File name: Pandora85s1_NewOrleansLA-XULA_20240617_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240709T182346.8Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240617_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240617 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240617T131118.3Z 8934.549518 159 1 53.84 2 64.11 76.72 158.48 312.35 0.00 1 0.00 1 0 17 1.858e-02 1.148e-02 2.090e-03 8.988e-04 2.719502e-01 4.649808e-04 3.069567e-03 -6.000000e+00 1.084162e-02 230.94 -2.00 3.24 -2.00 316.55 0.00e+00 1.130233e-03 5.698740e-05 4.225087e-04 -6.000000e+00 4.903502e-04 292.76 -2.00 20.00 -2.00 315.69 0.00e+00 2.276 0.000 302.00 328.00 3 3.3702e+00 1.2164e-03 2.6189e-02 -6.0000e+00 2.7055e-02 4.2420e-03 1.3549e-03 1.3028e-02 -6.0000e+00 2.9146e-02 5.5931e-03 7.8990e-04 6.2772e-03 -6.0000e+00 1.7426e-02 -1.1319e-02 3.7936e-04 1.7344e-03 -6.0000e+00 7.5306e-03 1.3550e-03 3.1379e-04 2.5374e-05 1.9978e-05 -6.0000e+00 5.0227e-04 6.9175e-03 12 8 8 10 0 0 99.90 27.12 0.52 0.00692 0.00928 76 8 1 5 0 708.330 34.50 20.00 27.12 33.90 13.8 1013.80 3545 -427 2208 -4264 -7477 -3426 -1908 -5368 -1052 -3081 -3042 -5565 -3536 -1600 -171 2887 -1818 438 3259 2419 2388 200 1823 871 161 1216 1473 -398 -2215 -772 -729 216 715 -1031 -4212 -5095 -4890 -3229 -611 814 275 73 956 619 777 592 1313 243 -709 -387 469 1323 938 1726 1345 1188 1170 294 28 13 393 1484 2240 2672 1922 270 -880 -1401 -790 841 1120 1480 819 874 391 -804 -2111 -3103 -3171 -2220 -2243 -1490 -2028 -2712 -1254 -290 152 772 1375 933 1033 9 -1064 -1606 -1053 -1275 -459 661 682 170 -292 -1335 -2039 -1541 -832 -1265 -533 -266 273 1431 1576 2224 1743 1317 21 -480 -523 -49 310 816 714 876 888 477 88 90 -1055 -370 -455 -112 -197 -685 -745 -603 -314 -49 -23 667 586 359 168 -631 -945 900000 506 -72 379 -757 -1224 -500 -283 -913 -192 -619 -615 -1061 -730 -374 -45 775 -545 134 1013 788 802 68 619 314 57 446 550 -145 -825 -274 -271 80 287 -448 -1820 -2100 -2125 -1472 -304 447 170 45 611 405 509 390 851 156 -450 -243 303 914 656 1266 1035 889 894 228 21 10 301 1191 1851 2379 1702 242 -732 -1176 -672 749 1064 1428 811 845 376 -746 -1780 -2571 -2630 -1916 -2095 -1474 -2106 -2981 -1382 -328 182 923 1665 1118 1206 10 -1151 -1705 -1083 -1435 -526 805 876 224 -369 -1642 -2425 -1792 -1031 -1633 -689 -360 372 2048 2322 3274 2547 1892 29 -641 -675 -65 432 1173 1042 1281 1272 689 121 122 -1379 -482 -596 -157 -285 -1006 -1120 -898 -491 -78 -37 1099 986 601 272 -1027 -1492 900000 SS 20240617T131600.2Z 8934.552780 162 1 9.24 2 63.12 77.19 159.20 314.62 0.00 1 0.00 1 0 17 2.036e-02 1.239e-02 7.148e-03 3.056e-03 2.640151e-01 1.579867e-03 2.958196e-03 -6.000000e+00 1.188077e-02 230.94 -2.00 3.24 -2.00 316.52 0.00e+00 1.150457e-03 1.914041e-04 3.890424e-04 -6.000000e+00 5.372614e-04 292.76 -2.00 20.00 -2.00 315.64 0.00e+00 2.199 0.000 302.00 328.00 3 3.9602e+00 4.1342e-03 2.5316e-02 -6.0000e+00 2.9648e-02 9.0195e-03 4.6087e-03 1.2608e-02 -6.0000e+00 3.1938e-02 1.0748e-02 2.6876e-03 6.0866e-03 -6.0000e+00 1.9096e-02 -1.4970e-02 1.2857e-03 1.7002e-03 -6.0000e+00 8.2537e-03 8.1641e-04 5.1088e-04 8.6449e-05 1.9367e-05 -6.0000e+00 5.5031e-04 5.6856e-03 12 9 9 12 1 1 99.81 27.13 0.47 0.00569 0.00952 6 5 1 5 0 1319.050 34.25 20.00 27.13 34.15 13.8 1013.66 