File name: Pandora85s1_NewOrleansLA-XULA_20240615_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240709T182436.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240615_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240615 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240615T120503.0Z 8932.503507 95 1 54.43 2 77.78 69.94 151.00 333.16 0.00 1 0.00 1 0 25 3.159e-01 1.741e-02 1.069e-01 2.817e-03 5.626441e-01 1.539051e-03 6.960926e-03 -6.000000e+00 1.877385e-01 230.99 -2.00 3.24 -2.00 320.30 0.00e+00 1.327237e-03 5.809570e-04 4.777397e-03 -6.000000e+00 9.349597e-03 292.65 -2.00 20.00 -2.00 319.54 0.00e+00 4.584 0.001 302.00 328.00 3 2.9384e+00 4.7309e-03 5.7812e-02 -6.0000e+00 4.6882e-01 -7.0731e-02 5.9718e-03 4.0631e-02 -6.0000e+00 5.0705e-01 -2.5054e-03 5.4325e-03 1.4680e-02 -6.0000e+00 3.0103e-01 -1.1707e-02 2.7817e-03 5.3845e-03 -6.0000e+00 1.3166e-01 1.6727e-04 2.4496e-04 8.0417e-05 5.5867e-05 -6.0000e+00 8.7588e-03 1.2247e-02 12 8 8 10 0 0 76.33 27.30 0.92 0.01225 0.01409 46 5 1 5 0 1183.120 34.50 20.01 27.30 35.58 11.9 1013.05 900000 900000 900000 -134931 -120086 900000 900000 -85318 5612 -114332 900000 59108 -2991 -5261 17119 900000 -87650 -45822 900000 -14486 82327 -10387 49154 18332 32863 34474 58657 187015 -1247 64712 -27547 11476 -28512 -27655 -13311 -16782 -11270 -30570 3580 14834 1626 13010 17872 -1348 4216 -11885 22168 7998 -6443 9911 -744 14873 1257 809 10498 6483 -712 -3909 -1120 1850 -5715 8503 1462 -1433 4742 4619 -4330 -1605 342 3004 3963 3882 815 199 1419 -3506 -4652 -3481 -6246 -528 -3612 268 -559 -3802 -657 3076 650 67 2809 -206 2654 -721 -1109 -2075 69 -3291 -1002 268 -573 268 -60 -1640 -2655 -2245 -1640 -2121 -453 -359 596 2926 1211 3322 2680 1892 -987 -549 -1320 -1104 -295 304 791 83 1780 798 -381 -524 -2414 -126 -353 332 -398 -726 -585 -265 -990 -53 -104 559 956 727 876 -1117 -587 900000 900000 900000 900000 -2153 -1527 900000 900000 -1006 31 -2320 900000 243 -28 -63 207 900000 -4159 -1583 900000 -429 971 -313 849 473 802 889 1239 1077 -45 1260 -1549 516 -2221 -2374 -978 -1238 -850 -3278 335 1518 219 1706 2368 -225 675 -2285 3095 1314 -1265 1737 -144 3043 295 208 2636 1775 -218 -1255 -344 541 -1835 2553 529 -602 2018 1944 -1925 -699 156 1398 2069 2170 477 114 745 -1749 -2335 -1672 -3001 -278 -2300 189 -409 -3064 -548 2660 568 61 2544 -189 2400 -626 -911 -1692 59 -3072 -1052 297 -716 343 -74 -1892 -3010 -2453 -1771 -2472 -546 -461 764 4029 1768 5107 4220 2923 -1485 -776 -1959 -1588 -446 486 1290 134 2734 1201 -556 -783 -3534 -178 -544 537 -674 -1328 -1062 -503 -1919 -110 -223 1210 2097 1573 1805 -2230 -1174 900000 SS 20240615T121028.0Z 8932.507269 98 1 54.03 2 76.68 70.53 151.51 335.65 0.00 1 0.00 1 0 17 3.415e-01 1.516e-02 1.306e-01 2.241e-03 5.243598e-01 1.187521e-03 6.218019e-03 -6.000000e+00 1.992483e-01 230.99 -2.00 3.24 -2.00 319.88 0.00e+00 -3.408640e-05 3.915826e-04 3.390474e-03 -6.000000e+00 9.565039e-03 292.65 -2.00 20.00 -2.00 319.08 0.00e+00 4.231 0.001 302.00 328.00 3 2.8836e+00 3.5173e-03 5.1797e-02 -6.0000e+00 4.9760e-01 -7.7778e-02 4.2996e-03 3.3774e-02 -6.0000e+00 5.3665e-01 5.9939e-03 3.6390e-03 1.3057e-02 -6.0000e+00 3.2052e-01 -1.3132e-02 1.8973e-03 4.7262e-03 -6.0000e+00 1.4018e-01 2.5791e-04 1.2958e-04 6.3194e-05 