File name: Pandora85s1_NewOrleansLA-XULA_20240627_L2Fit_fout2c2d20230315p1-8.txt File generation date: 20240709T182453.4Z Data description: Level 2 spectral fitting results file Data file version: fout2c2p1-8 Local principal investigator: Morewell Gasseller Network principal investigator: Alexander Cede Instrument type: Pandora Instrument number: 85 Spectrometer number: 1 Processing software version used: BlickP v1.8.59 Instrument operation file used: Pandora85_OF_v3d20231120.txt Instrument calibration file used: Pandora85s1_CF_v2d20240315.txt Level 1 file used: Pandora85s1_NewOrleansLA-XULA_20240627_L1_smca1c2d20230315p1-8.txt Full location name: Xavier University of Louisiana Short location name: NewOrleansLA-XULA Country of location: United States Location latitude [deg]: 29.9643 Location longitude [deg]: -90.1074 Location altitude [m]: 10 Local noon date: 20240627 Notes on s-number (L1 configuration): Corrections NOT applied although requested by the s-number are latency correction, matrix method stray light correction (replaced by simple method) Data caveats: OOB session based on clearance session 1 First and last pixel inside fitting window: 196 339 Nominal wavelengths inside fitting window [nm]: 305.0087 305.1493 305.2899 305.4305 305.5710 305.7116 305.8522 305.9927 306.1332 306.2737 306.4143 306.5547 306.6952 306.8357 306.9762 307.1166 307.2571 307.3975 307.5379 307.6783 307.8187 307.9591 308.0994 308.2398 308.3801 308.5205 308.6608 308.8011 308.9414 309.0817 309.2220 309.3623 309.5025 309.6428 309.7830 309.9232 310.0634 310.2036 310.3438 310.4840 310.6242 310.7643 310.9045 311.0446 311.1847 311.3248 311.4649 311.6050 311.7451 311.8851 312.0252 312.1652 312.3053 312.4453 312.5853 312.7253 312.8653 313.0052 313.1452 313.2851 313.4251 313.5650 313.7049 313.8448 313.9847 314.1246 314.2644 314.4043 314.5442 314.6840 314.8238 314.9636 315.1034 315.2432 315.3830 315.5227 315.6625 315.8022 315.9420 316.0817 316.2214 316.3611 316.5008 316.6404 316.7801 316.9198 317.0594 317.1990 317.3386 317.4782 317.6178 317.7574 317.8970 318.0365 318.1761 318.3156 318.4551 318.5947 318.7342 318.8736 319.0131 319.1526 319.2920 319.4315 319.5709 319.7103 319.8497 319.9891 320.1285 320.2679 320.4073 320.5466 320.6859 320.8253 320.9646 321.1039 321.2432 321.3825 321.5217 321.6610 321.8002 321.9395 322.0787 322.2179 322.3571 322.4963 322.6355 322.7746 322.9138 323.0529 323.1921 323.3312 323.4703 323.6094 323.7485 323.8875 324.0266 324.1656 324.3047 324.4437 324.5827 324.7217 324.8607 324.9997 --------------------------------------------------------------------------------------- Column 1: Two letter code of measurement routine Column 2: UT date and time for center-time of measurement, yyyymmddThhmmssZ (ISO 8601) Column 3: Fractional days since 1-Jan-2000 midnight for center-time of measurement Column 4: Routine count (1 for the first routine of the day, 2 for the second, etc.) Column 5: Repetition count (1 for the first set in the routine, 2 for the second, etc.) Column 6: Total duration of measurement set in seconds Column 7: Data processing type index Column 8: Solar zenith angle for center-time of measurement in degree Column 9: Solar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 10: Lunar zenith angle for center-time of measurement in degree Column 11: Lunar azimuth for center-time of measurement in degree, 0=north, increases clockwise Column 12: Pointing zenith angle in degree, absolute or relative (see next column), 999=tracker not used Column 13: Zenith pointing mode: zenith angle is... 0=absolute, 1=relative to sun, 2=relative to moon Column 14: Pointing azimuth in degree, increases clockwise, absolute (0=north) or relative (see next column), 999=tracker not used Column 15: Azimuth pointing mode: like zenith angle mode but also fixed scattering angles relative to sun (3) or moon (4) Column 16: Fitting result index: 0=no error or warning, 1, 2=warning, >2=error Column 17: Number of function evaluations used, 0=linear fitting or fitting not successful or no fitting done Column 18: rms of unweighted fitting residuals, -9=fitting not successful Column 19: Normalized rms of fitting residuals weighted with independent uncertainty, -9=fitting not successful or no uncertainty used Column 20: Expected rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 21: Expected normalized weighted rms based on independent uncertainty, -9=fitting not successful or no uncertainty given Column 22: Ozone slant column amount [moles per square meter], -9e99=fitting not successful Column 23: Independent uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 24: Structured uncertainty of ozone slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 25: Common uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 26: rms-based uncertainty of ozone slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 27: Ozone effective temperature [K] Column 28: Independent uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 29: Structured uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 30: Common uncertainty of ozone effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 31: Effective ozone fitting wavelength [nm], -9=fitting not successful Column 32: Diffuse correction applied before fitting at effective fitting wavelength for ozone [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 33: Sulfur dioxide slant column amount [moles per square meter], -9e99=fitting not successful Column 34: Independent uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 35: Structured uncertainty of sulfur dioxide slant column amount [moles per square meter], -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 36: Common uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -6=no common uncertainty input was given, -7=not given since method "MEAS" was chosen, -9=spectral fitting not successful Column 37: rms-based uncertainty of sulfur dioxide slant column amount [moles per square meter], -1=cross section is zero in this wavelength range, -3=spectral fitting was done, but no rms-based uncertainty could be retrieved, -9=spectral fitting not successful Column 38: Sulfur dioxide effective temperature [K] Column 39: Independent uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no independent uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -5=no independent uncertainty input was given, -9=spectral fitting not successful Column 40: Structured uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -9=spectral fitting not successful Column 41: Common uncertainty of sulfur dioxide effective temperature [K], -1=temperature fitting was requested, but cross section is zero in this wavelength range, -2=no temperature fitting was requested and output for effective temperature and structured uncertainty of it is based on f-code, -3=spectral fitting was done, but no common uncertainty could be retrieved, -4=temperature fitting was requested, but differential optical depth is too small to retrieve the temperature, -6=no common uncertainty input was given, -9=spectral fitting not successful Column 42: Effective sulfur dioxide fitting wavelength [nm], -9=fitting not successful Column 43: Diffuse correction applied before fitting at effective fitting wavelength for sulfur dioxide [%], 0=no diffuse correction applied or fitting not requested, >0=measured diffuse correction, <0=(negative value of) calculated diffuse correction Column 44: Molecular scattering air mass factor used for molecular scattering subtraction before the fitting Column 45: Estimated uncertainty of molecular scattering air mass factor, -9=molecular scattering was not subtracted before the fitting Column 46: Lower limit used for