File name: Pandora85s1_NewOrleansLA-XULA_20240626_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240709T182512.2Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240626_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240626 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240626T115445.4Z 8943.496359 208 1 43.42 2 80.35 68.55 51.21 215.26 0.00 1 0.00 1 0 17 4.121e-01 2.312e-02 1.975e-01 4.534e-03 6.615220e-01 2.590720e-03 8.135528e-03 -6.000000e+00 2.464190e-01 230.68 -2.00 3.24 -2.00 320.94 0.00e+00 -2.019609e-03 1.219790e-03 7.082390e-03 -6.000000e+00 1.447765e-02 293.24 -2.00 20.00 -2.00 320.27 0.00e+00 5.686 0.002 302.00 328.00 3 2.3972e+00 8.7441e-03 7.5502e-02 -6.0000e+00 6.1453e-01 3.0756e-02 1.1918e-02 5.9839e-02 -6.0000e+00 6.6575e-01 -1.5242e-01 1.1730e-02 1.6789e-02 -6.0000e+00 3.9656e-01 6.0206e-02 5.7391e-03 1.2303e-02 -6.0000e+00 1.7515e-01 9.1241e-05 -2.7524e-04 1.2982e-04 5.5376e-05 -6.0000e+00 1.1760e-02 2.5042e-03 12 9 9 12 1 1 99.14 27.07 0.95 0.00250 0.00044 28 4 1 5 0 1497.180 34.25 20.00 27.07 33.17 15.0 1013.01 900000 900000 900000 900000 -184557 900000 -111266 -65625 900000 -176076 900000 -99908 76527 900000 -20740 900000 -84945 -96666 900000 900000 35298 -57735 900000 900000 -25005 900000 900000 900000 -39334 205646 -24681 23643 -30606 -29731 -82411 -65531 -1772 -19560 61774 6933 32808 57512 72602 5321 11501 22323 58289 51333 -8636 11044 -8910 52189 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-858 -798 186 -157 -304 -1988 -508 -1441 -1940 -3666 -1477 949 88 4734 2593 5346 4511 2144 -1641 -1614 -2529 -1318 754 -2034 1170 1333 4338 1226 460 -500 -4704 738 -3193 984 -576 -955 -1592 -146 -451 584 -742 968 1109 834 4001 -3371 -1178 900000 SS 20240626T120744.3Z 8943.505374 216 1 48.84 2 77.72 69.98 52.81 218.61 0.00 1 0.00 1 0 17 3.476e-01 2.711e-02 1.626e-01 4.714e-03 5.555128e-01 2.531449e-03 6.230791e-03 -6.000000e+00 2.029820e-01 230.68 -2.00 3.24 -2.00 320.39 0.00e+00 -4.214871e-03 9.911958e-04 3.862139e-03 -6.000000e+00 1.097379e-02 293.24 -2.00 20.00 -2.00 319.57 0.00e+00 4.564 0.001 302.00 328.00 3 3.6951e+00 7.9767e-03 5.7556e-02 -6.0000e+00 5.0684e-01 1.4010e-02 9.9728e-03 4.1472e-02 -6.0000e+00 5.5193e-01 -8.9922e-02 8.6190e-03 1.3012e-02 -6.0000e+00 3.2761e-01 3.8636e-02 4.3879e-03 9.9293e-03 -6.0000e+00 1.4074e-01 7.9579e-05 -1.5653e-04 1.3699e-04 4.0096e-05 -6.0000e+00 9.8185e-03 -1.0805e-03 12 9 9 12 1 1 99.53 27.11 0.80 -0.00108 -0.00226 14 2 1 5 0 3255.760 34.25 20.00 27.11 33.36 15.1 1012.94 900000 900000 900000 27317 900000 900000 -68312 -139685 900000 -24777 900000 -19863 -14164 900000 -23924 900000 -53359 -58025 900000 165657 29525 -31801 131675 67802 -27792 46546 900000 214501 -36831 36755 -23432 15831 -8432 -24270 -52750 -33799 676 -23839 