4.0083e-05 -6.0000e+00 9.3716e-03 1.2090e-02 12 8 8 10 0 0 97.96 27.34 0.84 0.01209 0.01306 57 6 1 5 0 947.760 34.50 20.01 27.34 35.89 11.9 1013.05 900000 -67898 900000 -102572 -54879 183240 241807 -95056 4028 -97914 900000 -35985 -22861 -19390 -13968 18357 -55499 -31714 120352 -1924 18834 -8089 7061 5387 423 11046 29880 -9048 -11869 24497 -14312 3181 -17462 -12360 -9040 -17750 -12681 -21444 -893 6634 12955 5303 9730 -2147 3709 -6622 10718 3341 -3551 3384 619 8306 1913 1645 5501 4079 484 -2209 -1975 1108 -3406 4097 2141 810 3798 3013 -3805 2795 210 1890 2454 2813 972 -30 545 -2721 -2972 -4715 -4920 -1075 -3586 -1204 -1417 -2971 -955 2063 732 861 2357 442 2059 -227 -1230 -2315 -111 -2992 -483 832 -99 68 -485 -1689 -2572 -1641 -886 -1794 -308 -321 603 2344 1350 2688 2469 1521 -451 -735 -1206 -818 -67 169 618 504 1371 790 45 -199 -2252 -404 -635 -249 -176 -631 -851 -236 -608 -61 -128 990 652 799 660 -766 -793 900000 900000 -935 900000 -2196 -671 400 528 -2077 38 -2845 900000 -637 -425 -432 -363 413 -2946 -1455 1315 -76 634 -360 281 239 22 545 1273 -557 -718 1049 -1019 222 -1720 -1280 -893 -1850 -1355 -2928 -122 1026 2171 947 1757 -452 744 -1498 2069 704 -823 763 156 2164 583 547 1888 1486 190 -830 -795 424 -1385 1658 905 389 1897 1490 -1933 1330 109 1099 1482 1812 649 -20 331 -1545 -1667 -2589 -2847 -636 -2540 -885 -1161 -2638 -886 1869 713 874 2397 451 1944 -203 -1118 -2078 -104 -3033 -513 995 -126 88 -610 -2108 -2947 -1806 -1033 -2268 -379 -420 838 3309 2010 4228 3947 2382 -680 -1103 -1779 -1238 -101 271 1013 816 2134 1200 70 -296 -3287 -572 -972 -401 -296 -1139 -1534 -441 -1162 -123 -269 2024 1360 1640 1354 -1518 -1577 900000 SS 20240615T121629.7Z 8932.511455 101 1 53.83 2 75.45 71.17 152.02 338.51 0.00 1 0.00 1 0 17 1.349e-01 1.295e-02 2.999e-02 1.393e-03 4.848715e-01 7.251689e-04 5.740169e-03 -6.000000e+00 7.870396e-02 230.99 -2.00 3.24 -2.00 319.38 0.00e+00 1.797672e-03 2.009179e-04 2.695312e-03 -6.000000e+00 3.559011e-03 292.65 -2.00 20.00 -2.00 318.54 0.00e+00 3.895 0.001 302.00 328.00 3 2.3628e+00 2.0651e-03 4.6717e-02 -6.0000e+00 1.9643e-01 -6.6622e-02 2.4376e-03 2.7901e-02 -6.0000e+00 2.1166e-01 -4.4766e-03 1.8830e-03 1.2407e-02 -6.0000e+00 1.2653e-01 -7.8211e-03 1.0008e-03 3.1861e-03 -6.0000e+00 5.4626e-02 6.1773e-04 1.3804e-04 3.8654e-05 3.8783e-05 -6.0000e+00 3.6487e-03 1.1427e-02 12 8 8 10 0 0 77.86 27.40 0.53 0.01143 0.01246 108 12 1 5 0 498.350 34.50 20.01 27.40 36.13 11.9 1013.09 58169 -49037 22396 -43481 -64878 12555 -4222 -61294 -33910 -57154 -1153 -24099 -11284 -16893 -16772 8741 -24272 -18389 19394 -5767 4081 -13071 -170 440 -2139 164 6018 7875 -8460 560 -11451 -3090 -8006 -7284 -7382 -9294 -9065 -13016 -1748 2903 3583 2058 3839 142 1151 -557 4381 1383 -1631 989 825 4356 1723 1738 3026 2937 1145 -129 -478 -255 -1010 2594 2515 2867 3352 1699 -1548 328 -202 1777 1922 2228 1229 622 84 -1839 -3302 -4555 -4228 -2582 -2882 -1043 -1512 -2543 -1043 445 676 1030 2144 1386 1209 -174 -1599 -2248 -1040 -2094 -749 666 516 32 -576 -1548 -2551 -1956 -900 -1392 -541 -594 301 1703 1925 2436 2048 1436 -245 -751 -781 -327 192 562 433 659 1172 668 86 -60 -1524 -417 -373 -149 -357 -908 -895 -604 -329 71 -12 687 748 465 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