wavelength scaling [nm] Column 47: Upper limit used for wavelength scaling [nm] Column 48: Order of smoothing polynomial Column 49: Smoothing polynomial coefficient, order 0 Column 50: Independent uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 51: Structured uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 52: Common uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 53: rms-based uncertainty of smoothing polynomial coefficient, order 0, -9=fitting not successful Column 54: Smoothing polynomial coefficient, order 1 Column 55: Independent uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 56: Structured uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 57: Common uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 58: rms-based uncertainty of smoothing polynomial coefficient, order 1, -9=fitting not successful Column 59: Smoothing polynomial coefficient, order 2 Column 60: Independent uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 61: Structured uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 62: Common uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 63: rms-based uncertainty of smoothing polynomial coefficient, order 2, -9=fitting not successful Column 64: Smoothing polynomial coefficient, order 3 Column 65: Independent uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 66: Structured uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 67: Common uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 68: rms-based uncertainty of smoothing polynomial coefficient, order 3, -9=fitting not successful Column 69: Mean value of measured data inside fitting window [same units as measurements] Column 70: Wavelength change polynomial coefficient, order 0 Column 71: Independent uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 72: Structured uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 73: Common uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 74: rms-based uncertainty of wavelength change polynomial coefficient, order 0, -9=fitting not successful Column 75: L1 based wavelength change coefficient, order 0, -9=no L1 wavelength change determination Column 76: L2Fit data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 77: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ1 limit, 0=L1 data quality above 0, 1=Spectral fitting was not successful, 2=Wavelength shift too large, 3=Normalized rms of fitting residuals weighted with independent uncertainty too large Column 78: Sum over 2^i using those i, for which the corresponding L2Fit data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 79: L1 data quality flag: 0=assured high quality, 1=assured medium quality, 2=assured low quality, 10=not-assured high quality, 11=not-assured medium quality, 12=not-assured low quality Column 80: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ1 limit, 0=Saturated data, 1=Too few dark counts measurements, 2=No temperature given or effective temperature too different from the reference temperature, 3=Dark count too high, 4=Unsuccessful dark background fitting, 5=The dark count differs significantly from the dark map for too many pixels, 6=Absolute value of estimated average residual stray light level too high, 7=Although attempted, no wavelength change could be retrieved, 8=Absolute value of retrieved wavelength shift too large, 9=Retrieved wavelength shift differs too much from the shift predicted by the effective temperature Column 81: Sum over 2^i using those i, for which the corresponding L1 data quality parameter exceeds the DQ2 limit (same parameters as for DQ1) Column 82: Atmospheric variability [%], 999=no atmospheric variability was determined Column 83: Wavelength effective temperature [°C], 999=no effective temperature given Column 84: Estimated average residual stray light level [%] (only valid for