3833 -624 -338 -7863 -5002 2073 1581 -3411 315 -3142 -4715 -6101 -4741 -566 1742 4749 -3364 -625 2707 1556 4076 427 4117 1080 -272 668 1067 -645 -2803 -1260 -1055 1549 164 -1210 -5577 -4676 -5076 -4261 -1166 1215 787 397 1124 689 1873 4 1493 61 -576 -326 -325 1375 971 1311 1036 1543 357 158 -467 466 609 1835 1834 2054 2575 98 -1232 -792 -497 1001 955 1386 582 653 481 -1623 -2262 -2832 -3539 -1158 -2846 -2186 -2125 -2286 -1342 158 -34 824 2009 1027 1332 422 -988 -1552 -1005 -1281 -345 846 857 289 -561 -1393 -2286 -1944 -777 -1406 -612 -145 184 1475 1709 2121 1808 1016 221 123 -861 -179 -193 939 665 594 1386 494 -136 140 -1378 -375 -544 39 -565 -699 -496 -748 -229 -1 -98 808 941 326 389 -670 -1230 900000 544 -104 -59 -1438 -793 284 225 -564 56 -626 -958 -1259 -1065 -129 446 1329 -1003 -188 826 499 1314 142 1331 378 -102 258 419 -247 -1020 -436 -380 589 64 -508 -2349 -1845 -2124 -2021 -596 677 495 249 727 457 1230 3 978 40 -369 -206 -214 954 679 966 800 1209 274 122 -358 369 489 1461 1589 1823 2347 87 -1068 -653 -416 875 892 1373 592 649 453 -1492 -1977 -2303 -2894 -1019 -2740 -2220 -2239 -2426 -1494 179 -41 988 2426 1232 1559 476 -1079 -1594 -1043 -1389 -395 1024 1089 377 -732 -1703 -2717 -2265 -961 -1808 -785 -195 258 2082 2472 3172 2678 1435 301 161 -1141 -240 -265 1324 985 852 2007 700 -192 187 -1848 -481 -728 53 -803 -1037 -724 -1121 -346 -1 -158 1327 1576 545 628 -1093 -1953 900000 SS 20240617T132055.9Z 8934.556203 165 1 53.64 2 62.07 77.69 159.92 317.15 0.00 1 0.00 1 0 17 1.808e-02 1.157e-02 2.169e-03 1.015e-03 2.552643e-01 5.247273e-04 2.875589e-03 -6.000000e+00 1.054646e-02 230.94 -2.00 3.24 -2.00 316.31 0.00e+00 1.093937e-03 6.096371e-05 3.524090e-04 -6.000000e+00 4.770437e-04 292.76 -2.00 20.00 -2.00 315.47 0.00e+00 2.124 0.000 302.00 328.00 3 3.7744e+00 1.3698e-03 2.4475e-02 -6.0000e+00 2.6318e-02 5.9827e-03 1.5234e-03 1.2215e-02 -6.0000e+00 2.8353e-02 5.8437e-03 8.8232e-04 5.8869e-03 -6.0000e+00 1.6952e-02 -1.1511e-02 4.1898e-04 1.6280e-03 -6.0000e+00 7.3249e-03 1.0755e-03 1.8606e-04 2.8624e-05 1.9025e-05 -6.0000e+00 4.8866e-04 7.6697e-03 12 8 8 10 0 0 98.82 27.15 0.55 0.00767 0.00907 55 6 1 5 0 975.110 34.50 20.00 27.15 34.44 13.9 1013.65 4144 -807 2209 -3292 -7422 -2324 -1141 -4415 -2828 -2915 -2544 -5830 -3415 -1517 606 2610 844 -83 2813 1913 2140 150 2148 1124 194 1355 855 -6 -2121 -150 -1223 365 213 -1080 -4314 -5208 -4412 -3959 -511 489 388 233 1296 485 861 -222 932 265 -560 -131 329 1423 960 1777 1470 1110 1131 74 -41 -190 300 1851 2207 2452 1945 366 -1128 -1385 -596 785 1037 1398 799 646 371 -873 -2064 -3295 -2817 -1975 -2295 -1579 -2082 -2674 -1365 -130 216 728 1410 1100 918 115 -1240 -1404 -976 -1282 -469 756 775 107 -386 -1237 -2189 -1459 -764 -1314 -437 -149 198 1364 1555 2128 1820 1478 50 -430 -418 -64 209 707 582 619 1055 537 164 156 -1140 -326 -438 -237 -267 -684 -806 -617 -396 134 -80 852 531 357 227 -581 -1021 900000 680 -156 435 -608 -1387 -382 -191 -844 -596 -607 -529 -1252 -787 -394 177 774 271 -28 957 682 784 56 788 406 74 535 346 -2 -787 -56 -451 143 90 -494 -1958 -2252 -1997 -1901 -265 281 250 150 857 330 584 -152 626 175 -364 -89 218 999 682 1321 1144 885 919 58 -33 -153 245 1494 1930 2199 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