order 1 Column 66: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 67: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 68: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 69: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 70: Mean value of measured data inside fitting window [same units as measurements] Column 71: Wavelength change polynomial coefficient, order 0 Column 72: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 76: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 77: L1 based wavelength change coefficient, order 1, -9=no L1 wavelength change determination Column 78: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 79: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 80: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 81: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 82: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 83: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 84: Atmospheric variability [%], 999=no atmospheric variability was determined Column 85: Wavelength effective temperature [°C], 999=no effective temperature given Column 86: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 87: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 88: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 89: Number of bright count cycles Column 90: Number of dark count cycles Column 91: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 92: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 93: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 94: Integration time [ms] Column 95: Temperature at electronics board [°C], 999=no temperature signal Column 96: Spectrometer control temperature [°C], 999=no temperature signal Column 97: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 98: Temperature in head sensor [°C], 999=no temperature signal Column 99: Humidity in head sensor [%], -9=no humidity signal Column 100: Pressure in head sensor [hPa], -9=no pressure signal Columns 101-249: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 250-398: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SQ 20250607T161604.7Z 9289.677832 370 1 9.35 2 19.69 158.11 141.98 61.38 0.00 1 0.00 1 0 15 3.509e-03 3.511e-03 2.336e-03 2.329e-03 4.396614e+03 1.524492e+02 3.163644e+02 -6.000000e+00 2.031453e+02 285.53 -2.00 20.00 -2.00 505.23 0.00e+00 3.662974e-04 6.523855e-05 2.893874e-05 -6.000000e+00 1.004185e-04 285.53 -2.00 20.00 -2.00 500.35 0.00e+00 -1.013586e-01 4.728449e-02 2.768369e-02 -6.000000e+00 7.120499e-02 232.46 -2.00 3.52 -2.00 501.95 0.00e+00 1.062 0.000 489.00 513.00 1 7.2957e+00 3.6286e-03 2.9010e-03 -6.0000e+00 5.4658e-03 1.0137e-02 9.3332e-04 6.9437e-04 -6.0000e+00 1.4148e-03 1.1388e-03 9.0192e-04 2.4854e-04 3.5830e-05 -6.0000e+00 3.9205e-04 -1.3301e-03 -9.1453e-07 12 1 1 12 1 1 999.00 24.42 1.32 -0.00133 0.00493 2 3 1 4 0 3114.970 26.62 20.00 24.42 30.12 17.9 1072.69 -322 -129 -673 -223 407 490 175 470 486 377 176 -254 51 -328 -236 17 133 -180 49 -170 395 589 141 300 434 -19 -174 -754 -55 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66 504 68 -74 299 -66 216 185 261 426 -66 478 -242 -114 429 686 604 -438 -602 -480 -94 591 10 22 -146 -139 241 409 384 466 -437 -294 -149 -267 -246 SQ 20250607T165651.5Z 9289.706152 398 1 51.09 2 18.66 186.82 135.34 71.39 0.00 1 0.00 1 0 15 2.838e-03 2.821e-03 1.526e-03 1.519e-03 4.910839e+03 1.017030e+02 3.438248e+02 -6.000000e+00 1.642769e+02 285.53 -2.00 20.00 -2.00 505.23 0.00e+00 2.988446e-04 4.257248e-05 2.727927e-05 -6.000000e+00 8.120293e-05 285.53 -2.00 20.00 -2.00 500.25 