28204 14159 21687 24874 49470 9744 9861 -14491 39770 27379 -7843 12050 -6945 28865 6872 -4304 19661 10017 5019 2535 52 -7859 -10694 13485 2323 -7181 981 15153 -7443 9738 -6043 4537 8211 6785 303 -7082 4865 -7433 -3760 -2403 -2045 2252 -6913 -4947 -141 -4938 578 3495 -1799 -631 4023 -5335 4034 -787 -718 -4869 4045 -4389 -1435 548 1484 52 245 -1134 -1072 -593 -1215 -3862 -463 499 1410 3504 1480 4307 3850 3562 -1575 -688 -2301 -836 -2881 -1769 826 961 2629 403 80 -468 -3361 -654 -2243 990 764 -381 -405 -62 -1212 -339 -552 542 697 794 1243 -1461 -402 599 900000 900000 900000 125 900000 900000 -846 -3729 900000 -307 900000 -264 -208 900000 -571 900000 -2277 -2822 900000 988 718 -1444 1208 1307 -1556 1345 900000 1181 -2349 1113 -1430 755 -588 -2205 -6341 -3225 49 -2559 2213 1579 2617 3173 5198 1565 1583 -2985 4799 3769 -1572 2062 -1558 5059 1652 -1147 4898 2632 1451 768 16 -2524 -3533 3701 791 -3019 410 5454 -3222 3550 -2722 2093 4157 3753 183 -4100 2553 -3993 -1761 -1060 -937 1130 -4449 -3287 -100 -3938 464 2941 -1567 -567 3512 -5039 3550 -674 -577 -3975 3192 -3926 -1428 611 1703 63 287 -1339 -1148 -606 -1320 -4641 -525 594 1781 4745 2112 6446 5922 5368 -2368 -964 -3184 -1168 -4340 -2805 1314 1504 3921 596 113 -688 -4892 -909 -3391 1514 1290 -656 -732 -117 -2312 -685 -1163 1153 1507 1690 2513 -2878 -794 1160 SS 20240626T121244.6Z 8943.508850 219 1 7.68 2 76.70 70.53 53.46 219.85 0.00 1 0.00 1 0 17 3.030e-01 1.417e-02 1.398e-01 4.910e-03 5.105825e-01 2.580839e-03 5.932342e-03 -6.000000e+00 1.767831e-01 230.68 -2.00 3.24 -2.00 319.54 0.00e+00 1.287404e-03 7.582808e-04 2.666684e-03 -6.000000e+00 8.138614e-03 293.24 -2.00 20.00 -2.00 318.70 0.00e+00 4.238 0.001 302.00 328.00 3 2.4287e+00 7.4228e-03 5.0249e-02 -6.0000e+00 4.4082e-01 -2.5977e-02 8.8813e-03 2.9316e-02 -6.0000e+00 4.7500e-01 -7.9052e-04 7.1893e-03 1.2938e-02 -6.0000e+00 2.8417e-01 -1.3295e-02 3.8080e-03 3.4714e-03 -6.0000e+00 1.2434e-01 3.9592e-04 4.7130e-05 1.3648e-04 4.0875e-05 -6.0000e+00 8.2521e-03 4.6287e-04 12 9 9 12 1 1 18.66 27.11 0.71 0.00046 0.00082 8 7 1 5 0 852.230 34.25 20.01 27.11 33.44 15.0 1012.89 900000 -34347 900000 -26957 48501 300123 -62913 -55298 -31340 -37535 18416 -57013 27839 29299 -47410 74007 -17798 -8715 44807 19734 -6319 702 12556 -2354 -18700 22490 5546 -647 -18529 -10363 -11705 -1692 -14903 391 -19935 -20315 -11193 -12834 8657 1667 7397 3356 5948 2489 -418 -2144 4503 3187 -997 575 -2063 4058 1682 2716 3486 158 3383 -215 1432 -2886 -685 2119 1652 3519 1914 3871 -455 90 -2011 544 3128 2790 1060 869 817 -2495 -2572 -2218 -4091 -1768 -3439 -2972 -2115 -2747 -841 447 -75 1622 2975 -168 1714 -586 -960 -3715 -160 -2378 84 497 1279 -263 449 -1111 -2331 -1875 -562 -1057 -626 -562 954 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