stray light correction methods 2 and higher) Column 85: Retrieved wavelength shift from L1 data [nm], -9=no wavelength change determination Column 86: Retrieved total wavelength shift [nm], -9=no wavelength change fitting Column 87: Number of bright count cycles Column 88: Number of dark count cycles Column 89: Effective position of filterwheel #1, 0=filterwheel not used, 1-9 are valid positions Column 90: Effective position of filterwheel #2, 0=filterwheel not used, 1-9 are valid positions Column 91: Sum over 2^i, 0=spectra were interpolated in time, 1=spectra are corrected for off-target signal Column 92: Integration time [ms] Column 93: Temperature at electronics board [°C], 999=no temperature signal Column 94: Spectrometer control temperature [°C], 999=no temperature signal Column 95: Auxiliary spectrometer temperature [°C], 999=no temperature signal Column 96: Temperature in head sensor [°C], 999=no temperature signal Column 97: Humidity in head sensor [%], -9=no humidity signal Column 98: Pressure in head sensor [hPa], -9=no pressure signal Columns 99-242: Unweighted slant column residuals for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting Columns 243-386: Normalized slant column residuals weighted with independent instrumental uncertainty for each pixel inside the fitting window multiplied by 1e5, 9e5=pixel was not used for fitting, 0=no independent instrumental uncertainty was given --------------------------------------------------------------------------------------- SS 20240627T150448.0Z 8944.628333 336 1 36.16 2 40.29 88.55 69.61 249.38 0.00 1 0.00 1 0 17 1.325e-02 1.111e-02 5.626e-04 4.158e-04 1.742266e-01 2.133628e-04 1.956049e-03 -6.000000e+00 7.590046e-03 230.65 -2.00 3.24 -2.00 314.57 0.00e+00 7.575782e-04 1.763313e-05 1.229658e-04 -6.000000e+00 3.482034e-04 293.30 -2.00 20.00 -2.00 313.87 0.00e+00 1.310 0.000 302.00 328.00 3 2.5944e+00 5.4708e-04 1.5488e-02 -6.0000e+00 1.8915e-02 1.3430e-02 6.0791e-04 8.2646e-03 -6.0000e+00 2.0501e-02 5.3549e-03 3.4790e-04 3.9715e-03 -6.0000e+00 1.2271e-02 -1.0737e-02 1.4988e-04 1.0838e-03 -6.0000e+00 5.1658e-03 8.9883e-03 1.0956e-04 1.1581e-05 1.5371e-05 -6.0000e+00 3.5739e-04 -4.1747e-04 12 9 9 12 1 1 99.98 26.80 0.48 -0.00042 0.00041 209 35 1 5 0 172.160 34.25 20.01 26.80 31.00 15.0 1010.86 918 639 1334 -1259 -3216 -2936 -2278 -451 288 -373 -2279 -3041 -1544 -670 677 1187 339 832 1406 1787 1902 795 1296 1278 1044 1138 870 -461 -1200 -836 -175 198 1247 -155 -3576 -4080 -3875 -2834 -645 271 17 -18 390 158 488 847 291 -2 -359 -693 157 776 900 1399 987 958 1033 515 251 190 617 1306 2017 2656 1735 -6 -744 -1735 -873 558 698 1055 851 940 416 -440 -1468 -2983 -2890 -2189 -2123 -1600 -2113 -2312 -1331 -553 147 690 1334 1153 804 256 -982 -1474 -1143 -1112 -411 581 748 171 -221 -1237 -1988 -1514 -771 -1193 -535 -274 76 1122 1634 2038 1856 1407 308 -381 -302 -56 363 692 582 597 758 622 320 327 -774 -296 -215 -142 -145 -592 -797 -732 -265 43 38 672 523 374 110 -295 -822 -893 328 253 543 -505 -1234 -1024 -801 -170 113 -158 -976 -1280 -643 -309 327 598 179 446 772 957 1043 438 708 724 619 665 517 -266 -670 -460 -97 109 722 -91 -2190 -2345 -2317 -1810 -436 206 13 -15 320 132 405 698 237 -1 -284 -556 127 636 749 1212 859 845 924 466 224 167 549 1215 1940 2624 1716 -6 -684 -1559 -777 522 706 1099 881 986 418 -434 -1353 -2634 -2486 -2018 -2045 -1640 -2214 -2539 -1483 -641 175 831 1631 1393 943 292 -1057 -1511 -1198 -1210 -460 691 913 215 -273 -1481 -2293 -1710 -901 -1469 -666 -346 99 1486 2210 2826 2530 1858 397 -466 -363 -69 455 909 768 798 1024 817 410 409 -954 -348 -259 -176 -185 -764 -1046 -975 -358 61 54 971 775 553 159 -425 -1154 -1245 SS 20240627T151408.5Z 8944.634820 339 1 53.96 2 38.26 89.68 71.44 250.79 0.00 1 0.00 1 0 17 1.312e-02 1.101e-02 1.660e-04 1.247e-04 1.698123e-01 6.410566e-05 1.904390e-03 -6.000000e+00 7.514187e-03 