0.00e+00 -4.563355e-02 3.101020e-02 3.208624e-02 -6.000000e+00 5.757334e-02 232.46 -2.00 3.52 -2.00 501.86 0.00e+00 1.055 0.000 489.00 513.00 1 7.8345e+00 2.3802e-03 3.1859e-03 -6.0000e+00 4.4195e-03 7.5858e-03 6.1143e-04 7.8485e-04 -6.0000e+00 1.1437e-03 6.6229e-04 4.2785e-04 1.6208e-04 3.4797e-05 -6.0000e+00 3.1703e-04 -1.3910e-03 9.5981e-06 10 0 0 10 0 0 98.63 24.43 1.26 -0.00139 0.00158 14 2 1 4 0 3649.160 26.62 20.00 24.43 31.90 17.9 1083.67 6 317 -332 97 -186 91 361 392 488 433 131 -414 -22 102 -310 -228 50 21 43 176 171 329 230 216 427 450 -90 -138 -156 -305 -249 -328 -187 252 -443 -252 141 -67 -233 121 77 108 25 10 35 95 -19 -211 -59 -233 -459 -303 -489 -606 -404 -225 60 -165 39 581 229 193 171 21 -25 673 66 -464 -95 -248 9 490 39 -164 -306 -524 -70 139 -368 51 -139 -331 -174 126 -629 -287 -95 74 78 221 398 517 182 428 -270 -125 -86 -333 -276 -218 0 -150 -62 -392 -528 -99 -134 -93 -96 -512 245 -2 116 81 -106 241 134 55 197 95 257 303 654 511 134 270 242 223 181 -81 85 56 -807 -130 238 423 -317 -319 187 71 199 -83 516 -250 -154 -273 -35 102 280 5 316 -335 100 -198 99 395 420 531 466 140 -436 -23 105 -318 -236 52 22 46 190 184 355 249 235 463 486 -96 -146 -160 -307 -255 -332 -194 267 -481 -273 151 -71 -245 126 81 114 26 11 36 100 -20 -222 -61 -233 -448 -291 -472 -596 -407 -231 63 -169 40 590 234 198 175 21 -25 679 66 -461 -93 -241 8 477 38 -163 -298 -516 -68 133 -351 48 -133 -320 -166 121 -613 -280 -93 72 76 217 393 515 183 423 -264 -119 -80 -310 -252 -199 0 -139 -59 -388 -517 -96 -132 -91 -94 -496 239 -2 116 81 -107 243 135 56 196 93 247 289 622 488 129 258 232 213 172 -77 79 51 -741 -119 215 387 -298 -304 179 68 193 -81 503 -245 -150 -267 -34 96 261 SQ 20250607T171916.9Z 9289.721724 408 1 39.04 2 19.72 202.25 131.51 76.13 0.00 1 0.00 1 0 15 2.247e-03 2.241e-03 8.114e-04 8.082e-04 3.357950e+03 5.206762e+01 2.343487e+02 -6.000000e+00 1.300955e+02 285.53 -2.00 20.00 -2.00 505.22 0.00e+00 3.060394e-04 2.259678e-05 2.324671e-05 -6.000000e+00 6.430775e-05 285.53 -2.00 20.00 -2.00 500.31 0.00e+00 -1.151533e-01 1.641125e-02 2.339211e-02 -6.000000e+00 4.559744e-02 232.46 -2.00 3.52 -2.00 501.91 0.00e+00 1.062 0.000 489.00 513.00 1 6.7764e+00 1.2590e-03 2.5523e-03 -6.0000e+00 3.5002e-03 1.3853e-02 3.2473e-04 5.6164e-04 -6.0000e+00 9.0592e-04 1.9217e-03 3.8425e-04 8.7061e-05 2.5137e-05 -6.0000e+00 2.5107e-04 -1.6459e-03 4.3796e-06 12 1 1 12 1 1 99.94 24.44 1.30 -0.00165 0.00102 25 6 1 4 0 1501.410 26.62 20.00 24.44 31.96 18.2 1085.48 -439 75 -271 -126 86 293 160 264 365 217 221 13 -149 115 -297 -221 -123 -2 11 -70 209 240 216 213 239 258 60 -251 -281 -157 -7 -33 247 143 -416 -240 228 -119 94 31 10 105 287 2 192 -150 204 64 -74 -261 -363 -335 -420 -396 -358 -329 -234 -64 42 482 431 265 120 184 92 203 -121 -227 -253 -109 -121 -37 35 -41 -88 -155 -94 12 -94 -120 -229 -337 -31 -86 -131 -184 -357 43 -26 143 227 394 407 -12 98 -29 -190 -233 -310 -176 -215 -42 86 -181 -398 -343 -251 65 40 14 57 -87 -160 -2 55 311 192 199 314 156 46 135 209 357 190 270 395 295 394 57 49 -222 -250 -333 185 199 -166 -309 70 -199 144 469 289 86 -222 -217 -274 -202 -167 -430 74 -279 -133 89 309 171 283 388 228 229 14 -150 120 -310 -223 -126 -2 12 -75 225 258 232 230 259 277 64 -264 -287 -156 -7 -33 254 151 -449 -259 242 -126 98 32 10 111 304 2 206 -161 215 66 -75 -259 -352 -320 -402 -385 -358 -337 -243 -67 44 498 446 276 125 191 95 204 -121 -223 -246 -105 -116 -36 34 -41 -87 -152 -90 12 -88 -114 -218 -323 -30 -84 -129 -182 -355 43 -26 143 229 401 398 -12 98 -28 -181 -218 -285 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