230.65 -2.00 3.24 -2.00 314.47 0.00e+00 7.534321e-04 5.201563e-06 1.081995e-04 -6.000000e+00 3.447211e-04 293.30 -2.00 20.00 -2.00 313.78 0.00e+00 1.272 0.000 302.00 328.00 3 6.5508e-01 1.6422e-04 1.5065e-02 -6.0000e+00 1.8726e-02 1.8180e-03 1.8231e-04 8.0628e-03 -6.0000e+00 2.0296e-02 4.8641e-03 1.0446e-04 3.8725e-03 -6.0000e+00 1.2148e-02 -1.0825e-02 4.4883e-05 1.0607e-03 -6.0000e+00 5.1142e-03 6.5722e-02 1.1587e-04 3.4814e-06 1.4975e-05 -6.0000e+00 3.5381e-04 -4.8034e-04 12 8 8 10 0 0 99.97 26.83 0.44 -0.00048 0.00039 2045 227 1 5 0 26.380 34.25 20.01 26.83 31.66 15.1 1010.79 730 566 1067 -1147 -3352 -3181 -2265 -483 425 -250 -2357 -2763 -1579 -730 718 1032 476 1016 1208 1916 1850 866 1346 1335 1013 1237 750 -466 -1131 -860 11 233 1241 -69 -3353 -4020 -3831 -2776 -740 283 -105 13 323 175 462 802 319 -39 -384 -710 281 708 880 1378 916 917 1093 434 333 210 646 1310 1983 2678 1707 -36 -647 -1866 -930 420 625 986 812 954 393 -424 -1428 -2881 -2812 -2198 -2079 -1654 -2150 -2332 -1399 -573 131 724 1257 1190 816 285 -945 -1408 -1140 -1034 -416 617 767 170 -321 -1230 -2020 -1434 -753 -1145 -551 -285 73 1076 1655 2014 1825 1360 301 -329 -212 -30 305 751 558 596 695 541 327 300 -733 -337 -148 -185 -116 -572 -773 -758 -242 50 20 700 548 317 129 -302 -836 -849 285 231 449 -474 -1320 -1139 -815 -186 171 -108 -1040 -1192 -679 -348 360 541 250 540 659 1068 1058 497 765 754 599 755 448 -280 -656 -469 6 133 714 -42 -2033 -2391 -2272 -1768 -505 210 -84 11 271 145 392 676 266 -31 -309 -558 223 590 746 1179 816 828 969 389 295 189 588 1209 1901 2645 1693 -35 -609 -1714 -845 391 631 1029 845 1001 395 -416 -1304 -2588 -2459 -1997 -1988 -1691 -2260 -2503 -1570 -653 155 886 1526 1461 971 319 -1022 -1444 -1191 -1094 -469 722 951 211 -393 -1449 -2288 -1630 -889 -1395 -681 -359 95 1424 2241 2797 2491 1792 384 -397 -250 -36 378 977 736 797 914 710 417 372 -892 -402 -180 -228 -147 -754 -1010 -1007 -327 69 28 1016 799 462 187 -428 -1179 -1189 SS 20240627T152001.8Z 8944.638910 343 1 12.99 2 36.99 90.41 72.60 251.66 0.00 1 0.00 1 0 17 1.315e-02 1.118e-02 6.768e-04 5.149e-04 1.667695e-01 2.648961e-04 1.877209e-03 -6.000000e+00 7.532126e-03 230.65 -2.00 3.24 -2.00 314.39 0.00e+00 7.972123e-04 2.120055e-05 1.036316e-04 -6.000000e+00 3.455280e-04 293.30 -2.00 20.00 -2.00 313.71 0.00e+00 1.251 0.000 302.00 328.00 3 2.0827e+00 6.7826e-04 1.4814e-02 -6.0000e+00 1.8770e-02 1.3516e-02 7.5251e-04 7.9427e-03 -6.0000e+00 2.0345e-02 5.1844e-03 4.3134e-04 3.8074e-03 -6.0000e+00 1.2177e-02 -1.0838e-02 1.8527e-04 1.0447e-03 -6.0000e+00 5.1267e-03 1.6123e-02 1.1265e-04 1.4374e-05 1.4916e-05 -6.0000e+00 3.5464e-04 -8.2944e-04 12 9 9 12 1 1 99.88 26.85 0.47 -0.00083 0.00002 105 49 1 5 0 122.540 34.25 20.01 26.85 32.45 15.2 1010.57 671 717 879 -1069 -3147 -3171 -2075 -458 471 -97 -2423 -2630 -1611 -830 549 1163 483 1012 1289 1796 1802 784 1335 1274 1048 1199 731 -377 -1247 -863 -103 241 1252 -117 -3479 -4006 -3753 -2850 -876 116 -79 95 433 177 414 832 409 35 -316 -701 140 867 848 1333 969 1041 1048 470 266 202 585 1280 1992 2653 1751 24 -654 -1905 -964 468 605 1050 828 978 426 -411 -1555 -2903 -2882 -2200 -2179 -1692 -2115 -2291 -1295 -526 167 778 1228 1248 841 231 -1083 -1493 -1234 -1033 -458 587 835 167 -303 -1172 -1999 -1559 -747 -1132 -486 -257 76 1096 1634 2098 1924 1370 312 -300 -265 -101 285 728 532 570 701 627 356 349 -807 -392 -192 -80 -138 -550 -793 -813 -258 32 55 676 572 348 156 -302 -820 -893 258 304 384 -457 -1281 -1175 -770 -182 196 -41 -1047 -1167 -713 -388 283 625 260 551 720 1025 1055 460 776 735 632 746 445 -231 -737 -479 -57 140 731 -73 -2141 -2414 -2252 -1838 -605 87 -64 78 367 148 355 708 343 29 -256 -555 112 726 723 1145 865 941 932 422 236 183 534 1184 1910 2621 1735 23 -614 -1747 -874 447 608 1090 857 1022 427 -402 -1458 -2595 -2506 -1984 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